D 2005

NEW TOOLS FOR AN ANALYSIS OF EXPERIMENTAL (NMR) AND THEORETICAL (MD) DATA

NOVÁK, Petr; Lukáš ŽÍDEK; Pavel MACEK; Petr PADRTA; Vladimír SKLENÁŘ et al.

Základní údaje

Originální název

NEW TOOLS FOR AN ANALYSIS OF EXPERIMENTAL (NMR) AND THEORETICAL (MD) DATA

Název česky

Nové nástroje pro analýzu experimentálních (NMR) a teoretických (MD) dat

Autoři

NOVÁK, Petr; Lukáš ŽÍDEK; Pavel MACEK; Petr PADRTA a Vladimír SKLENÁŘ

Vydání

Brno, Konference mladých vědeckých pracovníků "Strukturní biofyzika makromolekul" 1 s. 2005

Nakladatel

Biofyzikální ústav AV CR a Masarykova univerzita-Přírodovědecká fakulta

Další údaje

Jazyk

angličtina

Typ výsledku

Stať ve sborníku

Obor

10600 1.6 Biological sciences

Stát vydavatele

Česká republika

Utajení

není předmětem státního či obchodního tajemství

Označené pro přenos do RIV

Ne

Organizační jednotka

Přírodovědecká fakulta

Klíčová slova anglicky

S3EPY; MD; RDC; PAIN;

Příznaky

Mezinárodní význam
Změněno: 9. 4. 2010 14:03, prof. Mgr. Lukáš Žídek, Ph.D.

Anotace

V originále

Once experiments or simulations are started one obtains a large amount of data which should be analyzed to get the desirable results. This is a fairly good reason for everlasting development of the new tools for the data analysis. Two major topics are covered by this work. Residual dipolar couplings (RDC) are measured as the difference of the scalar couplings in an isotropic and weakly aligned sample. In order to determine even the small scalar couplings (in the range of units or tens of Hertz), it is necessary to measure very sophisticated spin-state-selective E.COSY type experiments (1). The disadvantage of this approach is a tedious, error prone and complicated manipulation with the lots of spectra and with the large amount of data. To make this process as fast and fool-proof as possible, an S3E.py program was written. This is a Python extension of the program Sparky (2) commonly used for the graphical assignment and integration of the NMR spectra. Program has graphical users interface and is able to: * convert and process the spectra, * assign series of the spectra, * fit peaks and read precisely peak positions, * plot the graphs of the measured and theoretical peaks' displacements * fit dependencies and calculate real values of the small couplings Program was tested on and used for extract values of the small scalar couplings from the S3E type experiments measured on the molecule of ISL U6 RNA from Trypanosoma. Trajectories from the molecular dynamics (MD) simulations of the proteins contain wealth of data. From the MD trajectory not only coordinates of all atoms are known, but also their change in course of time as the molecule is position and conformation. That means possibility of extracting motional parameters if the proper tools do exist. For this purpose the program PAIN (Program for Analysis of Internal motioN) was written. It is written in C language so the analysis compared to the amount of data is fairly fast and it should be rather easily portable on the majority of the current platforms. Some key features implemented in PAIN up to date are calculation of the : * correlation function of the vector * generalized order parameter * frequency dependent generalized order parameter * conformation dependent generalized order parameter * spatial distribution of the internuclear vector orientations * histogram of the dihedral angle (including number of modes and distribution parameters estimation) * conformation transitions analysis Program was tested on and used for an analysis of the MD simulation of the mouse Major Urinary Protein-I in an explicit solvent.

Česky

Once experiments or simulations are started one obtains a large amount of data which should be analyzed to get the desirable results. This is a fairly good reason for everlasting development of the new tools for the data analysis. Two major topics are covered by this work. Residual dipolar couplings (RDC) are measured as the difference of the scalar couplings in an isotropic and weakly aligned sample. In order to determine even the small scalar couplings (in the range of units or tens of Hertz), it is necessary to measure very sophisticated spin-state-selective E.COSY type experiments (1). The disadvantage of this approach is a tedious, error prone and complicated manipulation with the lots of spectra and with the large amount of data. To make this process as fast and fool-proof as possible, an S3E.py program was written. This is a Python extension of the program Sparky (2) commonly used for the graphical assignment and integration of the NMR spectra. Program has graphical users interface and is able to: * convert and process the spectra, * assign series of the spectra, * fit peaks and read precisely peak positions, * plot the graphs of the measured and theoretical peaks' displacements * fit dependencies and calculate real values of the small couplings Program was tested on and used for extract values of the small scalar couplings from the S3E type experiments measured on the molecule of ISL U6 RNA from Trypanosoma. Trajectories from the molecular dynamics (MD) simulations of the proteins contain wealth of data. From the MD trajectory not only coordinates of all atoms are known, but also their change in course of time as the molecule is position and conformation. That means possibility of extracting motional parameters if the proper tools do exist. For this purpose the program PAIN (Program for Analysis of Internal motioN) was written. It is written in C language so the analysis compared to the amount of data is fairly fast and it should be rather easily portable on the majority of the current platforms. Some key features implemented in PAIN up to date are calculation of the : * correlation function of the vector * generalized order parameter * frequency dependent generalized order parameter * conformation dependent generalized order parameter * spatial distribution of the internuclear vector orientations * histogram of the dihedral angle (including number of modes and distribution parameters estimation) * conformation transitions analysis Program was tested on and used for an analysis of the MD simulation of the mouse Major Urinary Protein-I in an explicit solvent.

Návaznosti

GD204/03/H016, projekt VaV
Název: Strukturní biofyzika makromolekul
Investor: Grantová agentura ČR, Strukturní biofyzika makromolekul
MSM0021622413, záměr
Název: Proteiny v metabolismu a při interakci organismů s prostředím
Investor: Ministerstvo školství, mládeže a tělovýchovy ČR, Proteiny v metabolismu a při interakci organismů s prostředím