Calibration graphs for steels by IR laser ablation inductively
coupled plasma atomic emission spectrometry

J 2001

Calibration graphs for steels by IR laser ablation inductively coupled plasma atomic emission spectrometry

KANICKÝ, Viktor; Vítězslav OTRUBA; Karel NOVOTNÝ; Petr MUSIL; Jean-Michel MERMET et. al.

Základní údaje

Originální název

Calibration graphs for steels by IR laser ablation inductively coupled plasma atomic emission spectrometry

Autoři

KANICKÝ, Viktor; Vítězslav OTRUBA; Karel NOVOTNÝ; Petr MUSIL a Jean-Michel MERMET

Vydání

Fresenius Journal of Analytical Chemistry, Berlin, Springer-Verlag, 2001, 0937-0633

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10406 Analytical chemistry

Stát vydavatele

Německo

Utajení

není předmětem státního či obchodního tajemství

Impakt faktor

Impact factor: 1.649

Kód RIV

RIV/00216224:14310/01:00004314

Organizační jednotka

Přírodovědecká fakulta

UT WoS

000170115100012

Klíčová slova anglicky

Laser ablation; Infrared laser; Inductively coupled plasma; Atomic emission spectrometry; Steel; LINA

Štítky

atomic emission spectrometry, inductively coupled plasma, Infrared Laser, laser ablation, LinA, steel

Změněno: 28. 6. 2007 16:41, prof. RNDr. Viktor Kanický, DrSc.

Anotace

V originále

Infrared laser ablation (IR-LA) was studied as a sample introduction technique for the analysis of steels by inductively coupled plasma atomic emission spectrometry (ICP-AES).A comparison of two IR-LA-ICP-AES systems based on Q-switched nanosecond Nd:YAG lasers was performed. The beam of the Lina-SPARK Atomizer (LSA Sarl, Cully, Switzerland) based on the Surelite I-20 laser (Continuum, USA) was moved along a circle. A Perkin-Elmer Optima 3000 DV ICP system was used for emission measurement both with lateral and axial viewing modes. A laboratory-made ablation system based on the Brilliant laser (Quantel) was coupled to a Jobin-Yvon 170 Ultrace ICP (lateral viewing, polychromator part employed). A sample was rotated along a circle during ablation. Linearity of calibration plots was verified at least up to 19 % Cr and 12 % Ni without internal standardization for both LA-ICP-AES systems. Other elements were examined up to 3 % Mo, 1.5 % Mn, 1.7 % Si and 0.15 % Cu. The reproducibility was in the range 5 - 1 %RSD for a mass percentage 0.5 - 20 % of steel constituents. The relative uncertainty on centroid of a calibration line was in the range from ą 4% to ą 12% for Cr, Ni, Mn, Mo, Si, and from ą 8 % to ą 19 % for Cu. The lowest determinable quantities were calculated based on calibrated ranges. Performances of both the IR-LA-ICP-AES were comparable.

Návaznosti

MSM 143100003, záměr

Název: Studium plazmochemických reakcí v neizotermickém nízkoteplotním plazmatu a jeho interakcí s povrchem pevných látek

Investor: Ministerstvo školství, mládeže a tělovýchovy ČR, Studium plazmochemických reakcí v neizotermickém nízkoteplotním plazmatu a jeho interakcí s povrchem pevných látek

Citovat

KANICKÝ, Viktor; Vítězslav OTRUBA; Karel NOVOTNÝ; Petr MUSIL a Jean-Michel MERMET. Calibration graphs for steels by IR laser ablation inductively coupled plasma atomic emission spectrometry. Fresenius Journal of Analytical Chemistry. Berlin: Springer-Verlag, 2001, roč. 370, č. 4, s. 387-392. ISSN 0937-0633.

@article{366111,
   author = {Kanický, Viktor and Otruba, Vítězslav and Novotný, Karel and Musil, Petr and Mermet, JeanandMichel},
   article_location = {Berlin},
   article_number = {4},
   keywords = {Laser ablation; Infrared laser; Inductively coupled plasma; Atomic emission spectrometry; Steel; LINA},
   language = {eng},
   issn = {0937-0633},
   journal = {Fresenius Journal of Analytical Chemistry},
   title = {Calibration graphs for steels by IR laser ablation inductively coupled plasma atomic emission spectrometry},
   volume = {370},
   year = {2001}
}

TY  - JOUR
ID  - 366111
AU  - Kanický, Viktor - Otruba, Vítězslav - Novotný, Karel - Musil, Petr - Mermet, Jean-Michel
PY  - 2001
TI  - Calibration graphs for steels by IR laser ablation inductively coupled plasma atomic emission spectrometry
JF  - Fresenius Journal of Analytical Chemistry
VL  - 370
IS  - 4
SP  - 387
EP  - 387
PB  - Springer-Verlag
SN  - 09370633
KW  - Laser ablation
KW  - Infrared laser
KW  - Inductively coupled plasma
KW  - Atomic emission spectrometry
KW  - Steel
KW  - LINA
N2  - Infrared laser ablation (IR-LA) was studied as a sample introduction technique for the analysis of steels by inductively coupled plasma atomic emission spectrometry (ICP-AES).A comparison of two IR-LA-ICP-AES systems based on Q-switched nanosecond Nd:YAG lasers was performed. The beam of the Lina-SPARK Atomizer (LSA Sarl, Cully, Switzerland) based on the Surelite I-20 laser (Continuum, USA) was moved along a circle. A Perkin-Elmer Optima 3000 DV ICP system was used for emission measurement both with lateral and axial viewing modes. A laboratory-made ablation system based on the Brilliant laser (Quantel) was coupled to a Jobin-Yvon 170 Ultrace ICP (lateral viewing, polychromator part employed). A sample was rotated along a circle during ablation. Linearity of calibration plots was verified at least up to 19 % Cr and 12 % Ni without internal standardization for both LA-ICP-AES systems. Other elements were examined up to 3 % Mo, 1.5 % Mn, 1.7 % Si and 0.15 % Cu. The reproducibility was in the range 5 - 1 %RSD for a mass percentage 0.5 - 20 % of steel constituents. The relative uncertainty on centroid of a calibration line was in the range from ą 4% to ą 12% for Cr, Ni, Mn, Mo, Si, and from ą 8 % to ą 19 % for Cu. The lowest determinable quantities were calculated based on calibrated ranges. Performances of both the IR-LA-ICP-AES were comparable.
ER  -

KANICKÝ, Viktor; Vítězslav OTRUBA; Karel NOVOTNÝ; Petr MUSIL a Jean-Michel MERMET. Calibration graphs for steels by IR laser ablation inductively coupled plasma atomic emission spectrometry. \textit{Fresenius Journal of Analytical Chemistry}. Berlin: Springer-Verlag, 2001, roč.~370, č.~4, s.~387-392. ISSN~0937-0633.

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