catena-Poly[potassium
[copper(II)-mu-isothiocyanato-mu-N-salicylidene-beta-alaninato(
2-)]]

J 2003

catena-Poly[potassium [copper(II)-mu-isothiocyanato-mu-N-salicylidene-beta-alaninato(2-)]]

MAREK, Jaromír; J. VANČO a O. ŠVAJLENOVÁ

Základní údaje

Originální název

catena-Poly[potassium [copper(II)-mu-isothiocyanato-mu-N-salicylidene-beta-alaninato(2-)]]

Autoři

MAREK, Jaromír ; J. VANČO a O. ŠVAJLENOVÁ

Vydání

Acta Crystallographica Section C: Crystal Structure, Chester, UK, International Union of Crystallography, 2003, 0108-2701

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10402 Inorganic and nuclear chemistry

Stát vydavatele

Velká Británie a Severní Irsko

Utajení

není předmětem státního či obchodního tajemství

Impakt faktor

Impact factor: 0.828

Kód RIV

RIV/00216224:14330/03:00008597

Organizační jednotka

Fakulta informatiky

Klíčová slova anglicky

Schiff base; pseudohalogeno Schiff base cuprate(II)

Štítky

pseudohalogeno Schiff base cuprate(II), Schiff base

Změněno: 29. 5. 2004 18:54, RNDr. JUDr. Vladimír Šmíd, CSc.

Anotace

V originále

The title polymeric compound, catena-poly[dipotassium [bis[mu-N-salicylidene-beta-alaninato(2-)]-kappa4 O,N,O':O'';kappa4 O'':O,N,O'-dicopper(II)]-di-mu-isothiocyanato-kappa2 N:S;kappa2 S:N], {K[Cu(NCS)(C10H9NO3)]}n, consists of [isothiocyanato(N-salicylidene-beta-alaninato)copper(II)]- anions connected through the two three-atom thiocyanate (mu-NCS) and the two anti,anti-mu-carboxylate bridges into infinite one-dimensional polymeric anions, with coulombically interacting K+ counter-ions with coordination number 7 constrained between the chains. The CuII atoms adopt a distorted tetragonal-bipyramidal coordination, with three donor atoms of the tridentate Schiff base and one N atom of the bridging mu-NCS ligand in the basal plane. The first axial position is occupied by a thiocyanate S atom of a symmetry-related mu-NCS ligand at an apical distance of 2.9770 (8) A, and the second position is occupied by an O atom of a bridging carboxylate group from an adjacent coordination unit at a distance of 2.639 (2) A.

Návaznosti

GA203/02/0436, projekt VaV

Název: Aplikace krystalografických databází ve vědecké praxi

MSM 143100008, záměr

Název: Genomy a jejich funkce

Investor: Ministerstvo školství, mládeže a tělovýchovy ČR, Genomy a jejich funkce

Citovat

MAREK, Jaromír; J. VANČO a O. ŠVAJLENOVÁ. catena-Poly[potassium [copper(II)-mu-isothiocyanato-mu-N-salicylidene-beta-alaninato(2-)]]. Acta Crystallographica Section C: Crystal Structure. Chester, UK: International Union of Crystallography, 2003, roč. 2003, č. 12, s. m509-m511, 3 s. ISSN 0108-2701.

@article{490023,
   author = {Marek, Jaromír and Vančo, J. and Švajlenová, O.},
   article_location = {Chester, UK},
   article_number = {12},
   keywords = {Schiff base; pseudohalogeno Schiff base cuprate(II)},
   language = {eng},
   issn = {0108-2701},
   journal = {Acta Crystallographica Section C: Crystal Structure},
   title = {catena-Poly[potassium [copper(II)-mu-isothiocyanato-mu-N-salicylidene-beta-alaninato(2-)]]},
   volume = {2003},
   year = {2003}
}

TY  - JOUR
ID  - 490023
AU  - Marek, Jaromír - Vančo, J. - Švajlenová, O.
PY  - 2003
TI  - catena-Poly[potassium [copper(II)-mu-isothiocyanato-mu-N-salicylidene-beta-alaninato(2-)]]
JF  - Acta Crystallographica Section C: Crystal Structure
VL  - 2003
IS  - 12
SP  - m509-m511
EP  - m509-m511
PB  - International Union of Crystallography
SN  - 01082701
KW  - Schiff base
KW  - pseudohalogeno Schiff base cuprate(II)
N2  - The title polymeric compound, catena-poly[dipotassium [bis[mu-N-salicylidene-beta-alaninato(2-)]-kappa4 O,N,O':O'';kappa4 O'':O,N,O'-dicopper(II)]-di-mu-isothiocyanato-kappa2 N:S;kappa2 S:N], {K[Cu(NCS)(C10H9NO3)]}n, consists of [isothiocyanato(N-salicylidene-beta-alaninato)copper(II)]- anions connected through the two three-atom thiocyanate (mu-NCS) and the two anti,anti-mu-carboxylate bridges into infinite one-dimensional polymeric anions, with coulombically interacting K+ counter-ions with coordination number 7 constrained between the chains. The CuII atoms adopt a distorted tetragonal-bipyramidal coordination, with three donor atoms of the tridentate Schiff base and one N atom of the bridging mu-NCS ligand in the basal plane. The first axial position is occupied by a thiocyanate S atom of a symmetry-related mu-NCS ligand at an apical distance of 2.9770 (8) A, and the second position is occupied by an O atom of a bridging carboxylate group from an adjacent coordination unit at a distance of 2.639 (2) A.
ER  -

MAREK, Jaromír; J. VANČO a O. ŠVAJLENOVÁ. catena-Poly[potassium [copper(II)-mu-isothiocyanato-mu-N-salicylidene-beta-alaninato(2-)]]. \textit{Acta Crystallographica Section C: Crystal Structure}. Chester, UK: International Union of Crystallography, 2003, roč.~2003, č.~12, s.~m509-m511, 3 s. ISSN~0108-2701.

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