Use of multi-N-donor ligands for preparation of
organic-inorganic hybrid materials: Crystal structures of ionic
[M(aepn)2][Ni(CN)4].H2O and polymeric M(aepn)Ni(CN)4 (M =
Zn(II), Cd(II); aepn = N-(2-aminoethyl)-1,3-propanediamine)

J 2007

Use of multi-N-donor ligands for preparation of organic-inorganic hybrid materials: Crystal structures of ionic [M(aepn)2][Ni(CN)4].H2O and polymeric M(aepn)Ni(CN)4 (M = Zn(II), Cd(II); aepn = N-(2-aminoethyl)-1,3-propanediamine)

PAHAROVÁ, J.; J. ČERNÁK; Zdirad ŽÁK a Jaromír MAREK

Základní údaje

Originální název

Use of multi-N-donor ligands for preparation of organic-inorganic hybrid materials: Crystal structures of ionic [M(aepn)2][Ni(CN)4].H2O and polymeric M(aepn)Ni(CN)4 (M = Zn(II), Cd(II); aepn = N-(2-aminoethyl)-1,3-propanediamine)

Název česky

Užití násobných N-dovorových ligandů k přípravě hybridních organicko-anorganických materiálů: Krystalové struktury [M(aepn)2][Ni(CN)4].H2O a M(aepn)Ni(CN)4 (M = Zn(II), Cd(II); aepn = N-(2-aminoethyl)-1,3-propanediamine)

Autoři

PAHAROVÁ, J.; J. ČERNÁK; Zdirad ŽÁK a Jaromír MAREK

Vydání

Journal of Molecular Structure, U.K. Elsevier Science, 2007, 0022-2860

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10402 Inorganic and nuclear chemistry

Stát vydavatele

Velká Británie a Severní Irsko

Utajení

není předmětem státního či obchodního tajemství

Impakt faktor

Impact factor: 1.486

Kód RIV

RIV/00216224:14310/07:00022526

Organizační jednotka

Přírodovědecká fakulta

UT WoS

000250156700016

Klíčová slova anglicky

Tetracyanonickellate; Cadmium; Zinc; Crystal structure; Cyanocomplex; Multi N donor ligands

Štítky

cadmium, Crystal Structure, cyanocomplex, Multi N donor ligands, Tetracyanonickellate, zinc

Příznaky

Recenzováno

Změněno: 6. 9. 2007 11:00, doc. RNDr. Jaromír Marek, Ph.D.

Anotace

ORIG CZ

V originále

From aqueous systems M-aepn-[Ni(CN)4]2- (M = Zn, Cd; aepn = [N-(2-aminoethyl)-1,3-propanediamine]) using variable M: aepn molar ratios [Cd(aepn)2] [Ni(CN)4].H2O (1), Cd(aepn)Ni(CN)4 (2), [Zn(aepn)2][Ni(CN)4].H2O (3) and Zn(aepn)Ni(CN)4 (4) have been prepared and identified. Single crystal X-ray structure analyses have shown that the crystal structures of 1 and 3 are ionic and are built up of [Zn(aepn)2]2+ and [Cd(aepn)2]2+ cations, respectively, [Ni(CN)4]2- anions and water molecules of crystallisation, and 2 and 4 exhibit polymeric structures. In the three-dimensional structure of 2 two crystallographically independent tetracyanonickellate anions are placed on inversion centres and exhibit connectivities two and four, respectively, with bridging cyano groups linking cadmium and nickel atoms. Octahedrally coordinated cadmium atom exhibits connectivity three. In one-dimensional structure of 4 [Ni(CN)4]2- anions and [Zn(aepn)]2+ cations are linked via bridging cyano ligands. Both building species exhibits connectivity two. One chelate bonded aepn ligand blocks three coordination sites on the penta-coordinated Zn(II) atom.

Česky

Titulní sloučeniny byly připraveny z vodného systému M-aepn-[Ni(CN)4]2- (M = Zn, Cd; aepn = [N-(2-aminoethyl)-1,3-propanediamine]) za použití rozličných molár. poměrů M:aepn. Supramolekulární kontakty, do kterých se vzniklé komplexy zapojují, byly studovány metodami rtg strukturní krystalografie.

