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@article{932275,
author = {Kaleta, Jiří and Mazal, Ctibor},
article_location = {Washington D.C., USA},
article_number = {6},
doi = {http://dx.doi.org/10.1021/ol1031816},
keywords = {SHAPE-PERSISTENT MACROCYCLES; SUPRAMOLECULAR CHEMISTRY},
language = {eng},
issn = {1523-7060},
journal = {Organic Letters},
title = {A Triangular Macrocycle Altering Planar and Bulky Sections in Its Molecular Backbone},
url = {http://pubs.acs.org/doi/pdf/10.1021/ol1031816},
volume = {13},
year = {2011}
}
TY - JOUR
ID - 932275
AU - Kaleta, Jiří - Mazal, Ctibor
PY - 2011
TI - A Triangular Macrocycle Altering Planar and Bulky Sections in Its Molecular Backbone
JF - Organic Letters
VL - 13
IS - 6
SP - 1326-1329
EP - 1326-1329
PB - American Chemical Society
SN - 15237060
KW - SHAPE-PERSISTENT MACROCYCLES
KW - SUPRAMOLECULAR CHEMISTRY
UR - http://pubs.acs.org/doi/pdf/10.1021/ol1031816
L2 - http://pubs.acs.org/doi/pdf/10.1021/ol1031816
N2 - A triangular macrocyclic molecule has been synthesized which consists of substituted phenanthrene vertices interconnected by 1,3-diethynylbicyclo[1.1.1]pentane sides. The molecule is the very first example of exploiting the bicyclopentane motif in the construction of a shape persistent macrocycle's backbone. It carries new features such as bulkiness, nonconjugated sigma-bonding, and a certain conformational flexibility due to its easy longitudinal rotation. We have used some of the features in order to rationalize the observed tendency of the compound to form films on various surfaces.
ER -
KALETA, Jiří a Ctibor MAZAL. A Triangular Macrocycle Altering Planar and Bulky Sections in Its Molecular Backbone. \textit{Organic Letters}. Washington D.C., USA: American Chemical Society, roč.~13, č.~6, s.~1326-1329. ISSN~1523-7060. doi:10.1021/ol1031816. 2011.
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