Group-13 Azatranes - Structure and Reactivity

J 1994

Group-13 Azatranes - Structure and Reactivity

PINKAS, Jiří; T. L. WANG; R. A. JACOBSON a J. G. VERKADE

Základní údaje

Originální název

Group-13 Azatranes - Structure and Reactivity

Autoři

PINKAS, Jiří; T. L. WANG; R. A. JACOBSON a J. G. VERKADE

Vydání

Inorg. Chem. Spojené státy americké, American Chemical Society, Washington DC, 1994, 0020-1669

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10402 Inorganic and nuclear chemistry

Stát vydavatele

Spojené státy

Utajení

není předmětem státního či obchodního tajemství

Označené pro přenos do RIV

Ano

Organizační jednotka

Přírodovědecká fakulta

Klíčová slova anglicky

CRYSTAL-STRUCTURE; MOLECULAR-STRUCTURE; ORGANOMETALLIC PRECURSORS;SUBSTITUTION-REACTIONS; THERMAL-DECOMPOSITION; GALLIUM; COMPLEXES; ALUMINUM; BOND;AZASILATRANES

Štítky

aluminum, AZASILATRANES, BOND, Complexes, CRYSTAL-STRUCTURE, gallium, MOLECULAR-STRUCTURE, ORGANOMETALLIC PRECURSORS, SUBSTITUTION-REACTIONS, THERMAL-DECOMPOSITION

Změněno: 15. 8. 2001 11:49, prof. RNDr. Jiří Pinkas, Ph.D.

Anotace

V originále

The new monomeric azagallatranes ga(RNCH(2)CH(2))(3)N (R = SiMe(3), 10; SiMe(2)-t-Bu, 11) and dimeric azagallatrane [Ga(MeNCH(2)CH(2))(3)N](2), 14, were prepared by two synthetic routes: (i) the transamination reaction of [Ga (NMe(2))(3)](2), with (MeNHCH(2)CH(2))(3)N, 2, and (ii) the transmetalation reaction of [Al(MeNCH(2)CH(2))(3)N](2), 12, with Ga(acac)(3) (acac = penta-2,5-dienoate). Dimeric azaalumatrane 12, monomeric azaalumatranes Al(RNCH(2) CH2)(3)N (R = SiMe(3), 8; SiMe(2)-t-Bu, 9), and azaboratrane B(MeNCH(2)CH(2))(3)N, 6, react with a variety of alkoxides giving transition metal or main-group element azatranes. The molecular structures of 12 and 14 were established by X-ray diffraction experiments, and both possess an unusual cis configuration of the substituents on the central four-membered (M-N)(2) ring. Crystal data: 12, a = 37.372(10) Angstrom, b = 14.379(2) Angstrom c = 8.774(2) Angstrom, V = 4714.9(1) Angstrom(3), Z = 8, orthorhombic space group Pbca, R = 5.0%; 14, a = 9.716(1) Angstrom, b = 11.325(2) Angstrom, c = 11.343(1) Angstrom, alpha = 110.36(2)degrees, beta = 97.87(1)degrees, gamma = 90.34(1)degrees, V = 1157.2(3) Angstrom(3), Z = 2, triclinic space group P1bar, R = 4.7%.

Citovat

PINKAS, Jiří; T. L. WANG; R. A. JACOBSON a J. G. VERKADE. Group-13 Azatranes - Structure and Reactivity. Inorg. Chem. Spojené státy americké: American Chemical Society, Washington DC, 1994, roč. 33, č. 23, s. 5244-5253. ISSN 0020-1669.

@article{366817,
   author = {Pinkas, Jiří and Wang, T. L. and Jacobson, R. A. and Verkade, J. G.},
   article_location = {Spojené státy americké},
   article_number = {23},
   keywords = {CRYSTAL-STRUCTURE; MOLECULAR-STRUCTURE; ORGANOMETALLIC PRECURSORS;SUBSTITUTION-REACTIONS; THERMAL-DECOMPOSITION; GALLIUM; COMPLEXES; ALUMINUM; BOND;AZASILATRANES},
   language = {eng},
   issn = {0020-1669},
   journal = {Inorg. Chem.},
   title = {Group-13 Azatranes - Structure and Reactivity},
   volume = {33},
   year = {1994}
}

TY  - JOUR
ID  - 366817
AU  - Pinkas, Jiří - Wang, T. L. - Jacobson, R. A. - Verkade, J. G.
PY  - 1994
TI  - Group-13 Azatranes - Structure and Reactivity
JF  - Inorg. Chem.
VL  - 33
IS  - 23
SP  - 5244
EP  - 5244
PB  - American Chemical Society, Washington DC
SN  - 00201669
KW  - CRYSTAL-STRUCTURE
KW  - MOLECULAR-STRUCTURE
KW  - ORGANOMETALLIC PRECURSORS;SUBSTITUTION-REACTIONS
KW  - THERMAL-DECOMPOSITION
KW  - GALLIUM
KW  - COMPLEXES
KW  - ALUMINUM
KW  - BOND;AZASILATRANES
N2  - The new monomeric azagallatranes ga(RNCH(2)CH(2))(3)N (R = SiMe(3), 10; SiMe(2)-t-Bu, 11) and dimeric azagallatrane [Ga(MeNCH(2)CH(2))(3)N](2), 14, were prepared by two synthetic routes: (i) the transamination reaction of [Ga (NMe(2))(3)](2), with (MeNHCH(2)CH(2))(3)N, 2, and (ii) the transmetalation reaction of [Al(MeNCH(2)CH(2))(3)N](2), 12, with Ga(acac)(3) (acac = penta-2,5-dienoate). Dimeric azaalumatrane 12, monomeric azaalumatranes Al(RNCH(2) CH2)(3)N (R = SiMe(3), 8; SiMe(2)-t-Bu, 9), and azaboratrane B(MeNCH(2)CH(2))(3)N, 6, react with a variety of alkoxides giving transition metal or main-group element azatranes. The molecular structures of 12 and 14 were established by X-ray diffraction experiments, and both possess an unusual cis configuration of the substituents on the central four-membered (M-N)(2) ring. Crystal data: 12, a = 37.372(10) Angstrom, b = 14.379(2) Angstrom c = 8.774(2) Angstrom, V = 4714.9(1) Angstrom(3), Z = 8, orthorhombic space group Pbca, R = 5.0%; 14, a = 9.716(1) Angstrom, b = 11.325(2) Angstrom, c = 11.343(1) Angstrom, alpha = 110.36(2)degrees, beta = 97.87(1)degrees, gamma = 90.34(1)degrees, V = 1157.2(3) Angstrom(3), Z = 2, triclinic space group P1bar, R = 4.7%.
ER  -

PINKAS, Jiří; T. L. WANG; R. A. JACOBSON a J. G. VERKADE. Group-13 Azatranes - Structure and Reactivity. \textit{Inorg. Chem.}. Spojené státy americké: American Chemical Society, Washington DC, 1994, roč.~33, č.~23, s.~5244-5253. ISSN~0020-1669.

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