Capillary electrophoretic study of interactions of metal ions
with crown ethers, a sulfated beta-cyclodextrin, and
zwitterionic buffers present as additives in the background
electrolyte

J 2002

Capillary electrophoretic study of interactions of metal ions with crown ethers, a sulfated beta-cyclodextrin, and zwitterionic buffers present as additives in the background electrolyte

MUZIKÁŘ, Martin; Josef HAVEL a M. MACKA

Základní údaje

Originální název

Capillary electrophoretic study of interactions of metal ions with crown ethers, a sulfated beta-cyclodextrin, and zwitterionic buffers present as additives in the background electrolyte

Autoři

MUZIKÁŘ, Martin; Josef HAVEL a M. MACKA

Vydání

ELECTROPHORESIS, WEINHEIM, WILEY-V C H VERLAG GMBH, 2002, 0173-0835

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10406 Analytical chemistry

Stát vydavatele

Velká Británie a Severní Irsko

Utajení

není předmětem státního či obchodního tajemství

Impakt faktor

Impact factor: 4.325

Označené pro přenos do RIV

Ano

Kód RIV

RIV/00216224:14330/02:00007641

Organizační jednotka

Fakulta informatiky

UT WoS

000176857000005

Klíčová slova anglicky

capillary electrophoretic study; sulfated beta-cyclodextrin

Štítky

capillary electrophoretic study, sulfated beta-cyclodextrin

Změněno: 31. 5. 2003 15:08, RNDr. JUDr. Vladimír Šmíd, CSc.

Anotace

V originále

Stability constants of K, Na, Ca, and Ba with 18-crown-6, K, Na, L with sulfated P-cyclodextrin and K, Li, Ca, Mg, Sr, and Ba ions with ([2-hydroxy-1,1-bis(hydroxymethyl) ethyl]-amino)-1-propanesulfonic acid (TAPS) were determined by capillary electrophoresis and computed using a general least squares minimizing program CELET The results for 18-crown-6 agreed well with those evaluated by graphical methods or reported in the literature. Previously unknown stability constants of sulfated beta-cyclodextrins and TAPS determined for alkali and alkaline earth metals show that sulfated beta-cyclodextrin interacts with monovalent metals allowing to manipulate their effective mobility. It interacts stronger with divalent metal cations. TAPS, as zwitterionic buffer widely used in various analytical, biochemical and other applications, forms complexes with alkali and alkaline earth cations, and although the stability constants are rather low, the equilibria should be taken into account when TAPS is used and metal cations are present in solution at the same time.

Návaznosti

GA203/02/1103, projekt VaV

Název: Umělé neuronové sítě a plánování pokusů v analytické chemii, zejména v separačních metodách

Investor: Grantová agentura ČR, Umělé neuronové sítě a plánování pokusů v analytické chemii, zejména v separačních metodách

MSM 143100011, záměr

Název: Struktura a vazebné poměry, vlastnosti a analýza syntetických a přírodních molekulových ansamblů

Investor: Ministerstvo školství, mládeže a tělovýchovy ČR, Struktura a vazebné poměry, vlastnosti a analýza syntetických a přírodních molekulových ansamblů

Citovat

MUZIKÁŘ, Martin; Josef HAVEL a M. MACKA. Capillary electrophoretic study of interactions of metal ions with crown ethers, a sulfated beta-cyclodextrin, and zwitterionic buffers present as additives in the background electrolyte. ELECTROPHORESIS. WEINHEIM: WILEY-V C H VERLAG GMBH, 2002, roč. 23, č. 12, s. 1796-1802. ISSN 0173-0835.

@article{485224,
   author = {Muzikář, Martin and Havel, Josef and Macka, M.},
   article_location = {WEINHEIM},
   article_number = {12},
   keywords = {capillary electrophoretic study; sulfated beta-cyclodextrin},
   language = {eng},
   issn = {0173-0835},
   journal = {ELECTROPHORESIS},
   title = {Capillary electrophoretic study of interactions of metal ions with crown ethers, a sulfated beta-cyclodextrin, and zwitterionic buffers present as additives in the background electrolyte},
   volume = {23},
   year = {2002}
}

TY  - JOUR
ID  - 485224
AU  - Muzikář, Martin - Havel, Josef - Macka, M.
PY  - 2002
TI  - Capillary electrophoretic study of interactions of metal ions with crown ethers, a sulfated beta-cyclodextrin, and zwitterionic buffers present as additives in the background electrolyte
JF  - ELECTROPHORESIS
VL  - 23
IS  - 12
SP  - 1796-1802
EP  - 1796-1802
PB  - WILEY-V C H VERLAG GMBH
SN  - 01730835
KW  - capillary electrophoretic study
KW  - sulfated beta-cyclodextrin
N2  - Stability constants of K, Na, Ca, and Ba with 18-crown-6, K, Na, L with sulfated P-cyclodextrin and K, Li, Ca, Mg, Sr, and Ba ions with ([2-hydroxy-1,1-bis(hydroxymethyl) ethyl]-amino)-1-propanesulfonic acid (TAPS) were determined by capillary electrophoresis and computed using a general least squares minimizing program CELET The results for 18-crown-6 agreed well with those evaluated by graphical methods or reported in the literature. Previously unknown stability constants of sulfated beta-cyclodextrins and TAPS determined for alkali and alkaline earth metals show that sulfated beta-cyclodextrin interacts with monovalent metals allowing to manipulate their effective mobility. It interacts stronger with divalent metal cations. TAPS, as zwitterionic buffer widely used in various analytical, biochemical and other applications, forms complexes with alkali and alkaline earth cations, and although the stability constants are rather low, the equilibria should be taken into account when TAPS is used and metal cations are present in solution at the same time.
ER  -

MUZIKÁŘ, Martin; Josef HAVEL a M. MACKA. Capillary electrophoretic study of interactions of metal ions with crown ethers, a sulfated beta-cyclodextrin, and zwitterionic buffers present as additives in the background electrolyte. \textit{ELECTROPHORESIS}. WEINHEIM: WILEY-V C H VERLAG GMBH, 2002, roč.~23, č.~12, s.~1796-1802. ISSN~0173-0835.

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