New Polyheteroatomic Cyclic Molecules Containing Elements of
the 13. - 16. Group

J 2004

New Polyheteroatomic Cyclic Molecules Containing Elements of the 13. - 16. Group

ZAK, Zdirad a Jan TARABA

Základní údaje

Originální název

New Polyheteroatomic Cyclic Molecules Containing Elements of the 13. - 16. Group

Název česky

Nové polyheteroatomické molekuly obsahující prvky 13. - 16. skupiny

Autoři

ZAK, Zdirad (203 Česká republika, garant) a Jan TARABA (203 Česká republika)

Vydání

Phosphorus, Sulfur, and Silicon and the related elements, The United States of America, Taylor and Francis Inc. 2004, 1042-6507

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10402 Inorganic and nuclear chemistry

Stát vydavatele

Česká republika

Utajení

není předmětem státního či obchodního tajemství

Impakt faktor

Impact factor: 0.426

Kód RIV

RIV/00216224:14310/04:00021218

Organizační jednotka

Přírodovědecká fakulta

UT WoS

000222008200034

Klíčová slova anglicky

Polyheterocycle; preparation; X-ray structure; NMR

Štítky

NMR, Polyheterocycle, Preparation, X-RAY STRUCTURE

Změněno: 25. 6. 2006 09:18, RNDr. Jan Taraba, Ph.D.

Anotace

ORIG CZ

V originále

During our studies of the reactions of -N(H)SiMe3 and -N(Me)SiMe3 derivatives of Cl3PNSO2Cl with acetonitrile and BCl3 we have obtained six-membered polyheteroatomic cycles -P(Cl2)NSO2(Cl)N(H)C(Me)Nand -P(Cl2)NS(O)(Cl)OB(Cl2)N(Me) [1,2]. In the system Ph2PCl3, H2NSO2Cl and HN(SiMe3)2 we have identified and isolated several P-N-S cycles, e.g. the reaction of Ph2PCl3 with H2NSO2Cl gives Ph2ClPNSO2Cl [3] which with HN(SiMe3)2 reacts to ĄS(O2)N(H)P(Ph)2N(H)SO2N(H)P(Ph)2N(H), ĄS(O2)N(H)S(O2)N(H)P(Ph)2N(H)P(Ph)2N(H)and Ą[S(O2)N(H)P(Ph)2NP(Ph)2N(H)]+Cl-; Ph2PCl3 with HN(SiMe3)2 gives N[P(Ph)2N(H)SiMe3]2+ Cl-, and H2NSO2Cl with HN(SiMe3)2 leads to SO2(NHSiMe3)2. The reaction of Ph2PCl3 with HN(SiMe3)2 gives N(P(Ph)2NHSiMe3)2Cl in a very good yield which was further used to syntheses of metal-containing heterocycles. By the reaction of N[P(Ph)2N(H)SiMe3]2+Cl- with some covalent halogenides we have obtained six-membered heterocycles containing B, As, In, and Sn. The same cyclic compounds can also obtained by the reaction of N[P(Ph2)NH2]2+Cl- or HN(P(R2)N(H)SiMe3)2 with covalent halogenides [4,5,6]. However, the synthetic route via N[P(Ph)2NHSiMe3]2+Cl- is more convenient and gives the compounds in almost quantitative yields. The identity of all compounds was unambiguously established by their X-ray structure determination.

Česky

Nové polyheteroatomické molekuly obsahující prvky 13. - 16. skupiny

Návaznosti

MSM 143100011, záměr

Název: Struktura a vazebné poměry, vlastnosti a analýza syntetických a přírodních molekulových ansamblů

Investor: Ministerstvo školství, mládeže a tělovýchovy ČR, Struktura a vazebné poměry, vlastnosti a analýza syntetických a přírodních molekulových ansamblů

Citovat

ZAK, Zdirad a Jan TARABA. New Polyheteroatomic Cyclic Molecules Containing Elements of the 13. - 16. Group. Phosphorus, Sulfur, and Silicon and the related elements. The United States of America: Taylor and Francis Inc., 2004, roč. 179/2004, 4-5, s. 839-843. ISSN 1042-6507.

@article{556373,
   author = {Zak, Zdirad and Taraba, Jan},
   article_location = {The United States of America},
   article_number = {4-5},
   keywords = {Polyheterocycle; preparation; X-ray structure; NMR},
   language = {eng},
   issn = {1042-6507},
   journal = {Phosphorus, Sulfur, and Silicon and the related elements},
   title = {New Polyheteroatomic Cyclic Molecules Containing Elements of the 13. - 16. Group},
   volume = {179/2004},
   year = {2004}
}

TY  - JOUR
ID  - 556373
AU  - Zak, Zdirad - Taraba, Jan
PY  - 2004
TI  - New Polyheteroatomic Cyclic Molecules Containing Elements of the 13. - 16. Group
JF  - Phosphorus, Sulfur, and Silicon and the related elements
VL  - 179/2004
IS  - 4-5
SP  - 839-843
EP  - 839-843
PB  - Taylor and Francis Inc.
SN  - 10426507
KW  - Polyheterocycle
KW  - preparation
KW  - X-ray structure
KW  - NMR
N2  - During our studies of the reactions of -N(H)SiMe3 and -N(Me)SiMe3 derivatives of Cl3PNSO2Cl with acetonitrile and BCl3 we have obtained six-membered polyheteroatomic cycles -P(Cl2)NSO2(Cl)N(H)C(Me)Nand -P(Cl2)NS(O)(Cl)OB(Cl2)N(Me) [1,2]. In the system Ph2PCl3, H2NSO2Cl and HN(SiMe3)2 we have identified and isolated several P-N-S cycles, e.g. the reaction of Ph2PCl3 with H2NSO2Cl gives Ph2ClPNSO2Cl [3] which with HN(SiMe3)2 reacts to ĄS(O2)N(H)P(Ph)2N(H)SO2N(H)P(Ph)2N(H), ĄS(O2)N(H)S(O2)N(H)P(Ph)2N(H)P(Ph)2N(H)and Ą[S(O2)N(H)P(Ph)2NP(Ph)2N(H)]+Cl-; Ph2PCl3 with HN(SiMe3)2 gives N[P(Ph)2N(H)SiMe3]2+ Cl-, and H2NSO2Cl with HN(SiMe3)2 leads to SO2(NHSiMe3)2. The reaction of Ph2PCl3 with HN(SiMe3)2 gives N(P(Ph)2NHSiMe3)2Cl in a very good yield which was further used to syntheses of metal-containing heterocycles. By the reaction of N[P(Ph)2N(H)SiMe3]2+Cl- with some covalent halogenides we have obtained six-membered heterocycles containing B, As, In, and Sn. The same cyclic compounds can also obtained by the reaction of N[P(Ph2)NH2]2+Cl- or HN(P(R2)N(H)SiMe3)2 with covalent halogenides [4,5,6]. However, the synthetic route via N[P(Ph)2NHSiMe3]2+Cl- is more convenient and gives the compounds in almost quantitative yields. The identity of all compounds was unambiguously established by their X-ray structure determination.
ER  -

ZAK, Zdirad a Jan TARABA. New Polyheteroatomic Cyclic Molecules Containing Elements of the 13. - 16. Group. \textit{Phosphorus, Sulfur, and Silicon and the related elements}. The United States of America: Taylor and Francis Inc., 2004, roč.~179/2004, 4-5, s.~839-843. ISSN~1042-6507.

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