Robust 1D open rack-like architecture in coordination polymers
of Anderson POMs [{Na-4(H2O)(14)}{Cu(gly)}(2)][TeMo6O24] and
[{Cu(en)(2)}(3){TeW6O24}]: synthesis, characterization and
heterogeneous catalytic epoxidation of olefines

J 2010

Robust 1D open rack-like architecture in coordination polymers of Anderson POMs [{Na-4(H2O)(14)}{Cu(gly)}(2)][TeMo6O24] and [{Cu(en)(2)}(3){TeW6O24}]: synthesis, characterization and heterogeneous catalytic epoxidation of olefines

DUTTA, D.; A.D. JANA; M. DEBNATH; A. BHAUMIK; Jaromír MAREK et al.

Základní údaje

Originální název

Robust 1D open rack-like architecture in coordination polymers of Anderson POMs [{Na-4(H2O)(14)}{Cu(gly)}(2)][TeMo6O24] and [{Cu(en)(2)}(3){TeW6O24}]: synthesis, characterization and heterogeneous catalytic epoxidation of olefines

Název česky

Robustní 1D koordinační architektura mezi koordinač. polymery Anderson. polyoxometalátů

Autoři

DUTTA, D.; A.D. JANA; M. DEBNATH; A. BHAUMIK; Jaromír MAREK a Mahammad ALI

Vydání

Dalton transactions : an international journal of inorganic chemistry, Cambridge, The Royal Society of Chemistry, 2010, 1477-9226

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10402 Inorganic and nuclear chemistry

Stát vydavatele

Česká republika

Utajení

není předmětem státního či obchodního tajemství

Odkazy

URL

Impakt faktor

Impact factor: 3.647

Označené pro přenos do RIV

Ano

Kód RIV

RIV/00216224:14310/10:00047842

Organizační jednotka

Přírodovědecká fakulta

UT WoS

000284777500008

Klíčová slova anglicky

ORGANIC-INORGANIC HYBRID; TRANSITION-METAL-COMPLEXES; RARE-EARTH CATIONS; CHAIN-LIKE POLYMER; BUILDING-BLOCKS; CRYSTAL-STRUCTURE; KEGGIN POLYOXOMETALATE; HYDROTHERMAL SYNTHESIS; HETEROPOLY COMPOUNDS; MASS-SPECTROMETRY

Změněno: 2. 5. 2012 13:05, doc. RNDr. Jaromír Marek, Ph.D.

Anotace

ORIG CZ

V originále

Two novel organic-inorganic hybrid tungsto-and molybdo-telurates having formula [{Na-4(H2O)(14)}{Cu(gly)}(2)][TeMo6O24] (1){gly = glycine} and [{Cu(en)(2)}(3){TeW6O24}]center dot 6H(2)O {en = ethyline-diamine} (2) based on Anderson type heteropolyoxometalates (POMs) have been synthesized and characterized by X-ray crystallography. Common structural feature of both 1 and 2 is the presence of a unique 1D open rack-like architecture, where the disc shaped Anderson POMs act as steps and cationic Cu-organic complexes act as handles of the rack. In 1 the independent structural unit is a 1D coordination polymer with the above mentioned rack type architecture, while in 2, these independent rack-like architectures are further extended to a 2D coordination polymer. Heterogeneous catalysis for the epoxidation of cyclohexene and styrene by complexes 1 and 2 showed very good catalytic efficiency.

Česky

Byly připraveny a difrakčně charakterizovány 2 nové hybridní organicko-anorganické sloučeniny [{Na-4(H2O)(14)}{Cu(gly)}(2)][TeMo6O24] (1){gly = glycine} a [{Cu(en)(2)}(3){TeW6O24}] . 6H(2)O {en = ethyline-diamine} (2). Společným strukturním rysem obou sloučenin je unikátní jednodimenzionální koordinační struktura.

Návaznosti

MSM0021622415, záměr

Název: Molekulární podstata buněčných a tkáňových regulací

Investor: Ministerstvo školství, mládeže a tělovýchovy ČR, Molekulární podstata buněčných a tkáňových regulací

Citovat

DUTTA, D.; A.D. JANA; M. DEBNATH; A. BHAUMIK; Jaromír MAREK a Mahammad ALI. Robust 1D open rack-like architecture in coordination polymers of Anderson POMs [{Na-4(H2O)(14)}{Cu(gly)}(2)][TeMo6O24] and [{Cu(en)(2)}(3){TeW6O24}]: synthesis, characterization and heterogeneous catalytic epoxidation of olefines. Dalton transactions : an international journal of inorganic chemistry. Cambridge: The Royal Society of Chemistry, 2010, roč. 39, č. 48, s. 11551-11559. ISSN 1477-9226.

