A complex study of photocatalytic oxidation pathways of
antibiotics with graphitic carbon nitride–The way towards
continuous flow conditions

J 2024

A complex study of photocatalytic oxidation pathways of antibiotics with graphitic carbon nitride–The way towards continuous flow conditions

SCHIMON, Dominik; Karolina SMITKOVA; Petr STAVAREK; Natalie JAKLOVA; Anna VANLUCHENE et. al.

Základní údaje

Originální název

A complex study of photocatalytic oxidation pathways of antibiotics with graphitic carbon nitride–The way towards continuous flow conditions

Autoři

SCHIMON, Dominik; Karolina SMITKOVA; Petr STAVAREK; Natalie JAKLOVA; Anna VANLUCHENE; Petr DZIK; Tomáš HOMOLA (703 Slovensko, domácí); František ZAŽÍMAL (203 Česká republika, domácí) a Petr KLUSON

Vydání

Journal of Environmental Chemical Engineering, Elsevier Ltd, 2024, 2213-2929

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

20506 Coating and films

Stát vydavatele

Velká Británie a Severní Irsko

Utajení

není předmětem státního či obchodního tajemství

Odkazy

URL

Impakt faktor

Impact factor: 7.400 v roce 2023

Kód RIV

RIV/00216224:14310/24:00137728

Organizační jednotka

Přírodovědecká fakulta

DOI

http://dx.doi.org/10.1016/j.jece.2024.114801

UT WoS

001359170400001

EID Scopus

2-s2.0-85208763097

Klíčová slova anglicky

Carbon nitride; Fluid flow; Photocatalysis; Antibiotics; Kinetic model

Štítky

rivok

Příznaky

Mezinárodní význam, Recenzováno

Změněno: 9. 7. 2025 13:38, Mgr. Marie Novosadová Šípková, DiS.

Anotace

V originále

The release of pharmaceuticals and their metabolites into the environment poses pollution risks with consequences in fauna and flora that are not yet fully known nor understood. Photocatalysis with graphitic carbon nitride (g-C3N4) using solar light could potentially contribute to reducing these risks. In this work, g-C3N4 in two different forms was investigated for photooxidative degradation of three chosen antibiotics: tetracycline, trimethoprim, and sulfamethoxazole. The emphasis was put on investigation of degradation pathways description, mechanism modeling, and comparison of two photoreactor systems. g-C3N4 in powder form was studied in a batch photoreactor, while g-C3N4 in the form of a photocatalytic film was studied in a photomicroreactor with a slit geometry. It was found that during the photooxidative processes mainly oxidation products of starting material were prevaling in the reaction mixture, while the degradation products of smaller molecular mass were apparently directly mineralized. The comparison of batch and micro protoreactor has shown that the latter was substantially better performing thanks to the more efficient photocatalytic film irradiation and narrow internal space. It was found that the microphotoreactor with a photocatalytic film based on g-C3N4 is a promising concept that provides a high scalability potential and deserves further investigation and development.

Návaznosti

GA23-06843S, projekt VaV

Název: Pokročilé tenkovrstvé fotokatalyzátory na bázi grafitického karbon nitridu

Investor: Grantová agentura ČR, Pokročilé tenkovrstvé fotokatalyzátory na bázi grafitického karbon nitridu

90239, velká výzkumná infrastruktura

Název: CEPLANT II

90251, velká výzkumná infrastruktura

Název: CzechNanoLab II

Citovat

SCHIMON, Dominik; Karolina SMITKOVA; Petr STAVAREK; Natalie JAKLOVA; Anna VANLUCHENE; Petr DZIK; Tomáš HOMOLA; František ZAŽÍMAL a Petr KLUSON. A complex study of photocatalytic oxidation pathways of antibiotics with graphitic carbon nitride–The way towards continuous flow conditions. Journal of Environmental Chemical Engineering. Elsevier Ltd, 2024, roč. 12, č. 6, s. 114801-114814. ISSN 2213-2929. Dostupné z: https://dx.doi.org/10.1016/j.jece.2024.114801.

@article{2453920,
   author = {Schimon, Dominik and Smitkova, Karolina and Stavarek, Petr and Jaklova, Natalie and Vanluchene, Anna and Dzik, Petr and Homola, Tomáš and Zažímal, František and Kluson, Petr},
   article_number = {6},
   doi = {http://dx.doi.org/10.1016/j.jece.2024.114801},
   keywords = {Carbon nitride; Fluid flow; Photocatalysis; Antibiotics; Kinetic model},
   language = {eng},
   issn = {2213-2929},
   journal = {Journal of Environmental Chemical Engineering},
   title = {A complex study of photocatalytic oxidation pathways of antibiotics with graphitic carbon nitride–The way towards continuous flow conditions},
   url = {https://www.sciencedirect.com/science/article/pii/S2213343724029336},
   volume = {12},
   year = {2024}
}

TY  - JOUR
ID  - 2453920
AU  - Schimon, Dominik - Smitkova, Karolina - Stavarek, Petr - Jaklova, Natalie - Vanluchene, Anna - Dzik, Petr - Homola, Tomáš - Zažímal, František - Kluson, Petr
PY  - 2024
TI  - A complex study of photocatalytic oxidation pathways of antibiotics with graphitic carbon nitride–The way towards continuous flow conditions
JF  - Journal of Environmental Chemical Engineering
VL  - 12
IS  - 6
SP  - 114801
EP  - 114801
PB  - Elsevier Ltd
SN  - 22132929
KW  - Carbon nitride
KW  - Fluid flow
KW  - Photocatalysis
KW  - Antibiotics
KW  - Kinetic model
UR  - https://www.sciencedirect.com/science/article/pii/S2213343724029336
N2  - The release of pharmaceuticals and their metabolites into the environment poses pollution risks with consequences in fauna and flora that are not yet fully known nor understood. Photocatalysis with graphitic carbon nitride (g-C3N4) using solar light could potentially contribute to reducing these risks. In this work, g-C3N4 in two different forms was investigated for photooxidative degradation of three chosen antibiotics: tetracycline, trimethoprim, and sulfamethoxazole. The emphasis was put on investigation of degradation pathways description, mechanism modeling, and comparison of two photoreactor systems. g-C3N4 in powder form was studied in a batch photoreactor, while g-C3N4 in the form of a photocatalytic film was studied in a photomicroreactor with a slit geometry. It was found that during the photooxidative processes mainly oxidation products of starting material were prevaling in the reaction mixture, while the degradation products of smaller molecular mass were apparently directly mineralized. The comparison of batch and micro protoreactor has shown that the latter was substantially better performing thanks to the more efficient photocatalytic film irradiation and narrow internal space. It was found that the microphotoreactor with a photocatalytic film based on g-C3N4 is a promising concept that provides a high scalability potential and deserves further investigation and development.
ER  -

SCHIMON, Dominik; Karolina SMITKOVA; Petr STAVAREK; Natalie JAKLOVA; Anna VANLUCHENE; Petr DZIK; Tomáš HOMOLA; František ZAŽÍMAL a Petr KLUSON. A complex study of photocatalytic oxidation pathways of antibiotics with graphitic carbon nitride–The way towards continuous flow conditions. \textit{Journal of Environmental Chemical Engineering}. Elsevier Ltd, 2024, roč.~12, č.~6, s.~114801-114814. ISSN~2213-2929. Dostupné z: https://dx.doi.org/10.1016/j.jece.2024.114801.

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