Synthesis and Characterization of New Imidophosphanes and
Phosphine Oxides Containing 3,3,4,4-tetramethylsuccinimidyl
Group

J 2009

Synthesis and Characterization of New Imidophosphanes and Phosphine Oxides Containing 3,3,4,4-tetramethylsuccinimidyl Group

VYŠVAŘIL, Martin; Dalibor DASTYCH; Jan TARABA a Marek NEČAS

Základní údaje

Originální název

Synthesis and Characterization of New Imidophosphanes and Phosphine Oxides Containing 3,3,4,4-tetramethylsuccinimidyl Group

Název česky

Syntéza a charakterizace nových imidofosfanů a fosfinoxidů obsahujících 3,3,4,4-tetramethylsukcinimidovou skupinu

Autoři

VYŠVAŘIL, Martin; Dalibor DASTYCH; Jan TARABA a Marek NEČAS

Vydání

Inorganica Chimica Acta, USA, Elsevier Science, 2009, 0020-1693

Další údaje

Typ výsledku

Článek v odborném periodiku

Utajení

není předmětem státního či obchodního tajemství

Odkazy

URL

Impakt faktor

Impact factor: 2.322

Označené pro přenos do RIV

Organizační jednotka

Přírodovědecká fakulta

UT WoS

000270986800007

Klíčová slova česky

sukcinimid; fosfan; fosfinoxid; substituce; fosforylová skupina

Klíčová slova anglicky

succinimide; phosphane; phosphine oxide; substitution; phosphoryl group

Příznaky

Mezinárodní význam, Recenzováno

Změněno: 26. 11. 2009 18:15, Mgr. Martin Vyšvařil, Ph.D.

Anotace

V originále

A series of new imidophosphanes and phosphine oxides containing 3,3,4,4-tetramethylsuccinimidyl group were synthesized and characterized by 1H, 13C{1H} and 31P NMR spectroscopy, IR and MS. PhmPCln (m = 3 – n, n = 3, 2, 1) reacted with 3,3,4,4-tetramethylsuccinimide (TH) and potassium 3,3,4,4-tetramethylsuccinimidate 1 to give corresponding PhmPTn. Molecular structures of products were established by single-crystal X-ray diffraction experiments. Attempts to prepare new imidophosphoranes by reactions of 1 with PhmPCln (m = 5 – n, n = 4, 3, 2) resulted in phosphine oxides. In these reactions the phosphoryl group was formed and we characterized a by-product of this type of reaction.

Citovat

VYŠVAŘIL, Martin; Dalibor DASTYCH; Jan TARABA a Marek NEČAS. Synthesis and Characterization of New Imidophosphanes and Phosphine Oxides Containing 3,3,4,4-tetramethylsuccinimidyl Group. Inorganica Chimica Acta. USA: Elsevier Science, 2009, roč. 362/2009, s. 4899-4905. ISSN 0020-1693.

@article{856633,
   author = {Vyšvařil, Martin and Dastych, Dalibor and Taraba, Jan and Nečas, Marek},
   article_location = {USA},
   keywords = {succinimide; phosphane; phosphine oxide; substitution; phosphoryl group},
   issn = {0020-1693},
   journal = {Inorganica Chimica Acta},
   title = {Synthesis and Characterization of New Imidophosphanes and Phosphine Oxides Containing 3,3,4,4-tetramethylsuccinimidyl Group},
   url = {http://www.sciencedirect.com/science?_ob=MImg&_imagekey=B6TG5-4WVT0KS-1-S&_cdi=5245&_user=640830&_orig=search&_coverDate=11%2F10%2F2009&_sk=996379985&view=c&wchp=dGLbVtz-zSkzk&md5=c34009946e56c3cada55526876548140&ie=/sdarticle.pdf},
   volume = {362/2009},
   year = {2009}
}

TY  - JOUR
ID  - 856633
AU  - Vyšvařil, Martin - Dastych, Dalibor - Taraba, Jan - Nečas, Marek
PY  - 2009
TI  - Synthesis and Characterization of New Imidophosphanes and Phosphine Oxides Containing 3,3,4,4-tetramethylsuccinimidyl Group
JF  - Inorganica Chimica Acta
VL  - 362/2009
SP  - 4899-4905
EP  - 4899-4905
PB  - Elsevier Science
SN  - 00201693
KW  - succinimide
KW  - phosphane
KW  - phosphine oxide
KW  - substitution
KW  - phosphoryl group
UR  - http://www.sciencedirect.com/science?_ob=MImg&_imagekey=B6TG5-4WVT0KS-1-S&_cdi=5245&_user=640830&_orig=search&_coverDate=11%2F10%2F2009&_sk=996379985&view=c&wchp=dGLbVtz-zSkzk&md5=c34009946e56c3cada55526876548140&ie=/sdarticle.pdf
N2  - A series of new imidophosphanes and phosphine oxides containing 3,3,4,4-tetramethylsuccinimidyl group were synthesized and characterized by 1H, 13C{1H} and 31P NMR spectroscopy, IR and MS. PhmPCln (m = 3 – n, n = 3, 2, 1) reacted with 3,3,4,4-tetramethylsuccinimide (TH) and potassium 3,3,4,4-tetramethylsuccinimidate 1 to give corresponding PhmPTn. Molecular structures of products were established by single-crystal X-ray diffraction experiments. Attempts to prepare new imidophosphoranes by reactions of 1 with PhmPCln (m = 5 – n, n = 4, 3, 2) resulted in phosphine oxides. In these reactions the phosphoryl group was formed and we characterized a by-product of this type of reaction.
ER  -

VYŠVAŘIL, Martin; Dalibor DASTYCH; Jan TARABA a Marek NEČAS. Synthesis and Characterization of New Imidophosphanes and Phosphine Oxides Containing 3,3,4,4-tetramethylsuccinimidyl Group. \textit{Inorganica Chimica Acta}. USA: Elsevier Science, 2009, roč.~362/2009, s.~4899-4905. ISSN~0020-1693.

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