Neyite from the Yugo-Konevo Deposit (Southern Urals, Russia)
and Its Crystal Structure

J 2025

Neyite from the Yugo-Konevo Deposit (Southern Urals, Russia) and Its Crystal Structure

KORNYAKOV, I. V.; A. V. KASATKIN; V. V. GURZHIY; Radek ŠKODA; A. M. KUZNETSOV et al.

Základní údaje

Originální název

Neyite from the Yugo-Konevo Deposit (Southern Urals, Russia) and Its Crystal Structure

Autoři

KORNYAKOV, I. V.; A. V. KASATKIN; V. V. GURZHIY; Radek ŠKODA a A. M. KUZNETSOV

Vydání

GEOLOGY OF ORE DEPOSITS, TORTOLA, PLEIADES PUBLISHING LTD, 2025, 1075-7015

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10504 Mineralogy

Stát vydavatele

Spojené státy

Utajení

není předmětem státního či obchodního tajemství

Odkazy

URL

Impakt faktor

Impact factor: 0.600 v roce 2024

Označené pro přenos do RIV

Ano

Kód RIV

RIV/00216224:14310/25:00143731

Organizační jednotka

Přírodovědecká fakulta

Klíčová slova anglicky

neyite; optical data; chemical composition; crystal structure; Yugo-Konevo tungsten deposit; Southern Urals; first find in Russia

Štítky

14315010, rivok

Příznaky

Mezinárodní význam, Recenzováno

Změněno: 23. 2. 2026 11:13, Mgr. Marie Novosadová Šípková, DiS.

Anotace

V originále

Neyite Ag2Cu6Pb25Bi26S68 was identified in the wastes of the Yugo-Konevo tungsten deposit (Chelyabinsk oblast, Southern Urals) for a first time in Russia. This rare sulfosalt occurs as prismatic crystals up to 3 × 0.5 mm in fluorite–muscovite–quartz veins and is associated with aikinite, tetradymite, and pyrite. Reflectance spectra and coefficients of neyite are published for the first time. The electron microprobe composition of neyite (wt %, mean of seven analyses): Ag 1.75, Cu 3.59, Pb 35.01, Cd 0.12, Bi 42.59, S16.54, total 99.60. The empirical formula based on S = 68 apfu is Ag2.14Cu7.45Pb22.27Cd0.14Bi26.86S68. The crystal structure of neyite from Yugo-Konevo was refined based on the monocrystal, R1 = 3.43%, wR2 = 7.22%. The mineral is monoclinic, space group С2/m, a = 37.3900(6), b = 4.05500(10), c = 43.5821(7) Å, β = 108.740(2)°, V = 6257.5(2) Å3, Z = 2. The structure of neyite is based upon three different modules of archetypal structure of galena. (111)PbS blocks make up octahedral “columns” extended along the b direction, which alternate with (100)PbS blocks in the a direction. The resulting layers are alternated with (922)PbS layers along c. The main structural feature of neyite from Yugo-Konevo deposit that distinguishes it from previously described neyite from the type locality and cuproneyite is the disorder of the Me16 position and the presence of the additional Cu5 position. These features, along with analysis of the bond valence sums, suggest the presence of chains of CuS4 tetrahedra alternating with chains of BiS6 octahedra.

Citovat

KORNYAKOV, I. V.; A. V. KASATKIN; V. V. GURZHIY; Radek ŠKODA a A. M. KUZNETSOV. Neyite from the Yugo-Konevo Deposit (Southern Urals, Russia) and Its Crystal Structure. GEOLOGY OF ORE DEPOSITS. TORTOLA: PLEIADES PUBLISHING LTD, 2025, roč. 67, č. 8, s. 1209-1227. ISSN 1075-7015. Dostupné z: https://doi.org/10.1134/S1075701525700205.

@article{2556188,
   author = {Kornyakov, I. V. and Kasatkin, A. V. and Gurzhiy, V. V. and Škoda, Radek and Kuznetsov, A. M.},
   article_location = {TORTOLA},
   article_number = {8},
   doi = {https://doi.org/10.1134/S1075701525700205},
   keywords = {neyite; optical data; chemical composition; crystal structure; Yugo-Konevo tungsten deposit; Southern Urals; first find in Russia},
   language = {eng},
   issn = {1075-7015},
   journal = {GEOLOGY OF ORE DEPOSITS},
   title = {Neyite from the Yugo-Konevo Deposit (Southern Urals, Russia) and Its Crystal Structure},
   url = {https://link.springer.com/article/10.1134/S1075701525700205},
   volume = {67},
   year = {2025}
}

TY  - JOUR
ID  - 2556188
AU  - Kornyakov, I. V. - Kasatkin, A. V. - Gurzhiy, V. V. - Škoda, Radek - Kuznetsov, A. M.
PY  - 2025
TI  - Neyite from the Yugo-Konevo Deposit (Southern Urals, Russia) and Its Crystal Structure
JF  - GEOLOGY OF ORE DEPOSITS
VL  - 67
IS  - 8
SP  - 1209-1227
EP  - 1209-1227
PB  - PLEIADES PUBLISHING LTD
SN  - 10757015
KW  - neyite
KW  - optical data
KW  - chemical composition
KW  - crystal structure
KW  - Yugo-Konevo tungsten deposit
KW  - Southern Urals
KW  - first find in Russia
UR  - https://link.springer.com/article/10.1134/S1075701525700205
N2  - Neyite Ag2Cu6Pb25Bi26S68 was identified in the wastes of the Yugo-Konevo tungsten deposit (Chelyabinsk oblast, Southern Urals) for a first time in Russia. This rare sulfosalt occurs as prismatic crystals up to 3 × 0.5 mm in fluorite–muscovite–quartz veins and is associated with aikinite, tetradymite, and pyrite. Reflectance spectra and coefficients of neyite are published for the first time. The electron microprobe composition of neyite (wt %, mean of seven analyses): Ag 1.75, Cu 3.59, Pb 35.01, Cd 0.12, Bi 42.59, S16.54, total 99.60. The empirical formula based on S = 68 apfu is Ag2.14Cu7.45Pb22.27Cd0.14Bi26.86S68. The crystal structure of neyite from Yugo-Konevo was refined based on the monocrystal, R1 = 3.43%, wR2 = 7.22%. The mineral is monoclinic, space group С2/m, a = 37.3900(6), b = 4.05500(10), c = 43.5821(7) Å, β = 108.740(2)°, V = 6257.5(2) Å3, Z = 2. The structure of neyite is based upon three different modules of archetypal structure of galena. (111)PbS blocks make up octahedral “columns” extended along the b direction, which alternate with (100)PbS blocks in the a direction. The resulting layers are alternated with (922)PbS layers along c. The main structural feature of neyite from Yugo-Konevo deposit that distinguishes it from previously described neyite from the type locality and cuproneyite is the disorder of the Me16 position and the presence of the additional Cu5 position. These features, along with analysis of the bond valence sums, suggest the presence of chains of CuS4 tetrahedra alternating with chains of BiS6 octahedra.
ER  -

KORNYAKOV, I. V.; A. V. KASATKIN; V. V. GURZHIY; Radek ŠKODA a A. M. KUZNETSOV. Neyite from the Yugo-Konevo Deposit (Southern Urals, Russia) and Its Crystal Structure. \textit{GEOLOGY OF ORE DEPOSITS}. TORTOLA: PLEIADES PUBLISHING LTD, 2025, roč.~67, č.~8, s.~1209-1227. ISSN~1075-7015. Dostupné z: https://doi.org/10.1134/S1075701525700205.

Přehled o publikaci