Determination of cadmium, chromium and copper in high salt
samples by LA ICP OES after electrodeposition preliminary study

J 2010

Determination of cadmium, chromium and copper in high salt samples by LA ICP OES after electrodeposition preliminary study

KNÁPEK, Jan; Josef KOMÁREK a Karel NOVOTNÝ

Základní údaje

Originální název

Determination of cadmium, chromium and copper in high salt samples by LA ICP OES after electrodeposition preliminary study

Název česky

Stanovení kadmia, chromu a mědi ve vzorcích s vysokým obsahem solí LA ICP OES po elektrodepozici

Autoři

KNÁPEK, Jan; Josef KOMÁREK a Karel NOVOTNÝ

Vydání

Microchimica Acta, Wien (Austria), Springer, 2010, 0026-3672

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10406 Analytical chemistry

Stát vydavatele

Česká republika

Utajení

není předmětem státního či obchodního tajemství

Impakt faktor

Impact factor: 2.578

Označené pro přenos do RIV

Ano

Kód RIV

RIV/00216224:14310/10:00046262

Organizační jednotka

Přírodovědecká fakulta

UT WoS

000281669900020

Klíčová slova česky

elektrodepozice; LA ICP OES; vysoce zasolené matrice; stopové prvky; odpadní voda

Klíčová slova anglicky

electrodeposition; LA ICP OES; high salt matrix; trace elements; waste water

Změněno: 10. 1. 2011 15:03, doc. Mgr. Karel Novotný, Ph.D.

Anotace

V originále

A novel method is presented for determination of heavy metal ions in a high-saline matrix. It is based on the electrodeposition of the ions and subsequent laser ablation coupled to inductively coupled plasma optical emission spectrometry (LA ICP OES). Three arrangements for electrodeposition were worked out, two of them with stationary working electrodes. Materials for use in the working electrodes, and conditions for electrodeposition of Cd, Cr and Cu (pH, deposition current, time of electrolysis) were studied. Nickel was found to be the best electrode material. The metals accumulate on the surface of electrode and were then evaporated/ablated with a Nd:YAG laser focused into the ICP-OES spectrometer. The detection limits are 0.13 mg/L for Cd, 0.15 mg/L for Cu, and 1.9 mg/L for Cr in case of a stationary bottom working electrode, and 0.25 mg/L for Cd, 0.05 mg/L for Cu, 0.8 mg/L for Cr when using a rotating electrode. The relative standard deviation is in range from 3.8 to 10.3%. Waste water was analyzed in this way by the standard addition method.

Návaznosti

MSM0021622412, záměr

Název: Interakce mezi chemickými látkami, prostředím a biologickými systémy a jejich důsledky na globální, regionální a lokální úrovni (INCHEMBIOL) (Akronym: INCHEMBIOL)

Investor: Ministerstvo školství, mládeže a tělovýchovy ČR, Interakce mezi chemickými látkami, prostředím a biologickými systémy a jejich důsledky na globální , regionální a lokální úrovni

Citovat

KNÁPEK, Jan; Josef KOMÁREK a Karel NOVOTNÝ. Determination of cadmium, chromium and copper in high salt samples by LA ICP OES after electrodeposition preliminary study. Microchimica Acta. Wien (Austria): Springer, 2010, roč. 2010, č. 171, s. 145-150. ISSN 0026-3672.

@article{916224,
   author = {Knápek, Jan and Komárek, Josef and Novotný, Karel},
   article_location = {Wien (Austria)},
   article_number = {171},
   keywords = {electrodeposition; LA ICP OES; high salt matrix; trace elements; waste water},
   language = {eng},
   issn = {0026-3672},
   journal = {Microchimica Acta},
   title = {Determination of cadmium, chromium and copper in high salt samples by LA ICP OES after electrodeposition preliminary study},
   volume = {2010},
   year = {2010}
}

TY  - JOUR
ID  - 916224
AU  - Knápek, Jan - Komárek, Josef - Novotný, Karel
PY  - 2010
TI  - Determination of cadmium, chromium and copper in high salt samples by LA ICP OES after electrodeposition preliminary study
JF  - Microchimica Acta
VL  - 2010
IS  - 171
SP  - 145-150
EP  - 145-150
PB  - Springer
SN  - 00263672
KW  - electrodeposition
KW  - LA ICP OES
KW  - high salt matrix
KW  - trace elements
KW  - waste water
N2  - A novel method is presented for determination of heavy metal ions in a high-saline matrix. It is based on the electrodeposition of the ions and subsequent laser ablation coupled to inductively coupled plasma optical emission spectrometry (LA ICP OES). Three arrangements for electrodeposition were worked out, two of them with stationary working electrodes. Materials for use in the working electrodes, and conditions for electrodeposition of Cd, Cr and Cu (pH, deposition current, time of electrolysis) were studied. Nickel was found to be the best electrode material. The metals accumulate on the surface of electrode and were then evaporated/ablated with a Nd:YAG laser focused into the ICP-OES spectrometer. The detection limits are 0.13 mg/L for Cd, 0.15 mg/L for Cu, and 1.9 mg/L for Cr in case of a stationary bottom working electrode, and 0.25 mg/L for Cd, 0.05 mg/L for Cu, 0.8 mg/L for Cr when using a rotating electrode. The relative standard deviation is in range from 3.8 to 10.3%. Waste water was analyzed in this way by the standard addition method.
ER  -

KNÁPEK, Jan; Josef KOMÁREK a Karel NOVOTNÝ. Determination of cadmium, chromium and copper in high salt samples by LA ICP OES after electrodeposition preliminary study. \textit{Microchimica Acta}. Wien (Austria): Springer, 2010, roč.~2010, č.~171, s.~145-150. ISSN~0026-3672.

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