Synthesis and Structural Characterization of Functionalized
Dimeric Aluminophosphonates and a Monomeric Gallophosphonate
Anion

J 2001

Synthesis and Structural Characterization of Functionalized Dimeric Aluminophosphonates and a Monomeric Gallophosphonate Anion

CHAKRABORTY, Debashis; Sabine HORCHLER; Ralph KRÄTZNER; Saji P. VARKEY; Jiří PINKAS et. al.

Základní údaje

Originální název

Synthesis and Structural Characterization of Functionalized Dimeric Aluminophosphonates and a Monomeric Gallophosphonate Anion

Autoři

CHAKRABORTY, Debashis; Sabine HORCHLER; Ralph KRÄTZNER; Saji P. VARKEY; Jiří PINKAS; Herbert W. ROESKY; Isabel USÓN; Mathias NOLTEMEYER a Hans-Georg SCHMIDT

Vydání

Inorg. Chem. Spojené státy americké, American Chemical Society, Washington DC, 2001, 0020-1669

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10402 Inorganic and nuclear chemistry

Stát vydavatele

Spojené státy

Utajení

není předmětem státního či obchodního tajemství

Impakt faktor

Impact factor: 2.946

Kód RIV

RIV/00216224:14310/01:00004222

Organizační jednotka

Přírodovědecká fakulta

Klíčová slova anglicky

CRYSTAL-STRUCTURE; MOLECULAR-SIEVES; MODEL-COMPOUND; ZEOLITE-Y; GALLIUM; CATALYST;

Štítky

CATALYST, CRYSTAL-STRUCTURE, gallium, MODEL-COMPOUND, MOLECULAR-SIEVES, ZEOLITE-Y

Změněno: 15. 8. 2001 12:59, prof. RNDr. Jiří Pinkas, Ph.D.

Anotace

V originále

Reaction of t-BuP(O)(OSiMe3)(OH) with Me3Al leads to the formation of [Me2Al(mu -O)(2)P(OSiMe3)(t-Bu)](2) (1) whereas Me2AlCl reacts with Ph2P(O)(OH) to yield [(Cl)(Me)Al(mu -O)(2)PPh2](2) (2). These compounds represent the first examples of functionalized dimeric four-ring type aluminophosphonate systems. The double four-ring type gallophosphonate, namely, [t-BuPO3GaMe](4), reacts with n-Bu4NHF2 under ambient conditions, resulting in the formation of a monomeric gallophosphonate [n-Bu4N][MeGa(t-BuPO2(OH))(3)] (3) These derivatives have been adequately characterized using various spectroscopic techniques and X-ray diffraction studies.

Návaznosti

GA203/01/1533, projekt VaV

Název: Nové bezvodé metody přípravy fosfátových, silikátových, hybridních a oxidických materiálů

Investor: Grantová agentura ČR, Nové bezvodé metody přípravy fosfátových, silikátových, hybridních a oxidických materiálů

Citovat

CHAKRABORTY, Debashis; Sabine HORCHLER; Ralph KRÄTZNER; Saji P. VARKEY; Jiří PINKAS; Herbert W. ROESKY; Isabel USÓN; Mathias NOLTEMEYER a Hans-Georg SCHMIDT. Synthesis and Structural Characterization of Functionalized Dimeric Aluminophosphonates and a Monomeric Gallophosphonate Anion. Inorg. Chem. Spojené státy americké: American Chemical Society, Washington DC, 2001, roč. 40, č. 11, s. 2620-2624. ISSN 0020-1669.

@article{362632,
   author = {Chakraborty, Debashis and Horchler, Sabine and Krätzner, Ralph and Varkey, Saji P. and Pinkas, Jiří and Roesky, Herbert W. and Usón, Isabel and Noltemeyer, Mathias and Schmidt, HansandGeorg},
   article_location = {Spojené státy americké},
   article_number = {11},
   keywords = {CRYSTAL-STRUCTURE; MOLECULAR-SIEVES; MODEL-COMPOUND; ZEOLITE-Y; GALLIUM; CATALYST;},
   language = {eng},
   issn = {0020-1669},
   journal = {Inorg. Chem.},
   title = {Synthesis and Structural Characterization of Functionalized Dimeric Aluminophosphonates and a Monomeric Gallophosphonate Anion},
   volume = {40},
   year = {2001}
}

TY  - JOUR
ID  - 362632
AU  - Chakraborty, Debashis - Horchler, Sabine - Krätzner, Ralph - Varkey, Saji P. - Pinkas, Jiří - Roesky, Herbert W. - Usón, Isabel - Noltemeyer, Mathias - Schmidt, Hans-Georg
PY  - 2001
TI  - Synthesis and Structural Characterization of Functionalized Dimeric Aluminophosphonates and a Monomeric Gallophosphonate Anion
JF  - Inorg. Chem.
VL  - 40
IS  - 11
SP  - 2620
EP  - 2620
PB  - American Chemical Society, Washington DC
SN  - 00201669
KW  - CRYSTAL-STRUCTURE
KW  - MOLECULAR-SIEVES
KW  - MODEL-COMPOUND
KW  - ZEOLITE-Y
KW  - GALLIUM
KW  - CATALYST;
N2  - Reaction of t-BuP(O)(OSiMe3)(OH) with Me3Al leads to the formation of [Me2Al(mu -O)(2)P(OSiMe3)(t-Bu)](2) (1) whereas Me2AlCl reacts with Ph2P(O)(OH) to yield [(Cl)(Me)Al(mu -O)(2)PPh2](2) (2). These compounds represent the first examples of functionalized dimeric four-ring type aluminophosphonate systems. The double four-ring type gallophosphonate, namely, [t-BuPO3GaMe](4), reacts with n-Bu4NHF2 under ambient conditions, resulting in the formation of a monomeric gallophosphonate [n-Bu4N][MeGa(t-BuPO2(OH))(3)] (3) These derivatives have been adequately characterized using various spectroscopic techniques and X-ray diffraction studies.
ER  -

CHAKRABORTY, Debashis; Sabine HORCHLER; Ralph KRÄTZNER; Saji P. VARKEY; Jiří PINKAS; Herbert W. ROESKY; Isabel USÓN; Mathias NOLTEMEYER a Hans-Georg SCHMIDT. Synthesis and Structural Characterization of Functionalized Dimeric Aluminophosphonates and a Monomeric Gallophosphonate Anion. \textit{Inorg. Chem.}. Spojené státy americké: American Chemical Society, Washington DC, 2001, roč.~40, č.~11, s.~2620-2624. ISSN~0020-1669.

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