TRIETHANOLAMINE COMPLEXES OF H+, LI+, NA+, SR2+, AND BA2+
PERCHLORATES

J 1994

TRIETHANOLAMINE COMPLEXES OF H+, LI+, NA+, SR2+, AND BA2+ PERCHLORATES

NAIINI, A. A.; Jiří PINKAS; W. PLASS; V. G. YOUNG; J. G. VERKADE et al.

Základní údaje

Originální název

TRIETHANOLAMINE COMPLEXES OF H+, LI+, NA+, SR2+, AND BA2+ PERCHLORATES

Autoři

NAIINI, A. A.; Jiří PINKAS; W. PLASS; V. G. YOUNG a J. G. VERKADE

Vydání

Inorg. Chem. Spojené státy americké, American Chemical Society, Washington DC, 1994, 0020-1669

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10402 Inorganic and nuclear chemistry

Stát vydavatele

Spojené státy

Utajení

není předmětem státního či obchodního tajemství

Označené pro přenos do RIV

Ano

Organizační jednotka

Přírodovědecká fakulta

Klíčová slova anglicky

SOLID-STATE; PRECURSORS; ALKOXIDE

Štítky

ALKOXIDE, PRECURSORS, SOLID-STATE

Změněno: 15. 8. 2001 11:42, prof. RNDr. Jiří Pinkas, Ph.D.

Anotace

V originále

The syntheses of the perchlorate salts of H(TEA)+ (1), Li(TEA)+ (2), Na(TEA)+ (3), Sr(TEA)2(2+) (4), and Ba(TEA)2(2+) (5), wherein TEA = triethanolamine, are reported. Characterizational NMR spectral results (H-1, C-13, Li-7, Na-23) as well as crystal structures for 1, 3, and 5 are discussed. The structures of 1, 3, and 5 reveal respectively the cation H(TEA)+ in which the proton is in a tetrahedral environment,a seven-coordinate sodium weakly coordinated by a monodentate ClO4- and two OH oxygens from neighboring units, and a [Ba(TEA)ClO4]2(2+) cation in which two weakly coordinating perchlorates bridge two Ba2+ ions in a bidentate fashion. Extensive hydrogen bridging via ClO4- ions occurs in all three compounds giving rise to parallel sheet structures. Crystal data: 1 (at 22-degrees-C), a = 9.086(1) angstrom and c = 23.919(6) angstrom, with Z = 6 in space group R3c; 3 (at 20-degrees-C), a = 9.617(1) angstrom, b = 7.787(1) angstrom, c = 15.914(2) angstrom, and beta = 105.80-degrees, with Z = 4 in space group P2(1)/c; 5 (at -50-degrees-C), a = 7.498(2) angstrom, b = 10.492(2) angstrom, c = 15.749(3) angstrom, alpha = 76.06(2)-degrees, beta = 80.56(2)-degrees, and gamma = 76.70(2)-degrees, with Z = 2 in space group P1BAR.

Citovat

NAIINI, A. A.; Jiří PINKAS; W. PLASS; V. G. YOUNG a J. G. VERKADE. TRIETHANOLAMINE COMPLEXES OF H+, LI+, NA+, SR2+, AND BA2+ PERCHLORATES. Inorg. Chem. Spojené státy americké: American Chemical Society, Washington DC, 1994, roč. 33, č. 10, s. 2137-2141. ISSN 0020-1669.

@article{366814,
   author = {Naiini, A. A. and Pinkas, Jiří and Plass, W. and Young, V. G. and Verkade, J. G.},
   article_location = {Spojené státy americké},
   article_number = {10},
   keywords = {SOLID-STATE; PRECURSORS; ALKOXIDE},
   language = {eng},
   issn = {0020-1669},
   journal = {Inorg. Chem.},
   title = {TRIETHANOLAMINE COMPLEXES OF H+, LI+, NA+, SR2+, AND BA2+ PERCHLORATES},
   volume = {33},
   year = {1994}
}

TY  - JOUR
ID  - 366814
AU  - Naiini, A. A. - Pinkas, Jiří - Plass, W. - Young, V. G. - Verkade, J. G.
PY  - 1994
TI  - TRIETHANOLAMINE COMPLEXES OF H+, LI+, NA+, SR2+, AND BA2+ PERCHLORATES
JF  - Inorg. Chem.
VL  - 33
IS  - 10
SP  - 2137
EP  - 2137
PB  - American Chemical Society, Washington DC
SN  - 00201669
KW  - SOLID-STATE
KW  - PRECURSORS
KW  - ALKOXIDE
N2  - The syntheses of the perchlorate salts of H(TEA)+ (1), Li(TEA)+ (2), Na(TEA)+ (3), Sr(TEA)2(2+) (4), and Ba(TEA)2(2+) (5), wherein TEA = triethanolamine, are reported. Characterizational NMR spectral results (H-1, C-13, Li-7, Na-23) as well as crystal structures for 1, 3, and 5 are discussed. The structures of 1, 3, and 5 reveal respectively the cation H(TEA)+ in which the proton is in a tetrahedral environment,a seven-coordinate sodium weakly coordinated by a monodentate ClO4- and two OH oxygens from neighboring units, and a [Ba(TEA)ClO4]2(2+) cation in which two weakly coordinating perchlorates bridge two Ba2+ ions in a bidentate fashion. Extensive hydrogen bridging via ClO4- ions occurs in all three compounds giving rise to parallel sheet structures. Crystal data: 1 (at 22-degrees-C), a = 9.086(1) angstrom and c = 23.919(6) angstrom, with Z = 6 in space group R3c; 3 (at 20-degrees-C), a = 9.617(1) angstrom, b = 7.787(1) angstrom, c = 15.914(2) angstrom, and beta = 105.80-degrees, with Z = 4 in space group P2(1)/c; 5 (at -50-degrees-C), a = 7.498(2) angstrom, b = 10.492(2) angstrom, c = 15.749(3) angstrom, alpha = 76.06(2)-degrees, beta = 80.56(2)-degrees, and gamma = 76.70(2)-degrees, with Z = 2 in space group P1BAR.
ER  -

NAIINI, A. A.; Jiří PINKAS; W. PLASS; V. G. YOUNG a J. G. VERKADE. TRIETHANOLAMINE COMPLEXES OF H+, LI+, NA+, SR2+, AND BA2+ PERCHLORATES. \textit{Inorg. Chem.}. Spojené státy americké: American Chemical Society, Washington DC, 1994, roč.~33, č.~10, s.~2137-2141. ISSN~0020-1669.

Přehled o publikaci