Porous MIL, ZIF, and UiO metal-organic frameworks for
adsorption of pharmaceuticals and personal care products

J 2025

Porous MIL, ZIF, and UiO metal-organic frameworks for adsorption of pharmaceuticals and personal care products

ADEGOKE, Kayode Adesina; Emmanuel Sunday OKEKE; Elizabeth Oyinkansola OMOTOLA; Chinemerem Ruth OHORO; James F. AMAKU et al.

Základní údaje

Originální název

Porous MIL, ZIF, and UiO metal-organic frameworks for adsorption of pharmaceuticals and personal care products

Autoři

Vydání

Advances in Colloid and Interface Science, Elsevier B.V. 2025, 0001-8686

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10403 Physical chemistry

Stát vydavatele

Nizozemské království

Utajení

není předmětem státního či obchodního tajemství

Odkazy

URL

Impakt faktor

Impact factor: 19.300 v roce 2024

Označené pro přenos do RIV

Ano

Kód RIV

RIV/00216224:14310/25:00141582

Organizační jednotka

Přírodovědecká fakulta

Klíčová slova anglicky

Emerging pollutants; Pharmaceuticals and personal care products; Adsorption; Wastewater; Metal-organic frameworks

Štítky

143180, rivok

Příznaky

Mezinárodní význam, Recenzováno

Změněno: 21. 7. 2025 13:01, Mgr. Marie Novosadová Šípková, DiS.

Anotace

V originále

Pharmaceuticals and personal care products (PPCPs) are a newly identified category of emerging global pollutants often found in aquatic systems. Efficient removal of these pollutants from the water/wastewater is currently problematic because of their low biodegradability and high hydrophilicity, as well as their distinct physicochemical features and lower concentrations. Materials of Institut Lavoisier (MIL), Zeolitic imidazolate framework (ZIF), and University of Oslo (UiO) are highly engineered metal-organic frameworks (MOFs) composed of unique components necessary for the formation of crystals with exceptional porosity, large surface areas, large pore sizes, crystalline structures, tunable properties, excellent chemical and thermal stability for environmental remediation. This study provides detailed and combined applications of UiOs, MILs, and ZIFs as adsorbents for capturing the new class of emerging pollutants (PPCPs) from the liquid phase. MOFs as ideal candidates for PPCP decontamination were discussed, followed by the MOF porosity and factors that affect MOF stability. Various synthetic approaches for MILs, ZIFs, and UiOs were discussed, as well as their corresponding pros and cons. An in-depth performance of these three MOFs for adsorptive removal of PPCPs from the liquid phase was discussed, assessing the state-of-the-art for specific applications and the effectiveness of UiOs, MILs, and ZIFs as adsorbents for PPCP decontamination . The unique performance garnered from the study provided a way forward/potential for real-life/practical applications of these sorbents and insight into corresponding mechanisms and synergistic relationships. To foster the advancement of the field, viable shortcomings and strengths associated with these novel classes of MOFs, treatment options, and knowledge gaps to explore specific research directives for large-scale or industrial-scale applications were highlighted.

Citovat

ADEGOKE, Kayode Adesina; Emmanuel Sunday OKEKE; Elizabeth Oyinkansola OMOTOLA; Chinemerem Ruth OHORO; James F. AMAKU; Jeanet CONRADIE; Chijioke OLISAH; Kovo G. AKPOMIE; Alhadji MALLOUM a Samson O. AKPOTU. Porous MIL, ZIF, and UiO metal-organic frameworks for adsorption of pharmaceuticals and personal care products. Advances in Colloid and Interface Science. Elsevier B.V., 2025, roč. 342, August 2025, s. 1-38. ISSN 0001-8686. Dostupné z: https://doi.org/10.1016/j.cis.2025.103509.

