TRIETHANOLAMINE COMPLEXES OF H+, LI+, NA+, SR2+, AND BA2+
PERCHLORATES

J 1994

TRIETHANOLAMINE COMPLEXES OF H+, LI+, NA+, SR2+, AND BA2+ PERCHLORATES

NAIINI, A. A., Jiří PINKAS, W. PLASS, V. G. YOUNG, J. G. VERKADE et. al.

Základní údaje

Originální název

TRIETHANOLAMINE COMPLEXES OF H+, LI+, NA+, SR2+, AND BA2+ PERCHLORATES

Autoři

NAIINI, A. A., Jiří PINKAS, W. PLASS, V. G. YOUNG a J. G. VERKADE

Vydání

Inorg. Chem. Spojené státy americké, American Chemical Society, Washington DC, 1994, 0020-1669

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10402 Inorganic and nuclear chemistry

Stát vydavatele

Spojené státy

Utajení

není předmětem státního či obchodního tajemství

Organizační jednotka

Přírodovědecká fakulta

Klíčová slova anglicky

SOLID-STATE; PRECURSORS; ALKOXIDE

Štítky

ALKOXIDE, PRECURSORS, SOLID-STATE

Změněno: 15. 8. 2001 11:42, prof. RNDr. Jiří Pinkas, Ph.D.

Anotace

V originále

The syntheses of the perchlorate salts of H(TEA)+ (1), Li(TEA)+ (2), Na(TEA)+ (3), Sr(TEA)2(2+) (4), and Ba(TEA)2(2+) (5), wherein TEA = triethanolamine, are reported. Characterizational NMR spectral results (H-1, C-13, Li-7, Na-23) as well as crystal structures for 1, 3, and 5 are discussed. The structures of 1, 3, and 5 reveal respectively the cation H(TEA)+ in which the proton is in a tetrahedral environment,a seven-coordinate sodium weakly coordinated by a monodentate ClO4- and two OH oxygens from neighboring units, and a [Ba(TEA)ClO4]2(2+) cation in which two weakly coordinating perchlorates bridge two Ba2+ ions in a bidentate fashion. Extensive hydrogen bridging via ClO4- ions occurs in all three compounds giving rise to parallel sheet structures. Crystal data: 1 (at 22-degrees-C), a = 9.086(1) angstrom and c = 23.919(6) angstrom, with Z = 6 in space group R3c; 3 (at 20-degrees-C), a = 9.617(1) angstrom, b = 7.787(1) angstrom, c = 15.914(2) angstrom, and beta = 105.80-degrees, with Z = 4 in space group P2(1)/c; 5 (at -50-degrees-C), a = 7.498(2) angstrom, b = 10.492(2) angstrom, c = 15.749(3) angstrom, alpha = 76.06(2)-degrees, beta = 80.56(2)-degrees, and gamma = 76.70(2)-degrees, with Z = 2 in space group P1BAR.

Citovat

NAIINI, A. A., Jiří PINKAS, W. PLASS, V. G. YOUNG a J. G. VERKADE. TRIETHANOLAMINE COMPLEXES OF H+, LI+, NA+, SR2+, AND BA2+ PERCHLORATES. Inorg. Chem. Spojené státy americké: American Chemical Society, Washington DC, 1994, roč. 33, č. 10, s. 2137-2141. ISSN 0020-1669.

@article{366814,
   author = {Naiini, A. A. and Pinkas, Jiří and Plass, W. and Young, V. G. and Verkade, J. G.},
   article_location = {Spojené státy americké},
   article_number = {10},
   keywords = {SOLID-STATE; PRECURSORS; ALKOXIDE},
   language = {eng},
   issn = {0020-1669},
   journal = {Inorg. Chem.},
   title = {TRIETHANOLAMINE COMPLEXES OF H+, LI+, NA+, SR2+, AND BA2+ PERCHLORATES},
   volume = {33},
   year = {1994}
}

TY  - JOUR
ID  - 366814
AU  - Naiini, A. A. - Pinkas, Jiří - Plass, W. - Young, V. G. - Verkade, J. G.
PY  - 1994
TI  - TRIETHANOLAMINE COMPLEXES OF H+, LI+, NA+, SR2+, AND BA2+ PERCHLORATES
JF  - Inorg. Chem.
VL  - 33
IS  - 10
SP  - 2137
EP  - 2137
PB  - American Chemical Society, Washington DC
SN  - 00201669
KW  - SOLID-STATE
KW  - PRECURSORS
KW  - ALKOXIDE
N2  - The syntheses of the perchlorate salts of H(TEA)+ (1), Li(TEA)+ (2), Na(TEA)+ (3), Sr(TEA)2(2+) (4), and Ba(TEA)2(2+) (5), wherein TEA = triethanolamine, are reported. Characterizational NMR spectral results (H-1, C-13, Li-7, Na-23) as well as crystal structures for 1, 3, and 5 are discussed. The structures of 1, 3, and 5 reveal respectively the cation H(TEA)+ in which the proton is in a tetrahedral environment,a seven-coordinate sodium weakly coordinated by a monodentate ClO4- and two OH oxygens from neighboring units, and a [Ba(TEA)ClO4]2(2+) cation in which two weakly coordinating perchlorates bridge two Ba2+ ions in a bidentate fashion. Extensive hydrogen bridging via ClO4- ions occurs in all three compounds giving rise to parallel sheet structures. Crystal data: 1 (at 22-degrees-C), a = 9.086(1) angstrom and c = 23.919(6) angstrom, with Z = 6 in space group R3c; 3 (at 20-degrees-C), a = 9.617(1) angstrom, b = 7.787(1) angstrom, c = 15.914(2) angstrom, and beta = 105.80-degrees, with Z = 4 in space group P2(1)/c; 5 (at -50-degrees-C), a = 7.498(2) angstrom, b = 10.492(2) angstrom, c = 15.749(3) angstrom, alpha = 76.06(2)-degrees, beta = 80.56(2)-degrees, and gamma = 76.70(2)-degrees, with Z = 2 in space group P1BAR.
ER  -

NAIINI, A. A., Jiří PINKAS, W. PLASS, V. G. YOUNG a J. G. VERKADE. TRIETHANOLAMINE COMPLEXES OF H+, LI+, NA+, SR2+, AND BA2+ PERCHLORATES. \textit{Inorg. Chem.}. Spojené státy americké: American Chemical Society, Washington DC, 1994, roč.~33, č.~10, s.~2137-2141. ISSN~0020-1669.

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