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@inproceedings{384903,
author = {Drbálková, Eva and Janderka, Pavel},
address = {Nosyvaj},
booktitle = {Proceedings of the 19th Informal Meeting on Mass Spectrometry},
keywords = {formic acid; N;N-dimethylformamide; electro-hydrogenation; electro-oxidation; DEMS; voltammetry; mass spectrometry},
language = {eng},
location = {Nosyvaj},
pages = {98-99},
publisher = {MS Group of the Chemical Research Center of the Hungarian Academy of Sciences,Hungary and MS Service of CNR, Italy},
title = {Electrooxidation of small organic molecules on polycrystalline platinum electrode in aqueous acid solution using on-line MS study},
year = {2001}
}
TY - JOUR
ID - 384903
AU - Drbálková, Eva - Janderka, Pavel
PY - 2001
TI - Electrooxidation of small organic molecules on polycrystalline platinum electrode in aqueous acid solution using on-line MS study
PB - MS Group of the Chemical Research Center of the Hungarian Academy of Sciences,Hungary and MS Service of CNR, Italy
CY - Nosyvaj
KW - formic acid
KW - N;N-dimethylformamide
KW - electro-hydrogenation
KW - electro-oxidation
KW - DEMS
KW - voltammetry
KW - mass spectrometry
N2 - The electrochemical cell and mass spectrometer combination - differential electrochemical mass spectrometry (DEMS) - was used for detection, identification and observation in time of volatile and semivolatile species during the electrochemical polarisation of a working electrode. DEMS is a type of experimental technique, which makes possible an investigation of electro-sorption, electro-oxidation and electro-hydrogenation processes of molecules like aromatic hydrocarbons, some other small organic molecules and reaction intermediates. As a test system the electrochemical oxidation of formic acid and dimethylformamide in 0,5 M sulfuric acid on polycrystalline Pt electrode was studied. The results are presented as a plot of ion current of selected masses of expected products as function of working electrode potential. The faradaic current-potential curves were measured simultaneously.
ER -
DRBÁLKOVÁ, Eva a Pavel JANDERKA. Electrooxidation of small organic molecules on polycrystalline platinum electrode in aqueous acid solution using on-line MS study. In \textit{Proceedings of the 19th Informal Meeting on Mass Spectrometry}. Nosyvaj: MS Group of the Chemical Research Center of the Hungarian Academy of Sciences,Hungary and MS Service of CNR, Italy, 2001, s.~98-99.
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