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@inproceedings{694472,
author = {Pinkas, Jiří and Löbl, Jiří and Nečas, Marek},
address = {Oulu, Finland},
booktitle = {11th International Symposium on Inorganic Ring Systems},
edition = {1},
keywords = {Alumazene; dealkylsilylation; phosphonates;},
language = {eng},
location = {Oulu, Finland},
isbn = {951-42-8153-5},
pages = {25-25},
publisher = {University of Oulu, Oulu, Finland},
title = {Alumazene in dealkylsilylation reactions with E-O-SiMe3 compounds},
year = {2006}
}
TY - JOUR
ID - 694472
AU - Pinkas, Jiří - Löbl, Jiří - Nečas, Marek
PY - 2006
TI - Alumazene in dealkylsilylation reactions with E-O-SiMe3 compounds
PB - University of Oulu, Oulu, Finland
CY - Oulu, Finland
SN - 9514281535
KW - Alumazene
KW - dealkylsilylation
KW - phosphonates;
N2 - Alumazene, [2,6-(i-Pr)2C6H3NAlMe]3, is the only known trimeric iminoalane. Its high reactivity stems from the polar Al-N bonds and a low delocalization of the pi electrons in the ring. We studied the mild dealkylsilylation reaction of alumazene with a variety of trimethylsiloxy compounds of silicon, phosphorus, and sulfur with the aim of obtaining new polycyclic and polyhedral derivatives. During these studies we also prepared adducts of phosphine oxides and other Lewis bases with alumazene and established their molecular structures.
ER -
PINKAS, Jiří, Jiří LÖBL a Marek NEČAS. Alumazene in dealkylsilylation reactions with E-O-SiMe3 compounds. In \textit{11th International Symposium on Inorganic Ring Systems}. 1. vyd. Oulu, Finland: University of Oulu, Oulu, Finland, 2006, s.~25. ISBN~951-42-8153-5.
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