Structure-property relationships in novel
poly(imide-amide)-poly(ethylene glycol) hybrid networks

J 2006

Structure-property relationships in novel poly(imide-amide)-poly(ethylene glycol) hybrid networks

KRIPOTOU, S.; P. PISSIS; Petr SYSEL; Vladimír ŠINDELÁŘ; V. A. BERSHTEIN et al.

Základní údaje

Originální název

Structure-property relationships in novel poly(imide-amide)-poly(ethylene glycol) hybrid networks

Název česky

Vztah mezi strukturou a vlastnostmi nových hybridních sítí na bázi poly(imid-amid)-poly(ethylen glykol)

Autoři

KRIPOTOU, S.; P. PISSIS; Petr SYSEL; Vladimír ŠINDELÁŘ a V. A. BERSHTEIN

Vydání

Polymer, Amsterdam, Elsevier, 2006, 0032-3861

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10404 Polymer science

Stát vydavatele

Česká republika

Utajení

není předmětem státního či obchodního tajemství

Impakt faktor

Impact factor: 2.773

Označené pro přenos do RIV

Ano

Kód RIV

RIV/00216224:14310/06:00016589

Organizační jednotka

Přírodovědecká fakulta

UT WoS

000234617600047

Klíčová slova anglicky

DRS;TSDC;hybrid networks

Štítky

DRS, hybrid networks, TSDC

Příznaky

Mezinárodní význam, Recenzováno

Změněno: 5. 2. 2010 15:20, prof. Ing. Vladimír Šindelář, Ph.D.

Anotace

ORIG CZ

V originále

Broadband dielec. relaxation spectroscopy (DRS), thermally stimulated depolarisation currents (TSDC), differential scanning calorimetry (DSC) and to a lesser extent water uptake measurements, were employed to investigate mol. mobility, morphol. and crystn./melting events of PEG in poly(imide-amide)-polyethylene glycol hybrid networks (PIA-PEG) with short (M n=1000 g/mol) and long (M n=3400 g/mol) PEG crosslinks. The results obtained suggest long range connectivity of the PEG component in the hybrids with short PEG crosslinks at PEG content higher than 40 wt% and in these with long PEG crosslinks at PEG content higher than 20 wt%. Crystn. of the PEG component is obsd. by DSC in the hybrids with the longer crosslinks at sufficiently high content of PEG, only. The glass transition temp., T g, of PEG component in the hybrids with the shorter PEG crosslinks is shifted to higher temps. compared to that of the hybrids with longer PEG crosslinks, while suppression of the glass transition of the PEG component is obsd. in the hybrids with the shorter PEG crosslinks at PEG content lower than 40 wt%. The results are discussed in terms of constraints to segmental motion of the PEG crosslinks, imposed by fixed PEG chain ends on the rigid PI chains.

Česky

Vztah mezi strukturou a vlastnostmi nových hybridních sítí na bázi poly(imid-amid)-poly(ethylen glykol)byl studován pomocí širokopásové dielektrické relaxační spektroskopie(DRS), termicky stimulovaného depolarizačního proudu (TSDC) a diferenciální snímací kalorimetrie (DSC).

Citovat

KRIPOTOU, S.; P. PISSIS; Petr SYSEL; Vladimír ŠINDELÁŘ a V. A. BERSHTEIN. Structure-property relationships in novel poly(imide-amide)-poly(ethylene glycol) hybrid networks. Polymer. Amsterdam: Elsevier, 2006, roč. 47, č. 1, s. 357-366. ISSN 0032-3861.

@article{601384,
   author = {Kripotou, S. and Pissis, P. and Sysel, Petr and Šindelář, Vladimír and Bershtein, V. A.},
   article_location = {Amsterdam},
   article_number = {1},
   keywords = {DRS;TSDC;hybrid networks},
   language = {eng},
   issn = {0032-3861},
   journal = {Polymer},
   title = {Structure-property relationships in novel poly(imide-amide)-poly(ethylene glycol) hybrid networks},
   volume = {47},
   year = {2006}
}

TY  - JOUR
ID  - 601384
AU  - Kripotou, S. - Pissis, P. - Sysel, Petr - Šindelář, Vladimír - Bershtein, V. A.
PY  - 2006
TI  - Structure-property relationships in novel poly(imide-amide)-poly(ethylene glycol) hybrid networks
JF  - Polymer
VL  - 47
IS  - 1
SP  - 357-366
EP  - 357-366
PB  - Elsevier
SN  - 00323861
KW  - DRS;TSDC;hybrid networks
N2  - Broadband dielec. relaxation spectroscopy (DRS), thermally stimulated depolarisation currents (TSDC), differential scanning calorimetry (DSC) and to a lesser extent water uptake measurements, were employed to investigate mol. mobility, morphol. and crystn./melting events of PEG in poly(imide-amide)-polyethylene glycol hybrid networks (PIA-PEG) with short (M n=1000 g/mol) and long (M n=3400 g/mol) PEG crosslinks. The results obtained suggest long range connectivity of the PEG component in the hybrids with short PEG crosslinks at PEG content higher than 40 wt% and in these with long PEG crosslinks at PEG content higher than 20 wt%. Crystn. of the PEG component is obsd. by DSC in the hybrids with the longer crosslinks at sufficiently high content of PEG, only. The glass transition temp., T g, of PEG component in the hybrids with the shorter PEG crosslinks is shifted to higher temps. compared to that of the hybrids with longer PEG crosslinks, while suppression of the glass transition of the PEG component is obsd. in the hybrids with the shorter PEG crosslinks at PEG content lower than 40 wt%. The results are discussed in terms of constraints to segmental motion of the PEG crosslinks, imposed by fixed PEG chain ends on the rigid PI chains.
ER  -

KRIPOTOU, S.; P. PISSIS; Petr SYSEL; Vladimír ŠINDELÁŘ a V. A. BERSHTEIN. Structure-property relationships in novel poly(imide-amide)-poly(ethylene glycol) hybrid networks. \textit{Polymer}. Amsterdam: Elsevier, 2006, roč.~47, č.~1, s.~357-366. ISSN~0032-3861.

Přehled o publikaci