| BERAN, Martin, Jiří PŘÍHODA a Jan TARABA. A new route to the syntheses of N-(fluorosulfuryl)sulfonamide salts: Crystal structure of Ph4P+ [CF3SO2NSO2F]-. Polyhedron. Elsevier, 2010, roč. 2010, č. 29, s. 991-994. ISSN 0277-5387. Dostupné z: https://dx.doi.org/10.1016/j.poly.2009.11.024. |
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@article{869941,
author = {Beran, Martin and Příhoda, Jiří and Taraba, Jan},
article_number = {29},
doi = {http://dx.doi.org/10.1016/j.poly.2009.11.024},
keywords = {N-(fluorosulfuryl) sulfonamides N-(fluorosulfuryl)trifluoromethane sulfonamide N-(chlorosulfuryl)trifluoromethane sulfonamide},
language = {eng},
issn = {0277-5387},
journal = {Polyhedron},
title = {A new route to the syntheses of N-(fluorosulfuryl)sulfonamide salts: Crystal structure of Ph4P+ [CF3SO2NSO2F]-},
volume = {2010},
year = {2010}
}
TY - JOUR
ID - 869941
AU - Beran, Martin - Příhoda, Jiří - Taraba, Jan
PY - 2010
TI - A new route to the syntheses of N-(fluorosulfuryl)sulfonamide salts: Crystal structure of Ph4P+ [CF3SO2NSO2F]-
JF - Polyhedron
VL - 2010
IS - 29
SP - 991-994
EP - 991-994
PB - Elsevier
SN - 02775387
KW - N-(fluorosulfuryl) sulfonamides N-(fluorosulfuryl)trifluoromethane sulfonamide N-(chlorosulfuryl)trifluoromethane sulfonamide
N2 - A new route for the preparation of potassium and tetraphenylphosphonium salts of N-(fluorosulfuryl)trifluoromethane sulfonamide is described. N-(chlorosulfuryl)-trifluoromethane sulfonamide CF3SO2NH SO2Cl, that was used for preparations of both salts, was prepared by the reaction of trifluoromethane sulfonamide CF3SO2NH2 and chlorosulfonic acid in the presence of SOCl2. The obtained N-(chlorosulfuryl)trifluoromethane sulfonamide was converted to potassium N-(fluorosulfuryl)trifluoromethane sulfonamide by using anhydrous KF. Potassium N-(fluorosulfuryl)trifluoromethane sulfonamide served as a starting material for the preparation of the corresponding tetraphenylphosphonium N-(fluorosulfuryl)trifluoromethane sulfonamide that crystallizes from the aqueous solution of potassium N-(fluorosulfuryl)trifluoromethane sulfonamide and tetraphenylphosphonium chloride. N-(fluorosulfuryl)trifluoromethane sulfonamide tetraphenylphosphonium salt is tetragonal, space group P-4.
ER -
BERAN, Martin, Jiří PŘÍHODA a Jan TARABA. A new route to the syntheses of N-(fluorosulfuryl)sulfonamide salts: Crystal structure of Ph4P+ [CF3SO2NSO2F]-. \textit{Polyhedron}. Elsevier, 2010, roč.~2010, č.~29, s.~991-994. ISSN~0277-5387. Dostupné z: https://dx.doi.org/10.1016/j.poly.2009.11.024.
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