Carbon nitride boosts the CO2 methanation activity of Ni/CeO2

J 2025

Carbon nitride boosts the CO2 methanation activity of Ni/CeO2

ZHAO, Yingrui; Plaifa HONGMANOROM; Feilong YANG; Sandra CASALE; Capucine SASSOYE et al.

Základní údaje

Originální název

Carbon nitride boosts the CO2 methanation activity of Ni/CeO2

Autoři

ZHAO, Yingrui; Plaifa HONGMANOROM; Feilong YANG; Sandra CASALE; Capucine SASSOYE; Aleš STÝSKALÍK a Damien P. DEBECKER

Vydání

JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING, London, ELSEVIER SCI LTD, 2025, 2213-2929

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10402 Inorganic and nuclear chemistry

Stát vydavatele

Velká Británie a Severní Irsko

Utajení

není předmětem státního či obchodního tajemství

Odkazy

URL

Impakt faktor

Impact factor: 7.200 v roce 2024

Označené pro přenos do RIV

Ano

Kód RIV

RIV/00216224:14310/25:00142962

Organizační jednotka

Přírodovědecká fakulta

Klíčová slova anglicky

C3N4; Ceria; Nickel; Methane; CO2 hydrogenation

Štítky

14313010, CF NMR, rivok

Příznaky

Mezinárodní význam, Recenzováno

Změněno: 13. 3. 2026 08:13, Mgr. Marie Novosadová Šípková, DiS.

Anotace

V originále

Selective CO2 methanation using green H-2 offers a promising approach for tackling both energy and environmental challenges. Herein, a Ni/CeO2 catalyst was synthesized using a one-pot method in the presence of sacrificial C3N4 and evaluated for COQ methanation. The catalyst exhibited a high CO2 conversion of 82.6 % and a CH4 production rate of up to 178 mmol g(cat)(-1) h(-1), with high CH4 selectivity (99.4 %) at a remarkably low temperature of 250 degrees C. Surface characterization techniques, including Raman spectroscopy, XPS, P-31-MAS NMR of adsorbed trimethylphosphine, and CO2-TPD, demonstrate that the addition of C3N4 significantly enhanced the concentration of surface oxygen vacancies and medium-strength basic sites. In situ DRIFTS analysis indicated that CO2 methanation over Ni/CeO2 proceeded via the RWGS+CO hydrogenation and formate pathways, with the former being predominant at low temperatures. The exceptional low-temperature methanation performance of this new catalyst is attributed to the increased density of oxygen vacancies and medium-strength basic sites.

Návaznosti

EH23_015/0008175, projekt VaV

Název: Inovace České infrastruktury pro integrativní strukturní biologii

90242, velká výzkumná infrastruktura

Název: CIISB III

Citovat

ZHAO, Yingrui; Plaifa HONGMANOROM; Feilong YANG; Sandra CASALE; Capucine SASSOYE; Aleš STÝSKALÍK a Damien P. DEBECKER. Carbon nitride boosts the CO2 methanation activity of Ni/CeO2. JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING. London: ELSEVIER SCI LTD, 2025, roč. 13, č. 6, s. 1-10. ISSN 2213-2929. Dostupné z: https://doi.org/10.1016/j.jece.2025.119153.

@article{2541315,
   author = {Zhao, Yingrui and Hongmanorom, Plaifa and Yang, Feilong and Casale, Sandra and Sassoye, Capucine and Stýskalík, Aleš and Debecker, Damien P.},
   article_location = {London},
   article_number = {6},
   doi = {https://doi.org/10.1016/j.jece.2025.119153},
   keywords = {C3N4; Ceria; Nickel; Methane; CO2 hydrogenation},
   language = {eng},
   issn = {2213-2929},
   journal = {JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING},
   title = {Carbon nitride boosts the CO2 methanation activity of Ni/CeO2},
   url = {https://www.sciencedirect.com/science/article/pii/S2213343725038497?via%3Dihub#ack0005},
   volume = {13},
   year = {2025}
}

TY  - JOUR
ID  - 2541315
AU  - Zhao, Yingrui - Hongmanorom, Plaifa - Yang, Feilong - Casale, Sandra - Sassoye, Capucine - Stýskalík, Aleš - Debecker, Damien P.
PY  - 2025
TI  - Carbon nitride boosts the CO2 methanation activity of Ni/CeO2
JF  - JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
VL  - 13
IS  - 6
SP  - 1-10
EP  - 1-10
PB  - ELSEVIER SCI LTD
SN  - 22132929
KW  - C3N4
KW  - Ceria
KW  - Nickel
KW  - Methane
KW  - CO2 hydrogenation
UR  - https://www.sciencedirect.com/science/article/pii/S2213343725038497?via%3Dihub#ack0005
N2  - Selective CO2 methanation using green H-2 offers a promising approach for tackling both energy and environmental challenges. Herein, a Ni/CeO2 catalyst was synthesized using a one-pot method in the presence of sacrificial C3N4 and evaluated for COQ methanation. The catalyst exhibited a high CO2 conversion of 82.6 % and a CH4 production rate of up to 178 mmol g(cat)(-1) h(-1), with high CH4 selectivity (99.4 %) at a remarkably low temperature of 250 degrees C. Surface characterization techniques, including Raman spectroscopy, XPS, P-31-MAS NMR of adsorbed trimethylphosphine, and CO2-TPD, demonstrate that the addition of C3N4 significantly enhanced the concentration of surface oxygen vacancies and medium-strength basic sites. In situ DRIFTS analysis indicated that CO2 methanation over Ni/CeO2 proceeded via the RWGS+CO hydrogenation and formate pathways, with the former being predominant at low temperatures. The exceptional low-temperature methanation performance of this new catalyst is attributed to the increased density of oxygen vacancies and medium-strength basic sites.
ER  -

ZHAO, Yingrui; Plaifa HONGMANOROM; Feilong YANG; Sandra CASALE; Capucine SASSOYE; Aleš STÝSKALÍK a Damien P. DEBECKER. Carbon nitride boosts the CO2 methanation activity of Ni/CeO2. \textit{JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING}. London: ELSEVIER SCI LTD, 2025, roč.~13, č.~6, s.~1-10. ISSN~2213-2929. Dostupné z: https://doi.org/10.1016/j.jece.2025.119153.

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