@article{935619,
   author = {Dutta, D. and Jana, A.D. and Debnath, M. and Bhaumik, A. and Marek, Jaromír and Ali, Mahammad},
   article_location = {Cambridge},
   article_number = {48},
   keywords = {ORGANIC-INORGANIC HYBRID; TRANSITION-METAL-COMPLEXES; RARE-EARTH CATIONS; CHAIN-LIKE POLYMER; BUILDING-BLOCKS; CRYSTAL-STRUCTURE; KEGGIN POLYOXOMETALATE; HYDROTHERMAL SYNTHESIS; HETEROPOLY COMPOUNDS; MASS-SPECTROMETRY},
   language = {eng},
   issn = {1477-9226},
   journal = {Dalton transactions : an international journal of inorganic chemistry},
   title = {Robust 1D open rack-like architecture in coordination polymers of Anderson POMs [{Na-4(H2O)(14)}{Cu(gly)}(2)][TeMo6O24] and [{Cu(en)(2)}(3){TeW6O24}]: synthesis, characterization and heterogeneous catalytic epoxidation of olefines},
   url = {http://pubs.rsc.org/en/Content/ArticleLanding/2010/DT/c0dt00426j},
   volume = {39},
   year = {2010}
}

TY  - JOUR
ID  - 935619
AU  - Dutta, D. - Jana, A.D. - Debnath, M. - Bhaumik, A. - Marek, Jaromír - Ali, Mahammad
PY  - 2010
TI  - Robust 1D open rack-like architecture in coordination polymers of Anderson POMs [{Na-4(H2O)(14)}{Cu(gly)}(2)][TeMo6O24] and [{Cu(en)(2)}(3){TeW6O24}]: synthesis, characterization and heterogeneous catalytic epoxidation of olefines
JF  - Dalton transactions : an international journal of inorganic chemistry
VL  - 39
IS  - 48
SP  - 11551-11559
EP  - 11551-11559
PB  - The Royal Society of Chemistry
SN  - 14779226
KW  - ORGANIC-INORGANIC HYBRID
KW  - TRANSITION-METAL-COMPLEXES
KW  - RARE-EARTH CATIONS
KW  - CHAIN-LIKE POLYMER
KW  - BUILDING-BLOCKS
KW  - CRYSTAL-STRUCTURE
KW  - KEGGIN POLYOXOMETALATE
KW  - HYDROTHERMAL SYNTHESIS
KW  - HETEROPOLY COMPOUNDS
KW  - MASS-SPECTROMETRY
UR  - http://pubs.rsc.org/en/Content/ArticleLanding/2010/DT/c0dt00426j
N2  - Two novel organic-inorganic hybrid tungsto-and molybdo-telurates having formula [{Na-4(H2O)(14)}{Cu(gly)}(2)][TeMo6O24] (1){gly = glycine} and [{Cu(en)(2)}(3){TeW6O24}]center dot 6H(2)O {en = ethyline-diamine} (2) based on Anderson type heteropolyoxometalates (POMs) have been synthesized and characterized by X-ray crystallography. Common structural feature of both 1 and 2 is the presence of a unique 1D open rack-like architecture, where the disc shaped Anderson POMs act as steps and cationic Cu-organic complexes act as handles of the rack. In 1 the independent structural unit is a 1D coordination polymer with the above mentioned rack type architecture, while in 2, these independent rack-like architectures are further extended to a 2D coordination polymer. Heterogeneous catalysis for the epoxidation of cyclohexene and styrene by complexes 1 and 2 showed very good catalytic efficiency.
ER  -

DUTTA, D.; A.D. JANA; M. DEBNATH; A. BHAUMIK; Jaromír MAREK a Mahammad ALI. Robust 1D open rack-like architecture in coordination polymers of Anderson POMs [$\{$Na-4(H2O)(14)$\}\{$Cu(gly)$\}$(2)][TeMo6O24] and [$\{$Cu(en)(2)$\}$(3)$\{$TeW6O24$\}$]: synthesis, characterization and heterogeneous catalytic epoxidation of olefines. \textit{Dalton transactions : an international journal of inorganic chemistry}. Cambridge: The Royal Society of Chemistry, 2010, roč.~39, č.~48, s.~11551-11559. ISSN~1477-9226.

Přehled o publikaci