Peroxovanadium(V) complexes of -hydroxyhippuric acid. The X-ray
crystal structure of (NPr4)2[V2O2(O2)2(alpha-hhip)2] .5H2O,
[alpha-hhip=alpha-hydroxyhippurato (2-) - C9H7NO4 (2-)]

J 2004

Peroxovanadium(V) complexes of -hydroxyhippuric acid. The X-ray crystal structure of (NPr4)2[V2O2(O2)2(alpha-hhip)2] .5H2O, [alpha-hhip=alpha-hydroxyhippurato (2-) - C9H7NO4 (2-)]

SCHWENDT, P., M. AHMED a Jaromír MAREK

Základní údaje

Originální název

Peroxovanadium(V) complexes of -hydroxyhippuric acid. The X-ray crystal structure of (NPr4)2[V2O2(O2)2(alpha-hhip)2] .5H2O, [alpha-hhip=alpha-hydroxyhippurato (2-) - C9H7NO4 (2-)]

Název česky

Peroxovanadičnatý komplex kyseliny alfa-hydroxyhipurité. RTG struktura (NPr4)2[V2O2(O2)2(alpha-hhip)2] .5H2O, [alpha-hhip=alpha-hydroxyhippurato (2-) - C9H7NO4 (2-)].

Autoři

SCHWENDT, P. (703 Slovensko), M. AHMED (818 Egypt) a Jaromír MAREK (203 Česká republika, garant)

Vydání

Inorganic Chemistry Communications, Netherlands, Elsevier Science, 2004, 1387-7003

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10402 Inorganic and nuclear chemistry

Stát vydavatele

Portugalsko

Utajení

není předmětem státního či obchodního tajemství

Impakt faktor

Impact factor: 1.682

Kód RIV

RIV/00216224:14310/04:00010034

Organizační jednotka

Přírodovědecká fakulta

UT WoS

000221485800010

Klíčová slova anglicky

Peroxovanadium complexes; -hydroxyhippuric acid; IR and Raman spectroscopies; Crystal structure

Štítky

-hydroxyhippuric acid, Crystal Structure, IR and Raman spectroscopies, peroxovanadium complexes

Změněno: 10. 2. 2005 13:54, doc. RNDr. Jaromír Marek, Ph.D.

Anotace

ORIG CZ

V originále

Peroxovanadium(V) complexes of alpha-hydroxyhippuric acid (alpha-H2hhip), M2[V2O2(O2)2(alpha-hhip)2].nH2O [M=NMe4+ (1), NPr4+ (2); n=0.5, 5], have been prepared and characterized by elemental analysis and by IR and Raman spectroscopies. The X-ray crystal structure of 2 has been determined as the first crystal structure of an -hydroxyhippurato complex. A single crystal X-ray diffraction study has shown that the -hhip ligand behaves as a tridentate chelator adopting the (O-, COO-, CO) donor set. The coordination geometry of the vanadium atom is a distorted pentagonal bipyramid.

Česky

Peroxovanadičnatý komplex s kyselinou alfa-hydroxyhipuritou byl syntetizován a charakterizován element. analýzou, IR a Raman. spektroskopií a RTG trukturní analýzou. Jde o první RTG strukturu komplexu s touto kyselinou.

Návaznosti

MSM 143100008, záměr

Název: Genomy a jejich funkce

Investor: Ministerstvo školství, mládeže a tělovýchovy ČR, Genomy a jejich funkce

Citovat

SCHWENDT, P., M. AHMED a Jaromír MAREK. Peroxovanadium(V) complexes of -hydroxyhippuric acid. The X-ray crystal structure of (NPr4)2[V2O2(O2)2(alpha-hhip)2] .5H2O, [alpha-hhip=alpha-hydroxyhippurato (2-) - C9H7NO4 (2-)]. Inorganic Chemistry Communications. Netherlands: Elsevier Science, 2004, roč. 7, č. 5, s. 631-633. ISSN 1387-7003.

@article{554624,
   author = {Schwendt, P. and Ahmed, M. and Marek, Jaromír},
   article_location = {Netherlands},
   article_number = {5},
   keywords = {Peroxovanadium complexes; -hydroxyhippuric acid; IR and Raman spectroscopies; Crystal structure},
   language = {eng},
   issn = {1387-7003},
   journal = {Inorganic Chemistry Communications},
   title = {Peroxovanadium(V) complexes of -hydroxyhippuric acid. The X-ray crystal structure of (NPr4)2[V2O2(O2)2(alpha-hhip)2] .5H2O, [alpha-hhip=alpha-hydroxyhippurato (2-) - C9H7NO4 (2-)]},
   volume = {7},
   year = {2004}
}

TY  - JOUR
ID  - 554624
AU  - Schwendt, P. - Ahmed, M. - Marek, Jaromír
PY  - 2004
TI  - Peroxovanadium(V) complexes of -hydroxyhippuric acid. The X-ray crystal structure of (NPr4)2[V2O2(O2)2(alpha-hhip)2] .5H2O, [alpha-hhip=alpha-hydroxyhippurato (2-) - C9H7NO4 (2-)]
JF  - Inorganic Chemistry Communications
VL  - 7
IS  - 5
SP  - 631-633
EP  - 631-633
PB  - Elsevier Science
SN  - 13877003
KW  - Peroxovanadium complexes
KW  - -hydroxyhippuric acid
KW  - IR and Raman spectroscopies
KW  - Crystal structure
N2  - Peroxovanadium(V) complexes of alpha-hydroxyhippuric acid (alpha-H2hhip), M2[V2O2(O2)2(alpha-hhip)2].nH2O [M=NMe4+ (1), NPr4+ (2); n=0.5, 5], have been prepared and characterized by elemental analysis and by IR and Raman spectroscopies. The X-ray crystal structure of 2 has been determined as the first crystal structure of an -hydroxyhippurato complex. A single crystal X-ray diffraction study has shown that the -hhip ligand behaves as a tridentate chelator adopting the (O-, COO-, CO) donor set. The coordination geometry of the vanadium atom is a distorted pentagonal bipyramid.
ER  -

SCHWENDT, P., M. AHMED a Jaromír MAREK. Peroxovanadium(V) complexes of -hydroxyhippuric acid. The X-ray crystal structure of (NPr4)2[V2O2(O2)2(alpha-hhip)2] .5H2O, [alpha-hhip=alpha-hydroxyhippurato (2-) - C9H7NO4 (2-)]. \textit{Inorganic Chemistry Communications}. Netherlands: Elsevier Science, 2004, roč.~7, č.~5, s.~631-633. ISSN~1387-7003.

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