Structural variability of
copper-1,10-phenanthroline–oxovanadate hybrid inorganic–organic
compounds

J 2006

Structural variability of copper-1,10-phenanthroline–oxovanadate hybrid inorganic–organic compounds

JONIAKOVÁ, D.; R. GYEPES; E. RAKOVSKÝ; P. SCHWENDT; L. ŽÚRKOVÁ et al.

Základní údaje

Originální název

Structural variability of copper-1,10-phenanthroline–oxovanadate hybrid inorganic–organic compounds

Název česky

Strukturní variabilita hybridních organicko-anorganických měďnato-oxovanadičnatých komplexů

Autoři

JONIAKOVÁ, D.; R. GYEPES; E. RAKOVSKÝ; P. SCHWENDT; L. ŽÚRKOVÁ; Jaromír MAREK a Z. MIČKA

Vydání

Polyhedron, Velká Británie, Elsevier Science Ltd. 2006, 0277-5387

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10402 Inorganic and nuclear chemistry

Stát vydavatele

Velká Británie a Severní Irsko

Utajení

není předmětem státního či obchodního tajemství

Impakt faktor

Impact factor: 1.843

Označené pro přenos do RIV

Ano

Kód RIV

RIV/00216224:14310/06:00017824

Organizační jednotka

Přírodovědecká fakulta

UT WoS

000240578300002

Klíčová slova anglicky

Crystal structures; Copper–phenanthroline oxovanadates; Hybrid inorganic–organic compounds; IR spectra

Štítky

Copper–phenanthroline oxovanadates, crystal structures, Hybrid inorganic–organic compounds, IR spectra

Příznaky

Recenzováno

Změněno: 12. 12. 2006 10:00, doc. RNDr. Jaromír Marek, Ph.D.

Anotace

ORIG CZ

V originále

Reactions in the CuSO4–phen–KVO3–H2O–(KOH) systems under non-hydrothermal conditions yielded seven new compounds: [Cu2(H2O)2(OH)2(phen)2][Cu2(OH)2(phen)2(V4O12)].6H2O (3), [Cu2(phen)4(V4O12)].4H2O (4), [Cu2(phen)4(V4O12)].6H2O (5), [Cu2(phen)4(VO3)4].10H2O (6), [Cu(phen)3]2V4O12.phen.22H2O (7), [Cu(phen)(VO3)2] (9) and [Cu2(phen)4(V4O12)].4H2O (12). The prepared compounds were characterized by elemental analyses and IR spectra. The characteristic bands in the IR spectra corresponding to the V–O stretching modes enabled the different oxovanadate groups present in the structures to be unequivocally distinguished. Compounds 3, 4, 5, 6, 7 and 12 were characterized by X-ray single crystal diffraction. The structure of compound 3 consists of isolated dinuclear [(phen)(H2O)Cu(mu-OH)2Cu(phen)(H2O)]2+ ions and [(phen)Cu(OH)2Cu(phen)]2+ moieties attached to Click to view the MathML source rings. The structures of compounds 4, 5 and 12 contain [Cu2(phen)4(V4O12)] clusters with different bonding modes of Click to view the MathML source and Click to view the MathML source moieties. The structure of compound 7 is constructed by isolated [Cu(phen)3]2+ and Click to view the MathML source ions as well as molecules of uncoordinated 1,10-phenanthroline and water of crystallization, while a polymeric structure containing Click to view the MathML source chains, to which Click to view the MathML source fragments are attached through Cu–O bonds, was found for 6.

Česky

Metodami monokrystalové RTG difrakce na 7 nových sloučeninách, [Cu2(H2O)2(OH)2(phen)2] [Cu2(OH)2(phen)2(V4O12)].6H2O, [Cu2(phen)4(V4O12)].4H2O, [Cu2(phen)4(V4O12)].6H2O, [Cu2(phen)4(VO3)4].10H2O, [Cu(phen)3]2V4O12.phen.22H2O, [Cu(phen)(VO3)2] a [Cu2(phen)4(V4O12)].4H2O, byla popsána strukturní variabilita vzájemných vazebných interakcí mezi kationovou a anionovou částí studovaných komplexů.

