Manuelarossiite, CaPbAlF7, a new fluoride from the Vesuvius
volcano, Italy

J 2025

Manuelarossiite, CaPbAlF7, a new fluoride from the Vesuvius volcano, Italy

NESTOLA, Fabrizio; Anatoly V KASATKIN; Cristian BIAGIONI; Vladislav V GURZHIY; Radek ŠKODA et al.

Základní údaje

Originální název

Manuelarossiite, CaPbAlF7, a new fluoride from the Vesuvius volcano, Italy

Autoři

NESTOLA, Fabrizio; Anatoly V KASATKIN; Cristian BIAGIONI; Vladislav V GURZHIY; Radek ŠKODA; Lisa SANTELLO a Atali A AGAKHANOV

Vydání

Mineralogical Magazine, Cambridge University Press, 2025, 0026-461X

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10504 Mineralogy

Stát vydavatele

Velká Británie a Severní Irsko

Utajení

není předmětem státního či obchodního tajemství

Odkazy

URL

Impakt faktor

Impact factor: 1.400 v roce 2024

Označené pro přenos do RIV

Ano

Organizační jednotka

Přírodovědecká fakulta

Klíčová slova anglicky

manuelarossiite; fluoride; Raman spectroscopy; crystal structure; 1944 eruption; Vesuvius volcano; Italy

Štítky

14315010, rivok

Příznaky

Mezinárodní význam, Recenzováno

Změněno: 8. 9. 2025 11:40, Mgr. Marie Novosadová Šípková, DiS.

Anotace

V originále

Manuelarossiite, ideally CaPbAlF7, is a new fluoride mineral found in a specimen from a fumarole formed subsequent to the 1944 eruption of the Vesuvius volcano, Naples Province, Campania, Italy. It occurs as very rare tabular crystals, up to 0.06 × 0.04 × 0.015 mm, in the vugs of volcanic scoria, associated with cerussite. In the same scoria where manuelarossiite was found, anglesite, artroeite, atacamite, calcioaravaipaite, cerussite, challacolloite, cotunnite, hephaistosite, matlockite, napoliite and susannite were identified. Manuelarossiite is colourless with a white streak and adamantine lustre. It is brittle and has a laminated fracture. Cleavage is perfect on {001}. Dcalc = 5.095 g cm–3. The calculated mean refractive index is 1.625. The chemical composition (wt.%, electron microprobe, H2O calculated by stoichiometry) is: CaO 13.98, PbO 55.46, Al2O3 12.59, F 29.45, H2O 1.68, –O=F –12.40, total 100.76. The empirical formula calculated on the basis of 7 anions is Ca1.00Pb1.00Al1.00[F6.25(OH)0.75]Σ7.00. Raman spectroscopy confirms the limited presence of OH– groups in the mineral. Manuelarossiite is monoclinic, space group C2/m, with a = 7.6754(3), b = 7.4443(4), c = 9.2870(5) Å, β = 93.928(5)°, V = 529.39(5) Å3 and Z = 4. The strongest lines of the powder X-ray diffraction pattern [d, Å (I, %) (hkl)] are: 9.257 (57) (001); 4.537 (72) (111); 3.725 (98) (020); 3.630 (57) (20); 3.588 (65) (11); 3.460 (100) (021); 3.422 (63) (112); and 2.673 (65) (220). The crystal structure was refined to R1 = 0.056 for 849 reflections with F > 4σ(F). It is characterised by {001} layers formed by CaF8 polyhedra decorated on both sides by AlF6 octahedra, in turn connected to the {001} layer through edge-sharing. Successive {001} layers are bonded through Pb atoms. The new mineral honours Dr. Manuela Rossi (b. 1977) from the University of Naples for her contribution to the study of the Vesuvius volcano and its minerals.

Citovat

NESTOLA, Fabrizio; Anatoly V KASATKIN; Cristian BIAGIONI; Vladislav V GURZHIY; Radek ŠKODA; Lisa SANTELLO a Atali A AGAKHANOV. Manuelarossiite, CaPbAlF7, a new fluoride from the Vesuvius volcano, Italy. Mineralogical Magazine. Cambridge University Press, 2025, roč. 89, č. 1, s. 133-140. ISSN 0026-461X. Dostupné z: https://doi.org/10.1180/mgm.2024.59.

