Application of Elimination Voltammetry to the Electroanalysis
of an Adsorbed Substance

D 2000

Application of Elimination Voltammetry to the Electroanalysis of an Adsorbed Substance

TRNKOVÁ, Libuše; René KIZEK a Oldřich DRAČKA

Základní údaje

Originální název

Application of Elimination Voltammetry to the Electroanalysis of an Adsorbed Substance

Autoři

TRNKOVÁ, Libuše; René KIZEK a Oldřich DRAČKA

Vydání

Band/Volume22. Bonn, Electroanalysis ESEAC 2000 SEAC, od s. D 27, 1 s. Reihe Umwelt/Environment, 2000

Nakladatel

Rheinische-Friedrich-Wilhelms-Universitaet Bonn

Další údaje

Jazyk

angličtina

Typ výsledku

Stať ve sborníku

Obor

10405 Electrochemistry

Stát vydavatele

Německo

Utajení

není předmětem státního či obchodního tajemství

Označené pro přenos do RIV

Ano

Kód RIV

RIV/00216224:14310/00:00003067

Organizační jednotka

Přírodovědecká fakulta

ISBN

3-89336-261-4

Klíčová slova anglicky

Linear scan voltammetry; Elimination voltammetry; Adsorption

Štítky

adsorption, Elimination voltammetry, Linear scan voltammetry

Změněno: 12. 3. 2001 16:49, prof. RNDr. Libuše Trnková, CSc.

Anotace

V originále

In the elimination voltammetry with a linear scan rate (EVLS), elimination of the selected particular currents from the linear scan voltammetry results is achieved by an elimination function formed by a linear combination of the total currents measured at different scan rates.Theoretical curves of an irreversible current with adsorbed substance being electroactive were calculated for three elimination functions: A - the function eliminating Ik and Ic and conserving Ir , B - the function eliminating Ic and Ir , conserving Ik , and C - the function eliminating Ir and Ik and conserving Ic, where Ic , Ir , and Ik are the charging current, the reversible diffusion current, and the kinetic current, respectively. A larger difference between diffusion and adsorption was exhibited by the elimination function A. It provides a substantial increase in resolution and sensitivity as compared to the linear scan voltammetry current peak and clearly marks the adsorption.

Návaznosti

GV204/97/K084, projekt VaV

Název: Elektrody modifikované nukleovými kyselinami a bílkovinami. Nové nástroje v biochemickém a biomedicínském výzkumu

Investor: Grantová agentura ČR, Elektrody modifikované nukleovými kyselinami a bílkovinami. Nové nástroje v biochemickém a biomedicínském výzkumu

MSM 143100011, záměr

Název: Struktura a vazebné poměry, vlastnosti a analýza syntetických a přírodních molekulových ansamblů

Investor: Ministerstvo školství, mládeže a tělovýchovy ČR, Struktura a vazebné poměry, vlastnosti a analýza syntetických a přírodních molekulových ansamblů

Citovat

TRNKOVÁ, Libuše; René KIZEK a Oldřich DRAČKA. Application of Elimination Voltammetry to the Electroanalysis of an Adsorbed Substance. In Electroanalysis ESEAC 2000 SEAC. Band/Volume22. Bonn: Rheinische-Friedrich-Wilhelms-Universitaet Bonn, 2000, s. D 27, 1 s. Reihe Umwelt/Environment. ISBN 3-89336-261-4.

@inproceedings{325692,
   author = {Trnková, Libuše and Kizek, René and Dračka, Oldřich},
   address = {Bonn},
   booktitle = {Electroanalysis ESEAC 2000 SEAC},
   edition = {Band/Volume22},
   keywords = {Linear scan voltammetry; Elimination voltammetry; Adsorption},
   language = {eng},
   location = {Bonn},
   isbn = {3-89336-261-4},
   pages = {D 27},
   publisher = {Rheinische-Friedrich-Wilhelms-Universitaet Bonn},
   title = {Application of Elimination Voltammetry to the Electroanalysis of an Adsorbed Substance},
   year = {2000}
}

TY  - CONF
ID  - 325692
AU  - Trnková, Libuše - Kizek, René - Dračka, Oldřich
PY  - 2000
TI  - Application of Elimination Voltammetry to the Electroanalysis of an Adsorbed Substance
VL  - Reihe Umwelt/Environment
PB  - Rheinische-Friedrich-Wilhelms-Universitaet Bonn
CY  - Bonn
SN  - 3893362614
KW  - Linear scan voltammetry
KW  - Elimination voltammetry
KW  - Adsorption
N2  - In the elimination voltammetry with a linear scan rate (EVLS), elimination of the selected particular currents from the linear scan voltammetry results is achieved by an elimination function formed by a linear combination of the total currents measured at different scan rates.Theoretical curves of an irreversible current with adsorbed substance being electroactive were calculated for three elimination functions: A - the function eliminating Ik and Ic and conserving Ir , B - the function eliminating Ic and Ir , conserving Ik , and C - the function eliminating Ir and Ik and conserving Ic, where Ic , Ir , and Ik are the charging current, the reversible diffusion current, and the kinetic current, respectively. A larger difference between diffusion and adsorption was exhibited by the elimination function A. It provides a substantial increase in resolution and sensitivity as compared to the linear scan voltammetry current peak and clearly marks the adsorption.
ER  -

TRNKOVÁ, Libuše; René KIZEK a Oldřich DRAČKA. Application of Elimination Voltammetry to the Electroanalysis of an Adsorbed Substance. In \textit{Electroanalysis ESEAC 2000 SEAC}. Band/Volume22. Bonn: Rheinische-Friedrich-Wilhelms-Universitaet Bonn, 2000, s.~D 27, 1 s. Reihe Umwelt/Environment. ISBN~3-89336-261-4.

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