Selective and sensitive determination of phenolic compounds
using carbon screen printing electrodes modified with reduced
graphene oxide and silver nanoparticles

J 2024

Selective and sensitive determination of phenolic compounds using carbon screen printing electrodes modified with reduced graphene oxide and silver nanoparticles

CHAKKARAPANI, Lakshmi Devi; Zuzana BYTESNIKOVA; Lukas RICHTERA a Martin BRANDL

Základní údaje

Originální název

Selective and sensitive determination of phenolic compounds using carbon screen printing electrodes modified with reduced graphene oxide and silver nanoparticles

Autoři

CHAKKARAPANI, Lakshmi Devi; Zuzana BYTESNIKOVA; Lukas RICHTERA a Martin BRANDL

Vydání

Applied Materials Today, Amsterdam, Elsevier, 2024, 2352-9407

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10406 Analytical chemistry

Stát vydavatele

Nizozemské království

Utajení

není předmětem státního či obchodního tajemství

Odkazy

URL

Impakt faktor

Impact factor: 6.900

Označené pro přenos do RIV

Ano

Kód RIV

RIV/00216224:90242/24:00138498

Organizační jednotka

CIISB III

Klíčová slova anglicky

Nanoparticles; Screen -printed electrodes; Butylated hydroxyanisole; Reduced graphene oxide; Vanillin

Štítky

CF NANO, ne MU

Příznaky

Mezinárodní význam, Recenzováno

Změněno: 19. 3. 2025 17:01, Mgr. Eva Dubská

Anotace

V originále

Butylated hydroxyanisole (BHA) and vanillin (VA) are the well-known phenolic compounds often used as preservatives in various foods and beverages. BHA is a safe additive whose concentration in food should not exceed 0.02 %. VA is used as a flavoring agent in foods, but the maximum allowable amount for VA is limited to 7 mg/ 100 g. However, elevated levels of BHA and VA can lead to severe health issues in the human body. To ensure reliable quality control, the food industry must accurately determine the BHA and VA content in food. In this work, we developed an electrochemical sensor for the detection of BHA and VA using a screen-printed electrode (SPE) modified with reduced graphene oxide and silver nanoparticles (RGO-Ag NPs). The SPE modified with RGO-Ag NPs showed an oxidation potential for BHA of 0.34 V and 0.62 V for VA in phosphate buffer solution (0.1 M PBS, pH 7.4) at a scan rate of 50 mV/s. In contrast, the unmodified SPE shows no significant current and oxidation potential response of BHA and VA under the same experimental conditions. (Cyclic voltammetry (CV) measurements for BHA ranged from 9.9 mu M to 239.25 mu M, while differential pulse voltammetry (DPV) measurements of BHA provided a linear calibration from 0.49 mu M to 3.67 mu M with a lower detection limit of 0.16 mu M (S/N = 3). For VA, CV measurements covered a range from 82.6 mu M to 242.4 mu M, and DPV measurements displayed a linear calibration from 1.47 mu M to 12.79 mu M with a detection limit of 0.15 mu M (S/N = 3).

Návaznosti

90242, velká výzkumná infrastruktura

Název: CIISB III

Citovat

CHAKKARAPANI, Lakshmi Devi; Zuzana BYTESNIKOVA; Lukas RICHTERA a Martin BRANDL. Selective and sensitive determination of phenolic compounds using carbon screen printing electrodes modified with reduced graphene oxide and silver nanoparticles. Applied Materials Today. Amsterdam: Elsevier, 2024, roč. 37, Apr, s. 1-14. ISSN 2352-9407. Dostupné z: https://doi.org/10.1016/j.apmt.2024.102113.

@article{2468523,
   author = {Chakkarapani, Lakshmi Devi and Bytesnikova, Zuzana and Richtera, Lukas and Brandl, Martin},
   article_location = {Amsterdam},
   article_number = {Apr},
   doi = {https://doi.org/10.1016/j.apmt.2024.102113},
   keywords = {Nanoparticles; Screen -printed electrodes; Butylated hydroxyanisole; Reduced graphene oxide; Vanillin},
   language = {eng},
   issn = {2352-9407},
   journal = {Applied Materials Today},
   title = {Selective and sensitive determination of phenolic compounds using carbon screen printing electrodes modified with reduced graphene oxide and silver nanoparticles},
   url = {https://www.sciencedirect.com/science/article/pii/S2352940724000593?via%3Dihub},
   volume = {37},
   year = {2024}
}

TY  - JOUR
ID  - 2468523
AU  - Chakkarapani, Lakshmi Devi - Bytesnikova, Zuzana - Richtera, Lukas - Brandl, Martin
PY  - 2024
TI  - Selective and sensitive determination of phenolic compounds using carbon screen printing electrodes modified with reduced graphene oxide and silver nanoparticles
JF  - Applied Materials Today
VL  - 37
IS  - Apr
SP  - 1-14
EP  - 1-14
PB  - Elsevier
SN  - 23529407
KW  - Nanoparticles
KW  - Screen -printed electrodes
KW  - Butylated hydroxyanisole
KW  - Reduced graphene oxide
KW  - Vanillin
UR  - https://www.sciencedirect.com/science/article/pii/S2352940724000593?via%3Dihub
N2  - Butylated hydroxyanisole (BHA) and vanillin (VA) are the well-known phenolic compounds often used as preservatives in various foods and beverages. BHA is a safe additive whose concentration in food should not exceed 0.02 %. VA is used as a flavoring agent in foods, but the maximum allowable amount for VA is limited to 7 mg/ 100 g. However, elevated levels of BHA and VA can lead to severe health issues in the human body. To ensure reliable quality control, the food industry must accurately determine the BHA and VA content in food. In this work, we developed an electrochemical sensor for the detection of BHA and VA using a screen-printed electrode (SPE) modified with reduced graphene oxide and silver nanoparticles (RGO-Ag NPs). The SPE modified with RGO-Ag NPs showed an oxidation potential for BHA of 0.34 V and 0.62 V for VA in phosphate buffer solution (0.1 M PBS, pH 7.4) at a scan rate of 50 mV/s. In contrast, the unmodified SPE shows no significant current and oxidation potential response of BHA and VA under the same experimental conditions. (Cyclic voltammetry (CV) measurements for BHA ranged from 9.9 mu M to 239.25 mu M, while differential pulse voltammetry (DPV) measurements of BHA provided a linear calibration from 0.49 mu M to 3.67 mu M with a lower detection limit of 0.16 mu M (S/N = 3). For VA, CV measurements covered a range from 82.6 mu M to 242.4 mu M, and DPV measurements displayed a linear calibration from 1.47 mu M to 12.79 mu M with a detection limit of 0.15 mu M (S/N = 3).
ER  -

CHAKKARAPANI, Lakshmi Devi; Zuzana BYTESNIKOVA; Lukas RICHTERA a Martin BRANDL. Selective and sensitive determination of phenolic compounds using carbon screen printing electrodes modified with reduced graphene oxide and silver nanoparticles. \textit{Applied Materials Today}. Amsterdam: Elsevier, 2024, roč.~37, Apr, s.~1-14. ISSN~2352-9407. Dostupné z: https://doi.org/10.1016/j.apmt.2024.102113.

Přehled o publikaci