@article{2516622,
   author = {Nestola, Fabrizio and Kasatkin, Anatoly V and Biagioni, Cristian and Gurzhiy, Vladislav V and Škoda, Radek and Santello, Lisa and Agakhanov, Atali A},
   article_number = {1},
   doi = {https://doi.org/10.1180/mgm.2024.59},
   keywords = {manuelarossiite; fluoride; Raman spectroscopy; crystal structure; 1944 eruption; Vesuvius volcano; Italy},
   language = {eng},
   issn = {0026-461X},
   journal = {Mineralogical Magazine},
   title = {Manuelarossiite, CaPbAlF7, a new fluoride from the Vesuvius volcano, Italy},
   url = {https://doi.org/10.1180/mgm.2024.59},
   volume = {89},
   year = {2025}
}

TY  - JOUR
ID  - 2516622
AU  - Nestola, Fabrizio - Kasatkin, Anatoly V - Biagioni, Cristian - Gurzhiy, Vladislav V - Škoda, Radek - Santello, Lisa - Agakhanov, Atali A
PY  - 2025
TI  - Manuelarossiite, CaPbAlF7, a new fluoride from the Vesuvius volcano, Italy
JF  - Mineralogical Magazine
VL  - 89
IS  - 1
SP  - 133-140
EP  - 133-140
PB  - Cambridge University Press
SN  - 0026461X
KW  - manuelarossiite
KW  - fluoride
KW  - Raman spectroscopy
KW  - crystal structure
KW  - 1944 eruption
KW  - Vesuvius volcano
KW  - Italy
UR  - https://doi.org/10.1180/mgm.2024.59
N2  - Manuelarossiite, ideally CaPbAlF7, is a new fluoride mineral found in a specimen from a fumarole formed subsequent to the 1944 eruption of the Vesuvius volcano, Naples Province, Campania, Italy. It occurs as very rare tabular crystals, up to 0.06 × 0.04 × 0.015 mm, in the vugs of volcanic scoria, associated with cerussite. In the same scoria where manuelarossiite was found, anglesite, artroeite, atacamite, calcioaravaipaite, cerussite, challacolloite, cotunnite, hephaistosite, matlockite, napoliite and susannite were identified. Manuelarossiite is colourless with a white streak and adamantine lustre. It is brittle and has a laminated fracture. Cleavage is perfect on {001}. Dcalc = 5.095 g cm–3. The calculated mean refractive index is 1.625. The chemical composition (wt.%, electron microprobe, H2O calculated by stoichiometry) is: CaO 13.98, PbO 55.46, Al2O3 12.59, F 29.45, H2O 1.68, –O=F –12.40, total 100.76. The empirical formula calculated on the basis of 7 anions is Ca1.00Pb1.00Al1.00[F6.25(OH)0.75]Σ7.00. Raman spectroscopy confirms the limited presence of OH– groups in the mineral. Manuelarossiite is monoclinic, space group C2/m, with a = 7.6754(3), b = 7.4443(4), c = 9.2870(5) Å, β = 93.928(5)°, V = 529.39(5) Å3 and Z = 4. The strongest lines of the powder X-ray diffraction pattern [d, Å (I, %) (hkl)] are: 9.257 (57) (001); 4.537 (72) (111); 3.725 (98) (020); 3.630 (57) (20); 3.588 (65) (11); 3.460 (100) (021); 3.422 (63) (112); and 2.673 (65) (220). The crystal structure was refined to R1 = 0.056 for 849 reflections with F > 4σ(F). It is characterised by {001} layers formed by CaF8 polyhedra decorated on both sides by AlF6 octahedra, in turn connected to the {001} layer through edge-sharing. Successive {001} layers are bonded through Pb atoms. The new mineral honours Dr. Manuela Rossi (b. 1977) from the University of Naples for her contribution to the study of the Vesuvius volcano and its minerals.
ER  -

NESTOLA, Fabrizio; Anatoly V KASATKIN; Cristian BIAGIONI; Vladislav V GURZHIY; Radek ŠKODA; Lisa SANTELLO a Atali A AGAKHANOV. Manuelarossiite, CaPbAlF7, a new fluoride from the Vesuvius volcano, Italy. \textit{Mineralogical Magazine}. Cambridge University Press, 2025, roč.~89, č.~1, s.~133-140. ISSN~0026-461X. Dostupné z: https://doi.org/10.1180/mgm.2024.59.

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