HPLC separation, detection and Quatification of polycyclic Aromatic Nitrogen Heterocycles

ŠVÁBENSKÝ, Radim, Miroslav ORAVEC a Zdeněk ŠIMEK. HPLC separation, detection and Quatification of polycyclic Aromatic Nitrogen Heterocycles. In LC/MS Users Meeting. 2007.

Základní údaje

• Originální název: HPLC separation, detection and Quatification of polycyclic Aromatic Nitrogen Heterocycles
• Název česky: Separace, detekce a kvantifikace polycyklických aromatických dusíkatých heterocyklů
• Autoři: ŠVÁBENSKÝ, Radim, Miroslav ORAVEC a Zdeněk ŠIMEK.
• Vydání: LC/MS Users Meeting, 2007.

Další údaje

• Originální jazyk: angličtina
• Typ výsledku: Prezentace na konferencích
• Obor: 10406 Analytical chemistry
• Stát vydavatele: Česká republika
• Utajení: není předmětem státního či obchodního tajemství
• Organizační jednotka: Přírodovědecká fakulta
• Klíčová slova anglicky: PANHs; LC/MS; soil
• Štítky: LC/MS, PANHs, soil
• Příznaky: Mezinárodní význam

Anotace

Polycyclic aromatic nitrogen heterocycles (PANHs) are present in the environment in broad range of concentrations along with polycyclic aromatic hydrocarbons (PAH) and their derivatives, amino-, nitro-, methyl-, etc. Actual determinable amount of PANHs may vary depending on their fate in environmental samples. Adsorption and/or complexation processes accompanied by volatilization take place especially in soil samples. Successful identification and content determination of PANHs in complex mixtures requires efficient methods of their extraction from environmental samples, suitable preseparation, preconcentration and final analytical determination. Common used extraction methods recommended for isolation of PAHs, their derivatives and analogues may not be suitable for aromatic heterocycles, such as PANHs. The very low value of final amount determined in the complex mixture of may be result of significant difference affinity of extracted pollutant and applicable extraction solvent. Differences in extraction recovery of set of PANHs from soil observed using different extraction solvents is presented in the paper.

Anotace česky

Polycyclic aromatic nitrogen heterocycles (PANHs) are present in the environment in broad range of concentrations along with polycyclic aromatic hydrocarbons (PAH) and their derivatives, amino-, nitro-, methyl-, etc. Actual determinable amount of PANHs may vary depending on their fate in environmental samples. Adsorption and/or complexation processes accompanied by volatilization take place especially in soil samples. Successful identification and content determination of PANHs in complex mixtures requires efficient methods of their extraction from environmental samples, suitable preseparation, preconcentration and final analytical determination. Common used extraction methods recommended for isolation of PAHs, their derivatives and analogues may not be suitable for aromatic heterocycles, such as PANHs. The very low value of final amount determined in the complex mixture of may be result of significant difference affinity of extracted pollutant and applicable extraction solvent. Differences in extraction recovery of set of PANHs from soil observed using different extraction solvents is presented in the paper.

Návaznosti

• MSM0021622412, záměr: Název: Interakce mezi chemickými látkami, prostředím a biologickými systémy a jejich důsledky na globální, regionální a lokální úrovni (INCHEMBIOL) (Akronym: INCHEMBIOL)

Investor: Ministerstvo školství, mládeže a tělovýchovy ČR, Interakce mezi chemickými látkami, prostředím a biologickými systémy a jejich důsledky na globální , regionální a lokální úrovni