Synthesis and characterization of ceramic high entropy carbide
thin films from the Cr-Hf-Mo-Ta-W refractory metal system

J 2024

Synthesis and characterization of ceramic high entropy carbide thin films from the Cr-Hf-Mo-Ta-W refractory metal system

STASIAK, Tomasz; Stanislava DEBNÁROVÁ; Shuyao LIN; Nikola KOUTNÁ; Zsolt CZIGÁNY et al.

Základní údaje

Originální název

Synthesis and characterization of ceramic high entropy carbide thin films from the Cr-Hf-Mo-Ta-W refractory metal system

Autoři

STASIAK, Tomasz; Stanislava DEBNÁROVÁ ; Shuyao LIN; Nikola KOUTNÁ; Zsolt CZIGÁNY; Katalin BALÁZSI; Vilma BURŠÍKOVÁ; Petr VAŠINA a Pavel SOUČEK

Vydání

Surface and Coatings Technology, Elsevier B.V. 2024, 0257-8972

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10305 Fluids and plasma physics

Stát vydavatele

Švýcarsko

Utajení

není předmětem státního či obchodního tajemství

Odkazy

URL

Impakt faktor

Impact factor: 6.100

Označené pro přenos do RIV

Ano

Kód RIV

RIV/00216224:14310/24:00135972

Organizační jednotka

Přírodovědecká fakulta

Klíčová slova anglicky

High entropy carbide; High entropy alloy; Multicomponent ceramics; Multicomponent material; Thin film; Magnetron sputtering

Štítky

14312030, rivok

Příznaky

Mezinárodní význam, Recenzováno

Změněno: 9. 7. 2025 12:46, Mgr. Marie Novosadová Šípková, DiS.

Anotace

V originále

We use reactive DC magnetron sputtering to showcase synthesis strategies for multicomponent carbides with the NaCl-type fcc structure and illustrate how deposition conditions allow controlling the formation of metallic and ceramic single phases in the Cr-Hf-Mo-Ta-W system. The synthesis is performed in argon flow and different acetylene flows from 0 to 12 sccm, at ambient and elevated temperatures (700 °C), respectively, hindering/promoting the adatom diffusion. Structural and microstructural investigations reveal the formation of the bcc metallic phase (a = 3.188−3.209 Å) in films deposited without acetylene flow, also supported by ab initio density function theory (DFT) analysis of lattice parameters as a function of the C content. Experimentally, a bcc-to-fcc phase transition is observed through the formation of an amorphous coating. Contrarily, samples deposited in higher acetylene flow show an fcc multielement carbide phase (a = 4.33−4.49 Å). The crystalline films reveal columnar morphology, while the amorphous ones are very dense. We report promising mechanical properties, with hardness up to 25 ± 1 GPa. The indentation moduli reach up to 319 ± 6 GPa and show trends consistent with DFT predictions. Our study paves the path towards the preparation of Cr-Hf-Mo-Ta-W multicomponent carbides by magnetron sputtering, showing promising microstructure as well as mechanical properties.

Návaznosti

GA23-05947S, projekt VaV

Název: Teorií směřované studium povlaků keramik stabilizovaných vysokou entropií založených na těžkotavitelných kovech

Investor: Grantová agentura ČR, Teorií směřované studium povlaků keramik stabilizovaných vysokou entropií založených na těžkotavitelných kovech

90097, velká výzkumná infrastruktura

Název: CEPLANT

Citovat

STASIAK, Tomasz; Stanislava DEBNÁROVÁ; Shuyao LIN; Nikola KOUTNÁ; Zsolt CZIGÁNY; Katalin BALÁZSI; Vilma BURŠÍKOVÁ; Petr VAŠINA a Pavel SOUČEK. Synthesis and characterization of ceramic high entropy carbide thin films from the Cr-Hf-Mo-Ta-W refractory metal system. Surface and Coatings Technology. Elsevier B.V., 2024, roč. 485, June 2024, s. 1-12. ISSN 0257-8972. Dostupné z: https://doi.org/10.1016/j.surfcoat.2024.130839.

