New isostructural ethylenediammonium diphosphates
(NH3(CH2)2NH3)2[Me(HP2O7)2 · 2 H2O] [Me = Co, Ni]: X-ray
crystal structure and vibrational spectroscopy

J 2006

New isostructural ethylenediammonium diphosphates (NH3(CH2)2NH3)2[Me(HP2O7)2 · 2 H2O] [Me = Co, Ni]: X-ray crystal structure and vibrational spectroscopy

CAPITELLI, Francesco; Jan TARABA; Brahim EL BALI; Zdirad ŽÁK; Rachid ESSEHLI et. al.

Základní údaje

Originální název

New isostructural ethylenediammonium diphosphates (NH3(CH2)2NH3)2[Me(HP2O7)2 · 2 H2O] [Me = Co, Ni]: X-ray crystal structure and vibrational spectroscopy

Název česky

Nový isostrukturní ethylendiamonium difosforečnan (NH3(CH2)2NH3)2[Me(HP2O7)2 * 2 H2O] [Me = Co, Ni]: Rtg. strukturí analýza a viblační spektra

Autoři

CAPITELLI, Francesco; Jan TARABA; Brahim EL BALI; Zdirad ŽÁK; Rachid ESSEHLI; Mohammed LACHKAR; Veronica VALENTINI a Giorgio MATTEI

Vydání

Zeitschrift für Kristallographie, Mnichov, R. Oldenbourg Verlag, 2006, 0044-2968

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10402 Inorganic and nuclear chemistry

Stát vydavatele

Itálie

Utajení

není předmětem státního či obchodního tajemství

Impakt faktor

Impact factor: 1.897

Kód RIV

RIV/00216224:14310/06:00018630

Organizační jednotka

Přírodovědecká fakulta

UT WoS

000240862500005

Klíčová slova anglicky

diphosphate; ethylenediammonium; Raman and infrared spectroscopy; X-ray diffraction; single crystal structure analysis

Štítky

diphosphate, ethylenediammonium, Raman and infrared spectroscopy, single crystal structure analysis, X-ray diffraction

Příznaky

Mezinárodní význam, Recenzováno

Změněno: 23. 3. 2007 13:55, RNDr. Jan Taraba, Ph.D.

Anotace

ORIG CZ

V originále

New ethylenediammonium diphosphates (NH3(CH2)(2)NH3)(2)[Me(HP2O7)(2) center dot 2H(2)O] [Me = Co (1), Ni (2)] have been synthesized and investigated by single-crystal X-ray diffractometry. The two structures resulted to be isostructural within triclinic space group PT The unit-cell parameters are: a = 7.5211(6) A, b = 7.5574(3) angstrom, c = 9.7689(7) angstrom, a = 103.6(1)degrees, beta = 111.14(1)degrees, gamma = 98.04(1)degrees, V = 486.9(l) angstrom(3) (1) and a = 7.4631(15) angstrom, b = 7.5274(12) angstrom, c = 9.743(3) angstrom, alpha = 104.28(2)degrees, beta = 110.75(2)degrees, gamma = 97.50(2)degrees, V = 481.4(2) angstrom(3) (2). The three-dimensional network is built up by discrete Me(HP2O7)(2) center dot 2H(2)O moieties, which, via strong O-H center dot center dot center dot O bonds, form layers parallel to ab plane. Ethylenediammonium groups are located between such layers, stabilizing the framework via N-H center dot center dot center dot O bonds. The hydrogendiphosphate group presents bent eclipsed conformation, while the Me ion lies on inversion centre. The structural data, as the bent POP configuration, have been confirmed by the Raman and infrared spectra of the title compounds. In particular, the non-coincidence between the infrared and Raman bands supports the centrosymmetric structure of the investigated crystals.

Česky

Nový isostrukturní ethylendiamonium difosforečnan (NH3(CH2)2NH3)2[Me(HP2O7)2 * 2 H2O] [Me = Co, Ni]: Rtg. strukturí analýza a viblační spektra

Návaznosti

MSM 143100011, záměr

Název: Struktura a vazebné poměry, vlastnosti a analýza syntetických a přírodních molekulových ansamblů

Investor: Ministerstvo školství, mládeže a tělovýchovy ČR, Struktura a vazebné poměry, vlastnosti a analýza syntetických a přírodních molekulových ansamblů

Citovat

CAPITELLI, Francesco; Jan TARABA; Brahim EL BALI; Zdirad ŽÁK; Rachid ESSEHLI; Mohammed LACHKAR; Veronica VALENTINI a Giorgio MATTEI. New isostructural ethylenediammonium diphosphates (NH3(CH2)2NH3)2[Me(HP2O7)2 · 2 H2O] [Me = Co, Ni]: X-ray crystal structure and vibrational spectroscopy. Zeitschrift für Kristallographie. Mnichov: R. Oldenbourg Verlag, 2006, roč. 9/2006, č. 221, s. 649-655. ISSN 0044-2968.

