WEIDLICH, Tomáš, Anna KREJČOVÁ and Lubomír PROKEŠ. Study of dehalogenation of halogenoanilines using Raney Al-Ni alloy in aqueous medium at room temperature. Monatshefte fuer Chemie, Chemical Monthly. Wien: Springer-Verlag, 2010, vol. 141, No 9, p. 1015-1020. ISSN 0026-9247. |
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@article{895001, author = {Weidlich, Tomáš and Krejčová, Anna and Prokeš, Lubomír}, article_location = {Wien}, article_number = {9}, keywords = {Reductions - AOX removal - NMR spectroscopy - Metals - ICP-OES}, language = {eng}, issn = {0026-9247}, journal = {Monatshefte fuer Chemie, Chemical Monthly}, title = {Study of dehalogenation of halogenoanilines using Raney Al-Ni alloy in aqueous medium at room temperature}, url = {http://www.springerlink.com/content/e21013535k7mrjl1/}, volume = {141}, year = {2010} }
TY - JOUR ID - 895001 AU - Weidlich, Tomáš - Krejčová, Anna - Prokeš, Lubomír PY - 2010 TI - Study of dehalogenation of halogenoanilines using Raney Al-Ni alloy in aqueous medium at room temperature JF - Monatshefte fuer Chemie, Chemical Monthly VL - 141 IS - 9 SP - 1015-1020 EP - 1015-1020 PB - Springer-Verlag SN - 00269247 KW - Reductions - AOX removal - NMR spectroscopy - Metals - ICP-OES UR - http://www.springerlink.com/content/e21013535k7mrjl1/ N2 - Dehalogenation of halogenated anilines by action of powdered aluminium-nickel alloy in aqueous alkaline solution at room temperature has been studied. The reaction course was monitored by means of 1H nuclear magnetic resonance (NMR) spectroscopy. The rates of dehalogenation of 4-bromo-, 4-chloro-, 4-fluoro- and 3-chloroaniline were compared under conditions of minimum necessary excess of Al-Ni alloy as reducing agent in edetane buffer medium at pH 10.9. On the basis of the results obtained in buffers, the dehalogenation method of aqueous solutions of halogenoanilines was verified using NaOH as the base. ER -
WEIDLICH, Tomáš, Anna KREJČOVÁ and Lubomír PROKEŠ. Study of dehalogenation of halogenoanilines using Raney Al-Ni alloy in aqueous medium at room temperature. \textit{Monatshefte fuer Chemie, Chemical Monthly}. Wien: Springer-Verlag, 2010, vol.~141, No~9, p.~1015-1020. ISSN~0026-9247.
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