Detailed Information on Publication Record
2005
Spectroscopic Characterization of Eu(III) Complexes with New Monophosphorus Acid Derivatives of H4dota
TÁBORSKÝ, Petr, Ivona SVOBODOVÁ, Zbigniew HNATEJKO, Premysl LUBAL, Stefan LIS et. al.Basic information
Original name
Spectroscopic Characterization of Eu(III) Complexes with New Monophosphorus Acid Derivatives of H4dota
Name in Czech
Spektrální charakterizace Eu(III) komplex s novými analogy H4dota obsahujících fosfonovou skupinu
Authors
TÁBORSKÝ, Petr (203 Czech Republic, guarantor), Ivona SVOBODOVÁ (203 Czech Republic), Zbigniew HNATEJKO (616 Poland), Premysl LUBAL (203 Czech Republic), Stefan LIS (616 Poland), Michaela FÖRSTEROVÁ (203 Czech Republic), Petr HERMANN (203 Czech Republic), Ivan LUKEŠ (203 Czech Republic) and Josef HAVEL (203 Czech Republic)
Edition
Journal of fluorescence, 2005, 1053-0509
Other information
Language
English
Type of outcome
Článek v odborném periodiku
Field of Study
10406 Analytical chemistry
Country of publisher
Czech Republic
Confidentiality degree
není předmětem státního či obchodního tajemství
Impact factor
Impact factor: 2.038
RIV identification code
RIV/00216224:14310/05:00012918
Organization unit
Faculty of Science
UT WoS
000231940700007
Keywords in English
Macrocyclic DOTA-like ligands; phosphonate and phosphinate Eu(III) complexes; hydration
Změněno: 8/4/2010 20:03, prof. RNDr. Přemysl Lubal, Ph.D.
V originále
The luminescence lifetimes of europium(III) complexes with new monophosphorus acid derivatives of H4dota were measured by means of time-resolved laser-induced luminescence spectroscopy in H2O and D2O. The hydration numbers of these complexes were estimated using different empirical equations [Horrocks and Sudnick (1979) J. Am. Chem. Soc. 101 (1979) 334; Choppin and Barthelemy(1989) Inorg. Chem. 28, 33543357; Choppin and Bunzli Lanthanide probes in life, chemical and earth sciences. Theory and practice (1989); Kimura and Kato J. Alloys Comp. 275277 (1998) 806; Parker (1999) J. Chem. Soc., Perkin Trans. 2, 493503; Supkowski and Horroks (2002) Inorg. Chim. Acta. 340, 4448]. It was shown that all the relationships gave similar results with a satisfactory precision. The hydration numbers of complexes of H3do3a and H4dota agreed with the literature values. One water molecule is coordinated in complexes of the new ligands.
In Czech
Pomocí časově rozlišené laserem indukované luminiscenční spektroskopie byly změřeny časy vyhasínání nových Eu(III) komplexů s analogy ligandu H4DOTA obsahujícími fosfonovou skupinu v H2O a D2O. S použitím empirických rovnic popsaných v literratuře ([Horrocks and Sudnick (1979) J. Am. Chem. Soc. 101 (1979) 334; Choppin and Barthelemy(1989) Inorg. Chem. 28, 33543357; Choppin and Bunzli Lanthanide probes in life, chemical and earth sciences. Theory and practice (1989); Kimura and Kato J. Alloys Comp. 275277 (1998) 806; Parker (1999) J. Chem. Soc., Perkin Trans. 2, 493503; Supkowski and Horroks (2002) Inorg. Chim. Acta. 340, 4448]) byly odhadnuty počty molekul vod (q) obsažených ve vnitřní sféře komplexu.
Links
| GA203/02/0493, research and development project |
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| GA203/03/0168, research and development project |
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| OC D18.001, research and development project |
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