Air-soil cycling of oxygenated, nitrated and parent polycyclic
aromatic hydrocarbons in source and receptor areas

J 2024

Air-soil cycling of oxygenated, nitrated and parent polycyclic aromatic hydrocarbons in source and receptor areas

MWANGI, John Kennedy; Céline DEGRENDELE; Benjamin A. M. BANDOWE; Pernilla BOHLIN-NIZZETTO; Anne K. HALSE et al.

Základní údaje

Originální název

Air-soil cycling of oxygenated, nitrated and parent polycyclic aromatic hydrocarbons in source and receptor areas

Autoři

Vydání

Science of the Total Environment, AMSTERDAM, Elsevier, 2024, 0048-9697

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10511 Environmental sciences

Stát vydavatele

Nizozemské království

Utajení

není předmětem státního či obchodního tajemství

Odkazy

URL

Impakt faktor

Impact factor: 8.000

Označené pro přenos do RIV

Ano

Kód RIV

RIV/00216224:14310/24:00136716

Organizační jednotka

Přírodovědecká fakulta

Klíčová slova anglicky

Polycyclic aromatic compounds; Soil fugacity; Aerosol; Long-range atmospheric transport; Grasshopper effect

Štítky

143180, rivok

Příznaky

Mezinárodní význam, Recenzováno

Změněno: 24. 2. 2025 10:01, Mgr. Michaela Hylsová, Ph.D.

Anotace

V originále

Polycyclic aromatic hydrocarbons (PAHs) and their oxygenated and nitrated derivatives, OPAHs and NPAHs, are semivolatile air pollutants which are distributed and cycling regionally. Subsequent to atmospheric deposition to and accumulation in soils they may re -volatilise, a secondary source which is understudied. We studied the direction of air -soil mass exchange fluxes of 12 OPAHs, 17 NPAHs, 25 PAHs and one alkylated PAH in two rural environments being influenced by the pollutant concentrations in soil and air, by season, and by land cover. The OPAHs and NPAHs in samples of topsoil, of ambient air particulate and gas phases and in the gas phase equilibrated with soil were analysed by GC-APCI-MS/MS. The pollutants soil burdens show a pronounced seasonality, a winter maximum for NPAHs and PAHs and a summer maximum for OPAHs. One order of magnitude more OPAH and parent PAH are found stored in forest soil than in nearby grassland soil. Among a number of 3-4 ring PAHs, the OPAHs benzanthrone and 6H-benzo(c,d)pyren-6-one, and the NPAHs 1- and 2nitronaphthalene, 9-nitrophenanthrene and 7-nitrobenz(a)anthracene are found to re -volatilise from soils at a rural background site in central Europe in summer. At a receptor site in northern Europe, net deposition of polycyclic aromatic compounds (PACs) prevails and re -volatilisation occurs only sporadic. Re -volatilisation of a number of PACs, including strong mutagens, from soils in summer and even in winter indicates that long-range atmospheric transport of primary PAC emissions from central Europe to receptor areas might be enhanced by secondary emissions from soils.

Návaznosti

EF17_043/0009632, projekt VaV

Název: CETOCOEN Excellence

GA20-07117S, projekt VaV

Název: Nitro- a oxyderiváty polycyklických aromatických uhlovodíků v atmosféře - distribuce, výměna mezi ovzduším a povrchy a potenciál dálkového přenosu

Investor: Grantová agentura ČR, Nitro- a oxyderiváty polycyklických aromatických uhlovodíků v atmosféře - distribuce, výměna mezi ovzduším a povrchy a potenciál dálkového přenosu

90230, velká výzkumná infrastruktura

Název: ACTRIS-CZ III

90269, velká výzkumná infrastruktura

Název: RECETOX RI II

Citovat

MWANGI, John Kennedy; Céline DEGRENDELE; Benjamin A. M. BANDOWE; Pernilla BOHLIN-NIZZETTO; Anne K. HALSE; Adela Holubova SMEJKALOVA; Jun-Tae KIM; Petr KUKUČKA; Jakub MARTINÍK; Barbora PALÁTOVÁ NEŽIKOVÁ; Petra PŘIBYLOVÁ; Roman PROKEŠ; Milan SÁŇKA; Mariam TANNOUS; Jakub VINKLER a Gerhard LAMMEL. Air-soil cycling of oxygenated, nitrated and parent polycyclic aromatic hydrocarbons in source and receptor areas. Science of the Total Environment. AMSTERDAM: Elsevier, 2024, roč. 921, April 2024, s. 1-12. ISSN 0048-9697. Dostupné z: https://doi.org/10.1016/j.scitotenv.2024.170495.