@article{2400438,
   author = {Stasiak, Tomasz and Debnárová, Stanislava and Lin, Shuyao and Koutná, Nikola and Czigány, Zsolt and Balázsi, Katalin and Buršíková, Vilma and Vašina, Petr and Souček, Pavel},
   article_number = {June 2024},
   doi = {https://doi.org/10.1016/j.surfcoat.2024.130839},
   keywords = {High entropy carbide; High entropy alloy; Multicomponent ceramics; Multicomponent material; Thin film; Magnetron sputtering},
   language = {eng},
   issn = {0257-8972},
   journal = {Surface and Coatings Technology},
   title = {Synthesis and characterization of ceramic high entropy carbide thin films from the Cr-Hf-Mo-Ta-W refractory metal system},
   url = {https://www.sciencedirect.com/science/article/pii/S0257897224004705},
   volume = {485},
   year = {2024}
}

TY  - JOUR
ID  - 2400438
AU  - Stasiak, Tomasz - Debnárová, Stanislava - Lin, Shuyao - Koutná, Nikola - Czigány, Zsolt - Balázsi, Katalin - Buršíková, Vilma - Vašina, Petr - Souček, Pavel
PY  - 2024
TI  - Synthesis and characterization of ceramic high entropy carbide thin films from the Cr-Hf-Mo-Ta-W refractory metal system
JF  - Surface and Coatings Technology
VL  - 485
IS  - June 2024
SP  - 1-12
EP  - 1-12
PB  - Elsevier B.V.
SN  - 02578972
KW  - High entropy carbide
KW  - High entropy alloy
KW  - Multicomponent ceramics
KW  - Multicomponent material
KW  - Thin film
KW  - Magnetron sputtering
UR  - https://www.sciencedirect.com/science/article/pii/S0257897224004705
N2  - We use reactive DC magnetron sputtering to showcase synthesis strategies for multicomponent carbides with the NaCl-type fcc structure and illustrate how deposition conditions allow controlling the formation of metallic and ceramic single phases in the Cr-Hf-Mo-Ta-W system. The synthesis is performed in argon flow and different acetylene flows from 0 to 12 sccm, at ambient and elevated temperatures (700 °C), respectively, hindering/promoting the adatom diffusion. Structural and microstructural investigations reveal the formation of the bcc metallic phase (a = 3.188−3.209 Å) in films deposited without acetylene flow, also supported by ab initio density function theory (DFT) analysis of lattice parameters as a function of the C content. Experimentally, a bcc-to-fcc phase transition is observed through the formation of an amorphous coating. Contrarily, samples deposited in higher acetylene flow show an fcc multielement carbide phase (a = 4.33−4.49 Å). The crystalline films reveal columnar morphology, while the amorphous ones are very dense. We report promising mechanical properties, with hardness up to 25 ± 1 GPa. The indentation moduli reach up to 319 ± 6 GPa and show trends consistent with DFT predictions. Our study paves the path towards the preparation of Cr-Hf-Mo-Ta-W multicomponent carbides by magnetron sputtering, showing promising microstructure as well as mechanical properties.
ER  -

STASIAK, Tomasz; Stanislava DEBNÁROVÁ; Shuyao LIN; Nikola KOUTNÁ; Zsolt CZIGÁNY; Katalin BALÁZSI; Vilma BURŠÍKOVÁ; Petr VAŠINA a Pavel SOUČEK. Synthesis and characterization of ceramic high entropy carbide thin films from the Cr-Hf-Mo-Ta-W refractory metal system. \textit{Surface and Coatings Technology}. Elsevier B.V., 2024, roč.~485, June 2024, s.~1-12. ISSN~0257-8972. Dostupné z: https://doi.org/10.1016/j.surfcoat.2024.130839.

Přehled o publikaci