@article{2508035,
   author = {Adegoke, Kayode Adesina and Okeke, Emmanuel Sunday and Omotola, Elizabeth Oyinkansola and Ohoro, Chinemerem Ruth and Amaku, James F. and Conradie, Jeanet and Olisah, Chijioke and Akpomie, Kovo G. and Malloum, Alhadji and Akpotu, Samson O.},
   article_number = {August 2025},
   doi = {https://doi.org/10.1016/j.cis.2025.103509},
   keywords = {Emerging pollutants; Pharmaceuticals and personal care products; Adsorption; Wastewater; Metal-organic frameworks},
   language = {eng},
   issn = {0001-8686},
   journal = {Advances in Colloid and Interface Science},
   title = {Porous MIL, ZIF, and UiO metal-organic frameworks for adsorption of pharmaceuticals and personal care products},
   url = {https://www.sciencedirect.com/science/article/pii/S0001868625001204?via%3Dihub},
   volume = {342},
   year = {2025}
}

TY  - JOUR
ID  - 2508035
AU  - Adegoke, Kayode Adesina - Okeke, Emmanuel Sunday - Omotola, Elizabeth Oyinkansola - Ohoro, Chinemerem Ruth - Amaku, James F. - Conradie, Jeanet - Olisah, Chijioke - Akpomie, Kovo G. - Malloum, Alhadji - Akpotu, Samson O.
PY  - 2025
TI  - Porous MIL, ZIF, and UiO metal-organic frameworks for adsorption of pharmaceuticals and personal care products
JF  - Advances in Colloid and Interface Science
VL  - 342
IS  - August 2025
SP  - 1-38
EP  - 1-38
PB  - Elsevier B.V.
SN  - 00018686
KW  - Emerging pollutants
KW  - Pharmaceuticals and personal care products
KW  - Adsorption
KW  - Wastewater
KW  - Metal-organic frameworks
UR  - https://www.sciencedirect.com/science/article/pii/S0001868625001204?via%3Dihub
N2  - Pharmaceuticals and personal care products (PPCPs) are a newly identified category of emerging global pollutants often found in aquatic systems. Efficient removal of these pollutants from the water/wastewater is currently problematic because of their low biodegradability and high hydrophilicity, as well as their distinct physicochemical features and lower concentrations. Materials of Institut Lavoisier (MIL), Zeolitic imidazolate framework (ZIF), and University of Oslo (UiO) are highly engineered metal-organic frameworks (MOFs) composed of unique components necessary for the formation of crystals with exceptional porosity, large surface areas, large pore sizes, crystalline structures, tunable properties, excellent chemical and thermal stability for environmental remediation. This study provides detailed and combined applications of UiOs, MILs, and ZIFs as adsorbents for capturing the new class of emerging pollutants (PPCPs) from the liquid phase. MOFs as ideal candidates for PPCP decontamination were discussed, followed by the MOF porosity and factors that affect MOF stability. Various synthetic approaches for MILs, ZIFs, and UiOs were discussed, as well as their corresponding pros and cons. An in-depth performance of these three MOFs for adsorptive removal of PPCPs from the liquid phase was discussed, assessing the state-of-the-art for specific applications and the effectiveness of UiOs, MILs, and ZIFs as adsorbents for PPCP decontamination . The unique performance garnered from the study provided a way forward/potential for real-life/practical applications of these sorbents and insight into corresponding mechanisms and synergistic relationships. To foster the advancement of the field, viable shortcomings and strengths associated with these novel classes of MOFs, treatment options, and knowledge gaps to explore specific research directives for large-scale or industrial-scale applications were highlighted.
ER  -

ADEGOKE, Kayode Adesina; Emmanuel Sunday OKEKE; Elizabeth Oyinkansola OMOTOLA; Chinemerem Ruth OHORO; James F. AMAKU; Jeanet CONRADIE; Chijioke OLISAH; Kovo G. AKPOMIE; Alhadji MALLOUM a Samson O. AKPOTU. Porous MIL, ZIF, and UiO metal-organic frameworks for adsorption of pharmaceuticals and personal care products. \textit{Advances in Colloid and Interface Science}. Elsevier B.V., 2025, roč.~342, August 2025, s.~1-38. ISSN~0001-8686. Dostupné z: https://doi.org/10.1016/j.cis.2025.103509.

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