Influence of Phosphorus Acid Pendant Arms on Solution Properties of Metal Complexes of Polyazamacrocycles

HERMANN, Petr; Přemysl LUBAL a Jan KOTEK. Influence of Phosphorus Acid Pendant Arms on Solution Properties of Metal Complexes of Polyazamacrocycles. In Abstract Book of ISABC 10 conference (International Symposium on Applied Bioinorganic Chemistry). Debrecen: Department of Inorganic and Analytical Chemistry, Debrecen University, 2009, s. 136-136, 224 s. ISBN 978-963-473-307-2.

Základní údaje

Originální název

Influence of Phosphorus Acid Pendant Arms on Solution Properties of Metal Complexes of Polyazamacrocycles

Název česky

Vliv fosforových pendantních ramen na vlastnosti kovových komplexů polyazamakrocyclů

Autoři

HERMANN, Petr; Přemysl LUBAL a Jan KOTEK

Vydání

Debrecen, Abstract Book of ISABC 10 conference (International Symposium on Applied Bioinorganic Chemistry), od s. 136-136, 224 s. 2009

Nakladatel

Department of Inorganic and Analytical Chemistry, Debrecen University

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Další údaje

Jazyk

angličtina

Typ výsledku

Stať ve sborníku

Obor

10402 Inorganic and nuclear chemistry

Stát vydavatele

Maďarsko

Utajení

není předmětem státního či obchodního tajemství

Označené pro přenos do RIV

Ano

Kód RIV

RIV/00216224:14310/09:00037453

Organizační jednotka

Přírodovědecká fakulta

ISBN

978-963-473-307-2

Klíčová slova anglicky

macrocyclic ligands; metal complexes; MRI; nuclear and optical methods

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Anotace

V originále

Complexes of macrocyclic ligands are widely used in medicine (MRI, nuclear and optical methods) for diagnosis and/or therapy. Molecular imaging utilizing the metal complexes is an emerging field of medical/biological research. The complexes considered must be highly stable under competing conditions. Acid-assisted decomplexation kinetics is a method of choice for assesment of kinetic inertness of the complexes. Relations between structures of ligands and thermodynamic and kinetic stability of their complexes will be discussed.

Česky

Complexes of macrocyclic ligands are widely used in medicine (MRI, nuclear and optical methods) for diagnosis and/or therapy. Molecular imaging utilizing the metal complexes is an emerging field of medical/biological research. The complexes considered must be highly stable under competing conditions. Acid-assisted decomplexation kinetics is a method of choice for assesment of kinetic inertness of the complexes. Relations between structures of ligands and thermodynamic and kinetic stability of their complexes will be discussed.