@article{2421899,
   author = {Mwangi, John Kennedy and Degrendele, Céline and Bandowe, Benjamin A. M. and BohlinandNizzetto, Pernilla and Halse, Anne K. and Smejkalova, Adela Holubova and Kim, JunandTae and Kukučka, Petr and Martiník, Jakub and Palátová Nežiková, Barbora and Přibylová, Petra and Prokeš, Roman and Sáňka, Milan and Tannous, Mariam and Vinkler, Jakub and Lammel, Gerhard},
   article_location = {AMSTERDAM},
   article_number = {April 2024},
   doi = {https://doi.org/10.1016/j.scitotenv.2024.170495},
   keywords = {Polycyclic aromatic compounds; Soil fugacity; Aerosol; Long-range atmospheric transport; Grasshopper effect},
   language = {eng},
   issn = {0048-9697},
   journal = {Science of the Total Environment},
   title = {Air-soil cycling of oxygenated, nitrated and parent polycyclic aromatic hydrocarbons in source and receptor areas},
   url = {https://www.sciencedirect.com/science/article/pii/S0048969724006326?via%3Dihub},
   volume = {921},
   year = {2024}
}

TY  - JOUR
ID  - 2421899
AU  - Mwangi, John Kennedy - Degrendele, Céline - Bandowe, Benjamin A. M. - Bohlin-Nizzetto, Pernilla - Halse, Anne K. - Smejkalova, Adela Holubova - Kim, Jun-Tae - Kukučka, Petr - Martiník, Jakub - Palátová Nežiková, Barbora - Přibylová, Petra - Prokeš, Roman - Sáňka, Milan - Tannous, Mariam - Vinkler, Jakub - Lammel, Gerhard
PY  - 2024
TI  - Air-soil cycling of oxygenated, nitrated and parent polycyclic aromatic hydrocarbons in source and receptor areas
JF  - Science of the Total Environment
VL  - 921
IS  - April 2024
SP  - 1-12
EP  - 1-12
PB  - Elsevier
SN  - 00489697
KW  - Polycyclic aromatic compounds
KW  - Soil fugacity
KW  - Aerosol
KW  - Long-range atmospheric transport
KW  - Grasshopper effect
UR  - https://www.sciencedirect.com/science/article/pii/S0048969724006326?via%3Dihub
N2  - Polycyclic aromatic hydrocarbons (PAHs) and their oxygenated and nitrated derivatives, OPAHs and NPAHs, are semivolatile air pollutants which are distributed and cycling regionally. Subsequent to atmospheric deposition to and accumulation in soils they may re -volatilise, a secondary source which is understudied. We studied the direction of air -soil mass exchange fluxes of 12 OPAHs, 17 NPAHs, 25 PAHs and one alkylated PAH in two rural environments being influenced by the pollutant concentrations in soil and air, by season, and by land cover. The OPAHs and NPAHs in samples of topsoil, of ambient air particulate and gas phases and in the gas phase equilibrated with soil were analysed by GC-APCI-MS/MS. The pollutants soil burdens show a pronounced seasonality, a winter maximum for NPAHs and PAHs and a summer maximum for OPAHs. One order of magnitude more OPAH and parent PAH are found stored in forest soil than in nearby grassland soil. Among a number of 3-4 ring PAHs, the OPAHs benzanthrone and 6H-benzo(c,d)pyren-6-one, and the NPAHs 1- and 2nitronaphthalene, 9-nitrophenanthrene and 7-nitrobenz(a)anthracene are found to re -volatilise from soils at a rural background site in central Europe in summer. At a receptor site in northern Europe, net deposition of polycyclic aromatic compounds (PACs) prevails and re -volatilisation occurs only sporadic. Re -volatilisation of a number of PACs, including strong mutagens, from soils in summer and even in winter indicates that long-range atmospheric transport of primary PAC emissions from central Europe to receptor areas might be enhanced by secondary emissions from soils.
ER  -

MWANGI, John Kennedy; Céline DEGRENDELE; Benjamin A. M. BANDOWE; Pernilla BOHLIN-NIZZETTO; Anne K. HALSE; Adela Holubova SMEJKALOVA; Jun-Tae KIM; Petr KUKUČKA; Jakub MARTINÍK; Barbora PALÁTOVÁ NEŽIKOVÁ; Petra PŘIBYLOVÁ; Roman PROKEŠ; Milan SÁŇKA; Mariam TANNOUS; Jakub VINKLER a Gerhard LAMMEL. Air-soil cycling of oxygenated, nitrated and parent polycyclic aromatic hydrocarbons in source and receptor areas. \textit{Science of the Total Environment}. AMSTERDAM: Elsevier, 2024, roč.~921, April 2024, s.~1-12. ISSN~0048-9697. Dostupné z: https://doi.org/10.1016/j.scitotenv.2024.170495.

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