Plasma polymer films of tetravinylsilane modified by UV
irradiation

J 2010

Plasma polymer films of tetravinylsilane modified by UV irradiation

ČECH, V., S. LICHOVNÍKOVÁ, R. TRIVEDI, V. PEŘINA, J. ZEMEK et. al.

Základní údaje

Originální název

Plasma polymer films of tetravinylsilane modified by UV irradiation

Autoři

ČECH, V. (203 Česká republika), S. LICHOVNÍKOVÁ (203 Česká republika), R. TRIVEDI (840 Spojené státy), V. PEŘINA (203 Česká republika), J. ZEMEK (203 Česká republika), Petr MIKULÍK (203 Česká republika, garant, domácí) a Ondřej CAHA (203 Česká republika, domácí)

Vydání

Surface and Coatings Technology, 2010, 0257-8972

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10302 Condensed matter physics

Stát vydavatele

Nizozemské království

Utajení

není předmětem státního či obchodního tajemství

Odkazy

URL

Impakt faktor

Impact factor: 2.141

Kód RIV

RIV/00216224:14310/10:00046315

Organizační jednotka

Přírodovědecká fakulta

UT WoS

000286343200037

Klíčová slova anglicky

plasma polymer films; PECVD; tetravinylsilane; UV irradiation;

Změněno: 5. 1. 2011 10:42, doc. RNDr. Petr Mikulík, Ph.D.

Anotace

V originále

As-deposited plasma polymer films of tetravinylsilane were modified by UV irradiation at ambient conditions. Surface and bulk spectroscopic techniques confirmed significant changes in chemical composition and structure that resulted in increased mechanical constants (Young's modulus, hardness) and density of the material due to the formation of a stronger polymer network with higher cross-linking. A decrease of the refractive index and extinction coefficient of the UV-irradiated material was caused by UV-induced chain scission and subsequent oxidation of the plasma polymer network. The surface morphology (RMS roughness) and wettability (surface free energy) of films can be controlled by UV exposition time. The most intensive aging effect was observed for the as-deposited film; in contrast, the 1000-min-UV-irradiated film appeared stable over 134 days. UV treatment can be characterized as an effective tool for additional tailoring of plasma polymer films according to their applications.

Návaznosti

MSM0021622410, záměr

Název: Fyzikální a chemické vlastnosti pokročilých materiálů a struktur

Investor: Ministerstvo školství, mládeže a tělovýchovy ČR, Fyzikální a chemické vlastnosti pokročilých materiálů a struktur

Citovat

ČECH, V., S. LICHOVNÍKOVÁ, R. TRIVEDI, V. PEŘINA, J. ZEMEK, Petr MIKULÍK a Ondřej CAHA. Plasma polymer films of tetravinylsilane modified by UV irradiation. Surface and Coatings Technology. 2010, roč. 205, č. 1, s. S177–S181, 5 s. ISSN 0257-8972.

@article{916510,
   author = {Čech, V. and Lichovníková, S. and Trivedi, R. and Peřina, V. and Zemek, J. and Mikulík, Petr and Caha, Ondřej},
   article_number = {1},
   keywords = {plasma polymer films; PECVD; tetravinylsilane; UV irradiation;},
   language = {eng},
   issn = {0257-8972},
   journal = {Surface and Coatings Technology},
   title = {Plasma polymer films of tetravinylsilane modified by UV irradiation},
   url = {http://www.sciencedirect.com/science?_ob=ArticleURL&_udi=B6TVV-50KC6GD-3&_user=835458&_coverDate=12%2F25%2F2010&_rdoc=1&_fmt=high&_orig=search&_origin=search&_sort=d&_docanchor=&view=c&_acct=C000045159&_version=1&_urlVersion=0&_userid=835458&md5=2a10abab},
   volume = {205},
   year = {2010}
}

TY  - JOUR
ID  - 916510
AU  - Čech, V. - Lichovníková, S. - Trivedi, R. - Peřina, V. - Zemek, J. - Mikulík, Petr - Caha, Ondřej
PY  - 2010
TI  - Plasma polymer films of tetravinylsilane modified by UV irradiation
JF  - Surface and Coatings Technology
VL  - 205
IS  - 1
SP  - S177–S181
EP  - S177–S181
SN  - 02578972
KW  - plasma polymer films
KW  - PECVD
KW  - tetravinylsilane
KW  - UV irradiation;
UR  - http://www.sciencedirect.com/science?_ob=ArticleURL&_udi=B6TVV-50KC6GD-3&_user=835458&_coverDate=12%2F25%2F2010&_rdoc=1&_fmt=high&_orig=search&_origin=search&_sort=d&_docanchor=&view=c&_acct=C000045159&_version=1&_urlVersion=0&_userid=835458&md5=2a10abab
N2  - As-deposited plasma polymer films of tetravinylsilane were modified by UV irradiation at ambient conditions. Surface and bulk spectroscopic techniques confirmed significant changes in chemical composition and structure that resulted in increased mechanical constants (Young's modulus, hardness) and density of the material due to the formation of a stronger polymer network with higher cross-linking. A decrease of the refractive index and extinction coefficient of the UV-irradiated material was caused by UV-induced chain scission and subsequent oxidation of the plasma polymer network. The surface morphology (RMS roughness) and wettability (surface free energy) of films can be controlled by UV exposition time. The most intensive aging effect was observed for the as-deposited film; in contrast, the 1000-min-UV-irradiated film appeared stable over 134 days. UV treatment can be characterized as an effective tool for additional tailoring of plasma polymer films according to their applications.
ER  -

ČECH, V., S. LICHOVNÍKOVÁ, R. TRIVEDI, V. PEŘINA, J. ZEMEK, Petr MIKULÍK a Ondřej CAHA. Plasma polymer films of tetravinylsilane modified by UV irradiation. \textit{Surface and Coatings Technology}. 2010, roč.~205, č.~1, s.~S177–S181, 5 s. ISSN~0257-8972.

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