| REVESZ, Agnes, Detlef SCHRODER, Jan ŠVEC, Michaela WIMMEROVÁ and Vladimír ŠINDELÁŘ. Anion Binding by Bambus[6]uril Probed in the Gas Phase and in Solution. J. Phys. Chem. A. American Chemical Society, 2011, vol. 115, No 41, p. 11378–11386. ISSN 1089-5639. Available from: https://dx.doi.org/10.1021/jp205218k. |
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@article{951258,
author = {Revesz, Agnes and Schroder, Detlef and Švec, Jan and Wimmerová, Michaela and Šindelář, Vladimír},
article_number = {41},
doi = {http://dx.doi.org/10.1021/jp205218k},
keywords = {Bambus[6]uril; halide ions; anion binding; condensed phase},
language = {eng},
issn = {1089-5639},
journal = {J. Phys. Chem. A},
title = {Anion Binding by Bambus[6]uril Probed in the Gas Phase and in Solution},
url = {http://pubs.acs.org/doi/abs/10.1021/jp205218k?prevSearch=%255BContrib%253A%2Bsvec%255D&searchHistoryKey=},
volume = {115},
year = {2011}
}
TY - JOUR
ID - 951258
AU - Revesz, Agnes - Schroder, Detlef - Švec, Jan - Wimmerová, Michaela - Šindelář, Vladimír
PY - 2011
TI - Anion Binding by Bambus[6]uril Probed in the Gas Phase and in Solution
JF - J. Phys. Chem. A
VL - 115
IS - 41
SP - 11378–11386
EP - 11378–11386
PB - American Chemical Society
SN - 10895639
KW - Bambus[6]uril
KW - halide ions
KW - anion binding
KW - condensed phase
UR - http://pubs.acs.org/doi/abs/10.1021/jp205218k?prevSearch=%255BContrib%253A%2Bsvec%255D&searchHistoryKey=
L2 - http://pubs.acs.org/doi/abs/10.1021/jp205218k?prevSearch=%255BContrib%253A%2Bsvec%255D&searchHistoryKey=
N2 - Electrospray ionization mass spectrometry (ESI-MS) is used to probe the binding of small anions to the macrocycle of bambus[6]uril. For the halide ions, the experimental patterns suggest F– < Cl– < Br– < I–, which is consistent with the order of anion binding found in the condensed phase. Parallel equilibrium studies in the condensed phase establish the association constants of halide anions and bambus[6]uril in mixed solvents. A detailed analysis of the mass spectrometric data is used to shed light on the correlations between the binding constants in the condensed phase and the ion abundances observed using ESI-MS. From the analysis it becomes apparent that ESI-MS can indeed represent the situation in solution to some extent, but the sampling in the gas-phase experiment is not 1:1 compared to that in solution.
ER -
REVESZ, Agnes, Detlef SCHRODER, Jan ŠVEC, Michaela WIMMEROVÁ and Vladimír ŠINDELÁŘ. Anion Binding by Bambus[6]uril Probed in the Gas Phase and in Solution. \textit{J. Phys. Chem. A}. American Chemical Society, 2011, vol.~115, No~41, p.~11378–11386. ISSN~1089-5639. Available from: https://dx.doi.org/10.1021/jp205218k.
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