The synthesis and characterisation of
bis(diisopropylphosphoryl)ferrocene Fe[(C5H4)P(O)i-Pr2]2,
bis(diisopropylthiophosphoryl)ferrocene Fe[(C5H4)P(S)i-Pr2]2
and bis(diisopropylselenophosphoryl)ferrocene
Fe[(C5H4)P(Se)i-Pr2]2

J 2001

The synthesis and characterisation of bis(diisopropylphosphoryl)ferrocene Fe[(C5H4)P(O)i-Pr2]2, bis(diisopropylthiophosphoryl)ferrocene Fe[(C5H4)P(S)i-Pr2]2 and bis(diisopropylselenophosphoryl)ferrocene Fe[(C5H4)P(Se)i-Pr2]2

NEČAS, Marek, Martin BERAN, John Derek WOOLLINS a Josef NOVOSAD

Základní údaje

Originální název

The synthesis and characterisation of bis(diisopropylphosphoryl)ferrocene Fe[(C5H4)P(O)i-Pr2]2, bis(diisopropylthiophosphoryl)ferrocene Fe[(C5H4)P(S)i-Pr2]2 and bis(diisopropylselenophosphoryl)ferrocene Fe[(C5H4)P(Se)i-Pr2]2

Autoři

NEČAS, Marek (203 Česká republika), Martin BERAN (203 Česká republika), John Derek WOOLLINS a Josef NOVOSAD (203 Česká republika, garant)

Vydání

Polyhedron, Oxford, UK, PERGAMON-ELSEVIER SCIENCE LTD, 2001, 0277-5387

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10402 Inorganic and nuclear chemistry

Stát vydavatele

Velká Británie a Severní Irsko

Utajení

není předmětem státního či obchodního tajemství

Impakt faktor

Impact factor: 1.200

Kód RIV

RIV/00216224:14310/01:00004261

Organizační jednotka

Přírodovědecká fakulta

UT WoS

000169075700023

Klíčová slova anglicky

diphosphino ligands; chalcogens; ferrocene; X-ray crystallography

Štítky

chalcogens, diphosphino ligands, ferrocene, X-ray crystallography

Změněno: 25. 6. 2009 11:58, doc. Mgr. Marek Nečas, Ph.D.

Anotace

V originále

The synthesis and spectroscopic characterisation of three chalcogenophosphoryl ligands derived from ferrocene is reported. The synthesis was based on the oxidation of Fe[(eta (5)-C5H4)P ' Pr-2](2) by elementary sulfur and selenium, and hydrogen peroxide, respectively. All new compounds were characterised by X-ray crystallography and comparison with their aryl analogues was made. Contrary to Fe[(eta(5)-C5H4)P(E)Ph-2](2) (E = O, S, Se), the prepared compounds are not centrosymmetric, with the iso-propyl groups showing more flexibility than the phenyl substituents.

Návaznosti

GA203/99/0067, projekt VaV

Název: Pronájem krystalografických databází

MSM 143100011, záměr

Název: Struktura a vazebné poměry, vlastnosti a analýza syntetických a přírodních molekulových ansamblů

Investor: Ministerstvo školství, mládeže a tělovýchovy ČR, Struktura a vazebné poměry, vlastnosti a analýza syntetických a přírodních molekulových ansamblů

Citovat

NEČAS, Marek, Martin BERAN, John Derek WOOLLINS a Josef NOVOSAD. The synthesis and characterisation of bis(diisopropylphosphoryl)ferrocene Fe[(C5H4)P(O)i-Pr2]2, bis(diisopropylthiophosphoryl)ferrocene Fe[(C5H4)P(S)i-Pr2]2 and bis(diisopropylselenophosphoryl)ferrocene Fe[(C5H4)P(Se)i-Pr2]2. Polyhedron. Oxford, UK: PERGAMON-ELSEVIER SCIENCE LTD, 2001, roč. 20, 7-8, s. 741-746. ISSN 0277-5387.

@article{365091,
   author = {Nečas, Marek and Beran, Martin and Woollins, John Derek and Novosad, Josef},
   article_location = {Oxford, UK},
   article_number = {7-8},
   keywords = {diphosphino ligands; chalcogens; ferrocene; X-ray crystallography},
   language = {eng},
   issn = {0277-5387},
   journal = {Polyhedron},
   title = {The synthesis and characterisation of bis(diisopropylphosphoryl)ferrocene Fe[(C5H4)P(O)i-Pr2]2, bis(diisopropylthiophosphoryl)ferrocene Fe[(C5H4)P(S)i-Pr2]2 and bis(diisopropylselenophosphoryl)ferrocene Fe[(C5H4)P(Se)i-Pr2]2},
   volume = {20},
   year = {2001}
}

TY  - JOUR
ID  - 365091
AU  - Nečas, Marek - Beran, Martin - Woollins, John Derek - Novosad, Josef
PY  - 2001
TI  - The synthesis and characterisation of bis(diisopropylphosphoryl)ferrocene Fe[(C5H4)P(O)i-Pr2]2, bis(diisopropylthiophosphoryl)ferrocene Fe[(C5H4)P(S)i-Pr2]2 and bis(diisopropylselenophosphoryl)ferrocene Fe[(C5H4)P(Se)i-Pr2]2
JF  - Polyhedron
VL  - 20
IS  - 7-8
SP  - 741
EP  - 741
PB  - PERGAMON-ELSEVIER SCIENCE LTD
SN  - 02775387
KW  - diphosphino ligands
KW  - chalcogens
KW  - ferrocene
KW  - X-ray crystallography
N2  - The synthesis and spectroscopic characterisation of three chalcogenophosphoryl ligands derived from ferrocene is reported. The synthesis was based on the oxidation of Fe[(eta (5)-C5H4)P ' Pr-2](2) by elementary sulfur and selenium, and hydrogen peroxide, respectively. All new compounds were characterised by X-ray crystallography and comparison with their aryl analogues was made. Contrary to Fe[(eta(5)-C5H4)P(E)Ph-2](2) (E = O, S, Se), the prepared compounds are not centrosymmetric, with the iso-propyl groups showing more flexibility than the phenyl substituents.
ER  -

NEČAS, Marek, Martin BERAN, John Derek WOOLLINS a Josef NOVOSAD. The synthesis and characterisation of bis(diisopropylphosphoryl)ferrocene Fe[(C5H4)P(O)i-Pr2]2, bis(diisopropylthiophosphoryl)ferrocene Fe[(C5H4)P(S)i-Pr2]2 and bis(diisopropylselenophosphoryl)ferrocene Fe[(C5H4)P(Se)i-Pr2]2. \textit{Polyhedron}. Oxford, UK: PERGAMON-ELSEVIER SCIENCE LTD, 2001, roč.~20, 7-8, s.~741-746. ISSN~0277-5387.

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