Polymerisation and Surface Modification of Methacrylate
Monoliths in Polyimide Channels and Polyimide Coated
Capillaries using 660 nm Light Emitting Diodes

J 2011

Polymerisation and Surface Modification of Methacrylate Monoliths in Polyimide Channels and Polyimide Coated Capillaries using 660 nm Light Emitting Diodes

WALSH, Zarah; Paul A. LEVKIN; Silvija ABELE; Silvia SCARMAGNANI; Dominik HEGER et. al.

Basic information

Original name

Polymerisation and Surface Modification of Methacrylate Monoliths in Polyimide Channels and Polyimide Coated Capillaries using 660 nm Light Emitting Diodes

Authors

WALSH, Zarah (372 Ireland); Paul A. LEVKIN (840 United States of America); Silvija ABELE (372 Ireland); Silvia SCARMAGNANI (372 Ireland); Dominik HEGER (203 Czech Republic, belonging to the institution); Petr KLÁN (203 Czech Republic, belonging to the institution); Dermot DIAMOND (372 Ireland); Brett PAULL (372 Ireland); Frantisek SVEC (840 United States of America) and Miroslav MACKA (372 Ireland, guarantor, belonging to the institution)

Edition

Journal of Chromatography A, Amsterdam, Elsevier, 2011, 0021-9673

Other information

Language

English

Type of outcome

Article in a journal

Field of Study

10401 Organic chemistry

Country of publisher

Czech Republic

Confidentiality degree

is not subject to a state or trade secret

Impact factor

Impact factor: 4.531

RIV identification code

RIV/00216224:14310/11:00049770

Organization unit

Faculty of Science

DOI

https://doi.org/10.1016/j.chroma.2011.03.021

UT WoS

000291065500017

Keywords in English

Monolith Photo-initiated polymerisation Visible light Red LED Polyimide Micro-fluidic chips Grafting

Abstract

In the original language

An investigation into the preparation of monolithic separation media utilising a cyanine dye sensitiser/triphenylbutylborate/N-methoxy-4-phenylpyridinium tetrafluoroborate initiating system activated by 660nm light emitting diodes is reported. The work demonstrates multiple uses of redlight initiated polymerisation in the preparation of monolithic stationary phases within polyimide and polyimide coated channels and the modification of monolithic materials with molecules which absorb strongly in the UV region. This initiator complex was used to synthesise poly(butyl methacrylateco- ethylene dimethacrylate) and poly(methyl methacrylate-co-ethylene dimethacrylate) monolithic stationary phases in polyimide coated fused silica capillaries of varying internal diameters, as well as within polyimide micro-fluidic chips.

Links

ED0001/01/01, research and development project

Name: CETOCOEN

GP203/09/P445, research and development project

Name: Luminiscenční a elektrochemická studie látek v ledu

Investor: Czech Science Foundation, Luminescence and Electrochemical Study of Compounds in Ice

MSM0021622413, plan (intention)

Name: Proteiny v metabolismu a při interakci organismů s prostředím

Investor: Ministry of Education, Youth and Sports of the CR, Proteins in metabolism and interaction of organisms with the environment

MUNI/A/0980/2009, interní kód MU

Name: Molekulární a supramolekulární stavební bloky pro nanostrukturované materiály (Acronym: MOSTNAMAT)

Investor: Masaryk University, Category A

Cite

WALSH, Zarah; Paul A. LEVKIN; Silvija ABELE; Silvia SCARMAGNANI; Dominik HEGER; Petr KLÁN; Dermot DIAMOND; Brett PAULL; Frantisek SVEC and Miroslav MACKA. Polymerisation and Surface Modification of Methacrylate Monoliths in Polyimide Channels and Polyimide Coated Capillaries using 660 nm Light Emitting Diodes. Journal of Chromatography A. Amsterdam: Elsevier, 2011, vol. 1218, No 20, p. 2954–2962. ISSN 0021-9673. Available from: https://doi.org/10.1016/j.chroma.2011.03.021.

@article{935970,
   author = {Walsh, Zarah and Levkin, Paul A. and Abele, Silvija and Scarmagnani, Silvia and Heger, Dominik and Klán, Petr and Diamond, Dermot and Paull, Brett and Svec, Frantisek and Macka, Miroslav},
   article_location = {Amsterdam},
   article_number = {20},
   doi = {https://doi.org/10.1016/j.chroma.2011.03.021},
   keywords = {Monolith Photo-initiated polymerisation Visible light Red LED Polyimide Micro-fluidic chips Grafting},
   language = {eng},
   issn = {0021-9673},
   journal = {Journal of Chromatography A},
   title = {Polymerisation and Surface Modification of Methacrylate Monoliths in Polyimide Channels and Polyimide Coated Capillaries using 660 nm Light Emitting Diodes},
   volume = {1218},
   year = {2011}
}

TY  - JOUR
ID  - 935970
AU  - Walsh, Zarah - Levkin, Paul A. - Abele, Silvija - Scarmagnani, Silvia - Heger, Dominik - Klán, Petr - Diamond, Dermot - Paull, Brett - Svec, Frantisek - Macka, Miroslav
PY  - 2011
TI  - Polymerisation and Surface Modification of Methacrylate Monoliths in Polyimide Channels and Polyimide Coated Capillaries using 660 nm Light Emitting Diodes
JF  - Journal of Chromatography A
VL  - 1218
IS  - 20
SP  - 2954–2962
EP  - 2954–2962
PB  - Elsevier
SN  - 00219673
KW  - Monolith Photo-initiated polymerisation Visible light Red LED Polyimide Micro-fluidic chips Grafting
N2  - An investigation into the preparation of monolithic separation media utilising a cyanine dye sensitiser/triphenylbutylborate/N-methoxy-4-phenylpyridinium tetrafluoroborate initiating system activated by 660nm light emitting diodes is reported. The work demonstrates multiple uses of redlight initiated polymerisation in the preparation of monolithic stationary phases within polyimide and polyimide coated channels and the modification of monolithic materials with molecules which absorb strongly in the UV region. This initiator complex was used to synthesise poly(butyl methacrylateco- ethylene dimethacrylate) and poly(methyl methacrylate-co-ethylene dimethacrylate) monolithic stationary phases in polyimide coated fused silica capillaries of varying internal diameters, as well as within polyimide micro-fluidic chips.
ER  -

WALSH, Zarah; Paul A. LEVKIN; Silvija ABELE; Silvia SCARMAGNANI; Dominik HEGER; Petr KLÁN; Dermot DIAMOND; Brett PAULL; Frantisek SVEC and Miroslav MACKA. Polymerisation and Surface Modification of Methacrylate Monoliths in Polyimide Channels and Polyimide Coated Capillaries using 660 nm Light Emitting Diodes. \textit{Journal of Chromatography A}. Amsterdam: Elsevier, 2011, vol.~1218, No~20, p.~2954–2962. ISSN~0021-9673. Available from: https://doi.org/10.1016/j.chroma.2011.03.021.

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