J 2024

Contrasting assemblages of secondary minerals after beryl from the granitic pegmatites Drahonín IV and Věžná I; evidence for high variability of mineralised fluids in the Rožná-Olší ore field area, Czech Republic

NOVÁK, Milan; Petr GADAS; Kamil SOBEK; Jiri TOMAN; Drahos SIKOLA et. al.

Základní údaje

Originální název

Contrasting assemblages of secondary minerals after beryl from the granitic pegmatites Drahonín IV and Věžná I; evidence for high variability of mineralised fluids in the Rožná-Olší ore field area, Czech Republic

Autoři

NOVÁK, Milan; Petr GADAS; Kamil SOBEK; Jiri TOMAN a Drahos SIKOLA

Vydání

Mineralogical Magazine, Cambridge University Press, 2024, 0026-461X

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10504 Mineralogy

Stát vydavatele

Velká Británie a Severní Irsko

Utajení

není předmětem státního či obchodního tajemství

Odkazy

Impakt faktor

Impact factor: 1.400

Kód RIV

RIV/00216224:14310/24:00139031

Organizační jednotka

Přírodovědecká fakulta

UT WoS

001421387000001

EID Scopus

2-s2.0-86000433725

Klíčová slova anglicky

beryl; secondary Be minerals; granitic pegmatites; internal hydrothermal fluids; external hydrothermal fluids

Štítky

Příznaky

Mezinárodní význam, Recenzováno
Změněno: 31. 3. 2025 12:30, Mgr. Marie Novosadová Šípková, DiS.

Anotace

V originále

This work presents data for the mineral assemblages, composition and Raman spectroscopy of proximal secondary Be and associated minerals in pseudomorphs after beryl from granitic pegmatites located along the contacts of major regional geological units. The pegmatites differ in their position relative to the ductile to brittle shear zones within the Rožná-Olší ore field (U-deposit), Czech Republic. Extensive dissolution of beryl crystals in the beryl–columbite pegmatites Drahonín IV and Věžná I situated within or close to the shear zones is evident in contrast to minor alteration of beryl in the Dolní Rožínka and Kovářová pegmatites located outside of the shear zones. Near-total replacement of beryl crystals, up to 40 cm in length, from the Drahonín IV pegmatite, located in the Olší shear zone formed the following secondary Be minerals in order of their abundance: bavenite–bohseite > bertrandite ≫ milarite > hydroxylgugiaite. This assemblage is also characterised by the presence of sulfides (pyrite, galena, sphalerite) and zeolites. Such an extensive replacement process required a substantial fluid flow and is very possibly related to the pre-uranium quartz–sulfide and carbonate–sulfide mineralisation events within the Rožná-Olší ore field. Alteration products resulting from breakdown of beryl in the Věžná I pegmatite follow the sequential substages (bertrandite + K-feldspar ± harmotome → epididymite + K-feldspar → hydroxylgugiaite + K-feldspar) and locally show cross-cutting textures. These assemblages were generated by post-magmatic residual fluids (early assemblage bertrandite + K-feldspar) as well as fluids related to a retrograde stage of metamorphism, compositionally contrasting with the host serpentinite, and perhaps also hydrothermal processes associated with the Olší shear zone. The pegmatites Dolní Rožínka and Kovářová, located outside of the shear zones, exhibit only a low degree of alteration and have differing textural and paragenetic development. Highly variable assemblages of secondary minerals after beryl are excellent mineral indicators of hydrothermal overprinting in granitic pegmatites during a variety of subsolidus processes.

Návaznosti

EF16_026/0008459, projekt VaV
Název: Dlouhodobý výzkum geochemických bariér pro ukládání jaderného odpadu