| DUTTA, D,, A. D. JANA, A. RAY, Jaromír MAREK a M. ALI. Synthesis of a new polymorph in [Cu(pyridine-2-carboxylate)(2)] system. INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY. NEW DELHI, INDIA: NATL INST SCIENCE COMMUNICATION, 2008, roč. 47, č. 11, s. 1656-1660. ISSN 0376-4710. |
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@article{806916,
author = {Dutta, D, and Jana, A. D. and Ray, A. and Marek, Jaromír and Ali, M.},
article_location = {NEW DELHI, INDIA},
article_number = {11},
keywords = {Copper; Complexes; Supramolecular motive},
language = {eng},
issn = {0376-4710},
journal = {INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY},
title = {Synthesis of a new polymorph in [Cu(pyridine-2-carboxylate)(2)] system},
volume = {47},
year = {2008}
}
TY - JOUR
ID - 806916
AU - Dutta, D, - Jana, A. D. - Ray, A. - Marek, Jaromír - Ali, M.
PY - 2008
TI - Synthesis of a new polymorph in [Cu(pyridine-2-carboxylate)(2)] system
JF - INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY
VL - 47
IS - 11
SP - 1656-1660
EP - 1656-1660
PB - NATL INST SCIENCE COMMUNICATION
SN - 03764710
KW - Copper
KW - Complexes
KW - Supramolecular motive
N2 - Single crystal X-ray studies on a doubly carboxylate bridged {[Cu(pic)(2)].2H(2)O}(n) (1) (pic = pyridine-2-carboxylate) polymeric chains extending along the crystallographic a axis reveal that adjacent polymeric chains are joined by the lattice water chains running parallel to the polymeric chain leading to a 2D sheet in the (101) plane. The successive sheets are interdigitated and glued to each other by a novel C=O...pi interaction into a 3D supramolecular motif. The complex (1) can be regarded as a pseudo-polymorph of [Cu(pic)(2)](n) which has been realized in two forms, violet (2) and blue-violet (3) from methanol.
ER -
DUTTA, D,, A. D. JANA, A. RAY, Jaromír MAREK a M. ALI. Synthesis of a new polymorph in [Cu(pyridine-2-carboxylate)(2)] system. \textit{INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL \&{} ANALYTICAL CHEMISTRY}. NEW DELHI, INDIA: NATL INST SCIENCE COMMUNICATION, 2008, roč.~47, č.~11, s.~1656-1660. ISSN~0376-4710.
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