@article{715079,
   author = {Capitelli, Francesco and Taraba, Jan and El Bali, Brahim and Žák, Zdirad and Essehli, Rachid and Lachkar, Mohammed and Valentini, Veronica and Mattei, Giorgio},
   article_location = {Mnichov},
   article_number = {221},
   keywords = {diphosphate; ethylenediammonium; Raman and infrared spectroscopy; X-ray diffraction; single crystal structure analysis},
   language = {eng},
   issn = {0044-2968},
   journal = {Zeitschrift für Kristallographie},
   title = {New isostructural ethylenediammonium diphosphates (NH3(CH2)2NH3)2[Me(HP2O7)2 · 2 H2O] [Me = Co, Ni]: X-ray crystal structure and vibrational spectroscopy},
   volume = {9/2006},
   year = {2006}
}

TY  - JOUR
ID  - 715079
AU  - Capitelli, Francesco - Taraba, Jan - El Bali, Brahim - Žák, Zdirad - Essehli, Rachid - Lachkar, Mohammed - Valentini, Veronica - Mattei, Giorgio
PY  - 2006
TI  - New isostructural ethylenediammonium diphosphates (NH3(CH2)2NH3)2[Me(HP2O7)2 · 2 H2O] [Me = Co, Ni]: X-ray crystal structure and vibrational spectroscopy
JF  - Zeitschrift für Kristallographie
VL  - 9/2006
IS  - 221
SP  - 649-655
EP  - 649-655
PB  - R. Oldenbourg Verlag
SN  - 00442968
KW  - diphosphate
KW  - ethylenediammonium
KW  - Raman and infrared spectroscopy
KW  - X-ray diffraction
KW  - single crystal structure analysis
N2  - New ethylenediammonium diphosphates (NH3(CH2)(2)NH3)(2)[Me(HP2O7)(2) center dot 2H(2)O] [Me = Co (1), Ni (2)] have been synthesized and investigated by single-crystal X-ray diffractometry. The two structures resulted to be isostructural within triclinic space group PT The unit-cell parameters are: a = 7.5211(6) A, b = 7.5574(3) angstrom, c = 9.7689(7) angstrom, a = 103.6(1)degrees, beta = 111.14(1)degrees, gamma = 98.04(1)degrees, V = 486.9(l) angstrom(3) (1) and a = 7.4631(15) angstrom, b = 7.5274(12) angstrom, c = 9.743(3) angstrom, alpha = 104.28(2)degrees, beta = 110.75(2)degrees, gamma = 97.50(2)degrees, V = 481.4(2) angstrom(3) (2). The three-dimensional network is built up by discrete Me(HP2O7)(2) center dot 2H(2)O moieties, which, via strong O-H center dot center dot center dot O bonds, form layers parallel to ab plane. Ethylenediammonium groups are located between such layers, stabilizing the framework via N-H center dot center dot center dot O bonds. The hydrogendiphosphate group presents bent eclipsed conformation, while the Me ion lies on inversion centre. The structural data, as the bent POP configuration, have been confirmed by the Raman and infrared spectra of the title compounds. In particular, the non-coincidence between the infrared and Raman bands supports the centrosymmetric structure of the investigated crystals.
ER  -

CAPITELLI, Francesco; Jan TARABA; Brahim EL BALI; Zdirad ŽÁK; Rachid ESSEHLI; Mohammed LACHKAR; Veronica VALENTINI a Giorgio MATTEI. New isostructural ethylenediammonium diphosphates (NH3(CH2)2NH3)2[Me(HP2O7)2 · 2 H2O] [Me = Co, Ni]: X-ray crystal structure and vibrational spectroscopy. \textit{Zeitschrift für Kristallographie}. Mnichov: R. Oldenbourg Verlag, 2006, roč.~9/2006, č.~221, s.~649-655. ISSN~0044-2968.

Přehled o publikaci