Návaznosti

MSM0021622415, záměr

Název: Molekulární podstata buněčných a tkáňových regulací

Investor: Ministerstvo školství, mládeže a tělovýchovy ČR, Molekulární podstata buněčných a tkáňových regulací

Citovat

JONIAKOVÁ, D.; R. GYEPES; E. RAKOVSKÝ; P. SCHWENDT; L. ŽÚRKOVÁ; Jaromír MAREK a Z. MIČKA. Structural variability of copper-1,10-phenanthroline–oxovanadate hybrid inorganic–organic compounds. Polyhedron. Velká Británie: Elsevier Science Ltd., 2006, roč. 25, č. 13, s. 2491-2502. ISSN 0277-5387.

@article{705043,
   author = {Joniaková, D. and Gyepes, R. and Rakovský, E. and Schwendt, P. and Žúrková, L. and Marek, Jaromír and Mička, Z.},
   article_location = {Velká Británie},
   article_number = {13},
   keywords = {Crystal structures; Copper–phenanthroline oxovanadates; Hybrid inorganic–organic compounds; IR spectra},
   language = {eng},
   issn = {0277-5387},
   journal = {Polyhedron},
   title = {Structural variability of copper-1,10-phenanthroline–oxovanadate hybrid inorganic–organic compounds},
   volume = {25},
   year = {2006}
}

TY  - JOUR
ID  - 705043
AU  - Joniaková, D. - Gyepes, R. - Rakovský, E. - Schwendt, P. - Žúrková, L. - Marek, Jaromír - Mička, Z.
PY  - 2006
TI  - Structural variability of copper-1,10-phenanthroline–oxovanadate hybrid inorganic–organic compounds
JF  - Polyhedron
VL  - 25
IS  - 13
SP  - 2491-2502
EP  - 2491-2502
PB  - Elsevier Science Ltd.
SN  - 02775387
KW  - Crystal structures
KW  - Copper–phenanthroline oxovanadates
KW  - Hybrid inorganic–organic compounds
KW  - IR spectra
N2  - Reactions in the CuSO4–phen–KVO3–H2O–(KOH) systems under non-hydrothermal conditions yielded seven new compounds: [Cu2(H2O)2(OH)2(phen)2][Cu2(OH)2(phen)2(V4O12)].6H2O (3), [Cu2(phen)4(V4O12)].4H2O (4), [Cu2(phen)4(V4O12)].6H2O (5), [Cu2(phen)4(VO3)4].10H2O (6), [Cu(phen)3]2V4O12.phen.22H2O (7), [Cu(phen)(VO3)2] (9) and [Cu2(phen)4(V4O12)].4H2O (12). The prepared compounds were characterized by elemental analyses and IR spectra. The characteristic bands in the IR spectra corresponding to the V–O stretching modes enabled the different oxovanadate groups present in the structures to be unequivocally distinguished. Compounds 3, 4, 5, 6, 7 and 12 were characterized by X-ray single crystal diffraction. The structure of compound 3 consists of isolated dinuclear [(phen)(H2O)Cu(mu-OH)2Cu(phen)(H2O)]2+ ions and [(phen)Cu(OH)2Cu(phen)]2+ moieties attached to Click to view the MathML source rings. The structures of compounds 4, 5 and 12 contain [Cu2(phen)4(V4O12)] clusters with different bonding modes of Click to view the MathML source and Click to view the MathML source moieties. The structure of compound 7 is constructed by isolated [Cu(phen)3]2+ and Click to view the MathML source ions as well as molecules of uncoordinated 1,10-phenanthroline and water of crystallization, while a polymeric structure containing Click to view the MathML source chains, to which Click to view the MathML source fragments are attached through Cu–O bonds, was found for 6.
ER  -

JONIAKOVÁ, D.; R. GYEPES; E. RAKOVSKÝ; P. SCHWENDT; L. ŽÚRKOVÁ; Jaromír MAREK a Z. MIČKA. Structural variability of copper-1,10-phenanthroline–oxovanadate hybrid inorganic–organic compounds. \textit{Polyhedron}. Velká Británie: Elsevier Science Ltd., 2006, roč.~25, č.~13, s.~2491-2502. ISSN~0277-5387.

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