Diaquabis(1,10-phenanthroline-kappa2N,N')manganese(II)
thiodiglycolate
bis(1,10-phenanthroline-kappa2N,N')(thiodiglycolato-kappa2O,O')
manganese(II) tridecahydrate

J 2003

Diaquabis(1,10-phenanthroline-kappa2N,N')manganese(II) thiodiglycolate bis(1,10-phenanthroline-kappa2N,N')(thiodiglycolato-kappa2O,O')manganese(II) tridecahydrate

MAREK, Jaromír; Z. TRÁVNÍČEK a P. KOPEL

Základní údaje

Originální název

Diaquabis(1,10-phenanthroline-kappa2N,N')manganese(II) thiodiglycolate bis(1,10-phenanthroline-kappa2N,N')(thiodiglycolato-kappa2O,O')manganese(II) tridecahydrate

Autoři

MAREK, Jaromír ; Z. TRÁVNÍČEK a P. KOPEL

Vydání

Acta Crystallographica Section C: Crystal Structure, Chester, UK, International Union of Crystallography, 2003, 0108-2701

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10402 Inorganic and nuclear chemistry

Stát vydavatele

Velká Británie a Severní Irsko

Utajení

není předmětem státního či obchodního tajemství

Impakt faktor

Impact factor: 0.828

Kód RIV

RIV/00216224:14330/03:00008583

Organizační jednotka

Fakulta informatiky

Klíčová slova anglicky

manganese(II); thiodiglycolic acid; crystal structure

Štítky

Crystal Structure, manganese(II), thiodiglycolic acid

Změněno: 29. 5. 2004 18:55, RNDr. JUDr. Vladimír Šmíd, CSc.

Anotace

V originále

The title compound, [Mn(C12H8N2)2(H2O)2](C4H4O4S).[Mn(C4H4O4S)(C12H8N2)2].13H2O, contains one dianion of thiodiglycolic acid (tdga2-) and two independent manganese(II) moieties, viz. [Mn(phen)2(H2O)2]2+ and [Mn(tdga)(phen)2], where phen is 1,10-phenanthroline. The MnII atoms are octahedrally coordinated by four N atoms of two bidentate phen ligands [Mn-N = 2.240 (2)-2.3222 (19) A] and either two water O atoms or two tdga carboxyl O atoms [Mn-O = 2.1214 (17)-2.1512 (17) A]. The tdga ligand chelates as an O,O'-bidentate ligand, forming an eight-membered ring with one Mn atom. The free tdga2- dianion is hydrogen bonded to an [Mn(phen)2(H2O)2]2+ ion, with OO distances of 2.606 (2) and 2.649 (2) A. The crystal structure is further stabilized by an extensive network of hydrogen bonds involving 13 water molecules.

Návaznosti

GA203/02/0436, projekt VaV

Název: Aplikace krystalografických databází ve vědecké praxi

MSM 143100008, záměr

Název: Genomy a jejich funkce

Investor: Ministerstvo školství, mládeže a tělovýchovy ČR, Genomy a jejich funkce

Citovat

MAREK, Jaromír; Z. TRÁVNÍČEK a P. KOPEL. Diaquabis(1,10-phenanthroline-kappa2N,N')manganese(II) thiodiglycolate bis(1,10-phenanthroline-kappa2N,N')(thiodiglycolato-kappa2O,O')manganese(II) tridecahydrate. Acta Crystallographica Section C: Crystal Structure. Chester, UK: International Union of Crystallography, 2003, C59, č. 11, s. m429-m431, 3 s. ISSN 0108-2701.

@article{489393,
   author = {Marek, Jaromír and Trávníček, Z. and Kopel, P.},
   article_location = {Chester, UK},
   article_number = {11},
   keywords = {manganese(II); thiodiglycolic acid; crystal structure},
   language = {eng},
   issn = {0108-2701},
   journal = {Acta Crystallographica Section C: Crystal Structure},
   title = {Diaquabis(1,10-phenanthroline-kappa2N,N')manganese(II) thiodiglycolate bis(1,10-phenanthroline-kappa2N,N')(thiodiglycolato-kappa2O,O')manganese(II) tridecahydrate},
   volume = {C59},
   year = {2003}
}

TY  - JOUR
ID  - 489393
AU  - Marek, Jaromír - Trávníček, Z. - Kopel, P.
PY  - 2003
TI  - Diaquabis(1,10-phenanthroline-kappa2N,N')manganese(II) thiodiglycolate bis(1,10-phenanthroline-kappa2N,N')(thiodiglycolato-kappa2O,O')manganese(II) tridecahydrate
JF  - Acta Crystallographica Section C: Crystal Structure
VL  - C59
IS  - 11
SP  - m429-m431
EP  - m429-m431
PB  - International Union of Crystallography
SN  - 01082701
KW  - manganese(II)
KW  - thiodiglycolic acid
KW  - crystal structure
N2  - The title compound, [Mn(C12H8N2)2(H2O)2](C4H4O4S).[Mn(C4H4O4S)(C12H8N2)2].13H2O, contains one dianion of thiodiglycolic acid (tdga2-) and two independent manganese(II) moieties, viz. [Mn(phen)2(H2O)2]2+ and [Mn(tdga)(phen)2], where phen is 1,10-phenanthroline. The MnII atoms are octahedrally coordinated by four N atoms of two bidentate phen ligands [Mn-N = 2.240 (2)-2.3222 (19) A] and either two water O atoms or two tdga carboxyl O atoms [Mn-O = 2.1214 (17)-2.1512 (17) A]. The tdga ligand chelates as an O,O'-bidentate ligand, forming an eight-membered ring with one Mn atom. The free tdga2- dianion is hydrogen bonded to an [Mn(phen)2(H2O)2]2+ ion, with OO distances of 2.606 (2) and 2.649 (2) A. The crystal structure is further stabilized by an extensive network of hydrogen bonds involving 13 water molecules.
ER  -

MAREK, Jaromír; Z. TRÁVNÍČEK a P. KOPEL. Diaquabis(1,10-phenanthroline-kappa2N,N')manganese(II) thiodiglycolate bis(1,10-phenanthroline-kappa2N,N')(thiodiglycolato-kappa2O,O')manganese(II) tridecahydrate. \textit{Acta Crystallographica Section C: Crystal Structure}. Chester, UK: International Union of Crystallography, 2003, C59, č.~11, s.~m429-m431, 3 s. ISSN~0108-2701.

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