TRÁVNÍČEK, Z., Jaromír MAREK a Š. ČERMÁKOVÁ. (mu(3)-Trithiocyanurato-kappa N-6(1),S-2 : N-3,S-4 : N-5,S-6) tris[(N,N,N ',N '',N ''-pentamethyldiethylenetriamine-kappa N-3,N ',N '')copper(II)] tris(perchlorate). Acta Crystallographica Section E: Structure Reports Online. Chester, England: IUCr, 2007, roč. 63, č. 6, s. M1742-M1743, 2 s. ISSN 1600-5368. |
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@article{755388, author = {Trávníček, Z. and Marek, Jaromír and Čermáková, Š.}, article_location = {Chester, England}, article_number = {6}, keywords = {CRYSTAL}, language = {eng}, issn = {1600-5368}, journal = {Acta Crystallographica Section E: Structure Reports Online}, title = {(mu(3)-Trithiocyanurato-kappa N-6(1),S-2 : N-3,S-4 : N-5,S-6) tris[(N,N,N ',N '',N ''-pentamethyldiethylenetriamine-kappa N-3,N ',N '')copper(II)] tris(perchlorate)}, volume = {63}, year = {2007} }
TY - JOUR ID - 755388 AU - Trávníček, Z. - Marek, Jaromír - Čermáková, Š. PY - 2007 TI - (mu(3)-Trithiocyanurato-kappa N-6(1),S-2 : N-3,S-4 : N-5,S-6) tris[(N,N,N ',N '',N ''-pentamethyldiethylenetriamine-kappa N-3,N ',N '')copper(II)] tris(perchlorate) JF - Acta Crystallographica Section E: Structure Reports Online VL - 63 IS - 6 SP - M1742-M1743 EP - M1742-M1743 PB - IUCr SN - 16005368 KW - CRYSTAL N2 - In the title compound, [Cu-3(C9H23N3)(3)(C3N3S3)](ClO4)(3), the three Cu-II centres, related by the body-diagonal threefold rotation symmetry along [ 111], are bridged by a trithiocyanurate( 3 -) anion ( ttc), with each centre having a considerably distorted trigonal - bipyramidal geometry and bonded to three N atoms of a tridentate N, N, N', N '', N ''-pentamethyldiethylenetriamine ligand, and one S and one N atoms of the ttc ligand. The secondary structure is stabilized by a variety of weak hydrogen bonds of the type C - H center dot center dot center dot O ( H center dot center dot center dot A < 2.7 angstrom) connecting the cation and perchlorate anions. ER -
TRÁVNÍČEK, Z., Jaromír MAREK a Š. ČERMÁKOVÁ. (mu(3)-Trithiocyanurato-kappa N-6(1),S-2 : N-3,S-4 : N-5,S-6) tris[(N,N,N ',N '',N ''-pentamethyldiethylenetriamine-kappa N-3,N ',N '')copper(II)] tris(perchlorate). \textit{Acta Crystallographica Section E: Structure Reports Online}. Chester, England: IUCr, 2007, roč.~63, č.~6, s.~M1742-M1743, 2 s. ISSN~1600-5368.
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