SCHWENDT, P., M. AHMED a Jaromír MAREK. Peroxovanadium(V) complexes of -hydroxyhippuric acid. The X-ray crystal structure of (NPr4)2[V2O2(O2)2(alpha-hhip)2] .5H2O, [alpha-hhip=alpha-hydroxyhippurato (2-) - C9H7NO4 (2-)]. Inorganic Chemistry Communications. Netherlands: Elsevier Science, 2004, roč. 7, č. 5, s. 631-633. ISSN 1387-7003. |
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@article{554624, author = {Schwendt, P. and Ahmed, M. and Marek, Jaromír}, article_location = {Netherlands}, article_number = {5}, keywords = {Peroxovanadium complexes; -hydroxyhippuric acid; IR and Raman spectroscopies; Crystal structure}, language = {eng}, issn = {1387-7003}, journal = {Inorganic Chemistry Communications}, title = {Peroxovanadium(V) complexes of -hydroxyhippuric acid. The X-ray crystal structure of (NPr4)2[V2O2(O2)2(alpha-hhip)2] .5H2O, [alpha-hhip=alpha-hydroxyhippurato (2-) - C9H7NO4 (2-)]}, volume = {7}, year = {2004} }
TY - JOUR ID - 554624 AU - Schwendt, P. - Ahmed, M. - Marek, Jaromír PY - 2004 TI - Peroxovanadium(V) complexes of -hydroxyhippuric acid. The X-ray crystal structure of (NPr4)2[V2O2(O2)2(alpha-hhip)2] .5H2O, [alpha-hhip=alpha-hydroxyhippurato (2-) - C9H7NO4 (2-)] JF - Inorganic Chemistry Communications VL - 7 IS - 5 SP - 631-633 EP - 631-633 PB - Elsevier Science SN - 13877003 KW - Peroxovanadium complexes KW - -hydroxyhippuric acid KW - IR and Raman spectroscopies KW - Crystal structure N2 - Peroxovanadium(V) complexes of alpha-hydroxyhippuric acid (alpha-H2hhip), M2[V2O2(O2)2(alpha-hhip)2].nH2O [M=NMe4+ (1), NPr4+ (2); n=0.5, 5], have been prepared and characterized by elemental analysis and by IR and Raman spectroscopies. The X-ray crystal structure of 2 has been determined as the first crystal structure of an -hydroxyhippurato complex. A single crystal X-ray diffraction study has shown that the -hhip ligand behaves as a tridentate chelator adopting the (O-, COO-, CO) donor set. The coordination geometry of the vanadium atom is a distorted pentagonal bipyramid. ER -
SCHWENDT, P., M. AHMED a Jaromír MAREK. Peroxovanadium(V) complexes of -hydroxyhippuric acid. The X-ray crystal structure of (NPr4)2[V2O2(O2)2(alpha-hhip)2] .5H2O, [alpha-hhip=alpha-hydroxyhippurato (2-) - C9H7NO4 (2-)]. \textit{Inorganic Chemistry Communications}. Netherlands: Elsevier Science, 2004, roč.~7, č.~5, s.~631-633. ISSN~1387-7003.
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