Návaznosti

MSM0021622415, záměr

Název: Molekulární podstata buněčných a tkáňových regulací

Investor: Ministerstvo školství, mládeže a tělovýchovy ČR, Molekulární podstata buněčných a tkáňových regulací

Citovat

PAHAROVÁ, J.; J. ČERNÁK; Zdirad ŽÁK a Jaromír MAREK. Use of multi-N-donor ligands for preparation of organic-inorganic hybrid materials: Crystal structures of ionic [M(aepn)2][Ni(CN)4].H2O and polymeric M(aepn)Ni(CN)4 (M = Zn(II), Cd(II); aepn = N-(2-aminoethyl)-1,3-propanediamine). Journal of Molecular Structure. U.K.: Elsevier Science, 2007, roč. 842, 1-3, s. 117-124. ISSN 0022-2860.

@article{724210,
   author = {Paharová, J. and Černák, J. and Žák, Zdirad and Marek, Jaromír},
   article_location = {U.K.},
   article_number = {1-3},
   keywords = {Tetracyanonickellate; Cadmium; Zinc; Crystal structure; Cyanocomplex; Multi N donor ligands},
   language = {eng},
   issn = {0022-2860},
   journal = {Journal of Molecular Structure},
   title = {Use of multi-N-donor ligands for preparation of organic-inorganic hybrid materials: Crystal structures of ionic [M(aepn)2][Ni(CN)4].H2O and polymeric M(aepn)Ni(CN)4 (M = Zn(II), Cd(II); aepn = N-(2-aminoethyl)-1,3-propanediamine)},
   volume = {842},
   year = {2007}
}

TY  - JOUR
ID  - 724210
AU  - Paharová, J. - Černák, J. - Žák, Zdirad - Marek, Jaromír
PY  - 2007
TI  - Use of multi-N-donor ligands for preparation of organic-inorganic hybrid materials: Crystal structures of ionic [M(aepn)2][Ni(CN)4].H2O and polymeric M(aepn)Ni(CN)4 (M = Zn(II), Cd(II); aepn = N-(2-aminoethyl)-1,3-propanediamine)
JF  - Journal of Molecular Structure
VL  - 842
IS  - 1-3
SP  - 117-124
EP  - 117-124
PB  - Elsevier Science
SN  - 00222860
KW  - Tetracyanonickellate
KW  - Cadmium
KW  - Zinc
KW  - Crystal structure
KW  - Cyanocomplex
KW  - Multi N donor ligands
N2  - From aqueous systems M-aepn-[Ni(CN)4]2- (M = Zn, Cd; aepn = [N-(2-aminoethyl)-1,3-propanediamine]) using variable M: aepn molar ratios [Cd(aepn)2] [Ni(CN)4].H2O (1), Cd(aepn)Ni(CN)4 (2), [Zn(aepn)2][Ni(CN)4].H2O (3) and Zn(aepn)Ni(CN)4 (4) have been prepared and identified. Single crystal X-ray structure analyses have shown that the crystal structures of 1 and 3 are ionic and are built up of [Zn(aepn)2]2+ and [Cd(aepn)2]2+ cations, respectively, [Ni(CN)4]2- anions and water molecules of crystallisation, and 2 and 4 exhibit polymeric structures. In the three-dimensional structure of 2 two crystallographically independent tetracyanonickellate anions are placed on inversion centres and exhibit connectivities two and four, respectively, with bridging cyano groups linking cadmium and nickel atoms. Octahedrally coordinated cadmium atom exhibits connectivity three. In one-dimensional structure of 4 [Ni(CN)4]2- anions and [Zn(aepn)]2+ cations are linked via bridging cyano ligands. Both building species exhibits connectivity two. One chelate bonded aepn ligand blocks three coordination sites on the penta-coordinated Zn(II) atom.
ER  -

PAHAROVÁ, J.; J. ČERNÁK; Zdirad ŽÁK a Jaromír MAREK. Use of multi-N-donor ligands for preparation of organic-inorganic hybrid materials: Crystal structures of ionic [M(aepn)2][Ni(CN)4].H2O and polymeric M(aepn)Ni(CN)4 (M = Zn(II), Cd(II); aepn = N-(2-aminoethyl)-1,3-propanediamine). \textit{Journal of Molecular Structure}. U.K.: Elsevier Science, 2007, roč.~842, 1-3, s.~117-124. ISSN~0022-2860.

Přehled o publikaci