Laser-Induced Breakdown Spectroscopy of Molten Metals: 
Influence of Sample Temperature

J 2011

Laser-Induced Breakdown Spectroscopy of Molten Metals: Influence of Sample Temperature

VACULOVIČ, Tomáš; Zbyněk ZVĚŘINA; Vítězslav OTRUBA a Viktor KANICKÝ

Základní údaje

Originální název

Laser-Induced Breakdown Spectroscopy of Molten Metals: Influence of Sample Temperature

Autoři

VACULOVIČ, Tomáš (203 Česká republika, garant, domácí); Zbyněk ZVĚŘINA (203 Česká republika, domácí); Vítězslav OTRUBA (203 Česká republika, domácí) a Viktor KANICKÝ (203 Česká republika, domácí)

Vydání

Zeitschrift fur Naturforschung A, 2011, 0932-0784

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10406 Analytical chemistry

Stát vydavatele

Německo

Utajení

není předmětem státního či obchodního tajemství

Impakt faktor

Impact factor: 0.940

Kód RIV

RIV/00216224:14310/11:00050464

Organizační jednotka

Přírodovědecká fakulta

UT WoS

000299194500010

Klíčová slova anglicky

Laser-Induced Breakdown Spectroscopy; Molten Metals; Sample Temperature

Štítky

AKR, rivok

Změněno: 7. 2. 2012 10:53, doc. Mgr. Tomáš Vaculovič, Ph.D.

Anotace

V originále

The aim of this work was to determine the influence of sample temperature on the laser-induced microplasma (LIP) emission intensity and to ascertain the possibility of laser-induced breakdown spectroscopy (LIBS) utilization for the monitoring of impurities in molten metals. Pure low-melting metals (bismuth, gallium, indium, lead, tin, and zinc) were used for all experiments. It was found out that the LIP emission increases linearly with increasing temperature within the range 25C to 70C above the melting point of the metal. The slope of this change in LIP intensity is related to the transition probability of a given emission line. If the LIP intensity of given solid and molten metals are compared, then their relative change is related to the coefficient of thermal conductivity. The LIBS shows possibilities for the identification of impurities in molten metals. Amounts of impurities in the order of tens mg=kg can be identified.

Návaznosti

GP203/08/P430, projekt VaV

Název: Spektrometrie laserem indukovaného plazmatu (LIBS) kapalin

Investor: Grantová agentura ČR, Spektrometrie laserem indukovaného plazmatu (LIBS) kapalin

Citovat

VACULOVIČ, Tomáš; Zbyněk ZVĚŘINA; Vítězslav OTRUBA a Viktor KANICKÝ. Laser-Induced Breakdown Spectroscopy of Molten Metals: Influence of Sample Temperature. Zeitschrift fur Naturforschung A. 2011, roč. 66a, 10/11, s. 643-648. ISSN 0932-0784.

@article{970096,
   author = {Vaculovič, Tomáš and Zvěřina, Zbyněk and Otruba, Vítězslav and Kanický, Viktor},
   article_number = {10/11},
   keywords = {Laser-Induced Breakdown Spectroscopy; Molten Metals; Sample Temperature},
   language = {eng},
   issn = {0932-0784},
   journal = {Zeitschrift fur Naturforschung A},
   title = {Laser-Induced Breakdown Spectroscopy of Molten Metals: Influence of Sample Temperature},
   volume = {66a},
   year = {2011}
}

TY  - JOUR
ID  - 970096
AU  - Vaculovič, Tomáš - Zvěřina, Zbyněk - Otruba, Vítězslav - Kanický, Viktor
PY  - 2011
TI  - Laser-Induced Breakdown Spectroscopy of Molten Metals: Influence of Sample Temperature
JF  - Zeitschrift fur Naturforschung A
VL  - 66a
IS  - 10/11
SP  - 643-648
EP  - 643-648
SN  - 09320784
KW  - Laser-Induced Breakdown Spectroscopy
KW  - Molten Metals
KW  - Sample Temperature
N2  - The aim of this work was to determine the influence of sample temperature on the laser-induced microplasma (LIP) emission intensity and to ascertain the possibility of laser-induced breakdown spectroscopy (LIBS) utilization for the monitoring of impurities in molten metals. Pure low-melting metals (bismuth, gallium, indium, lead, tin, and zinc) were used for all experiments. It was found out that the LIP emission increases linearly with increasing temperature within the range 25C to 70C above the melting point of the metal. The slope of this change in LIP intensity is related to the transition probability of a given emission line. If the LIP intensity of given solid and molten metals are compared, then their relative change is related to the coefficient of thermal conductivity. The LIBS shows possibilities for the identification of impurities in molten metals. Amounts of impurities in the order of tens mg=kg can be identified.
ER  -

VACULOVIČ, Tomáš; Zbyněk ZVĚŘINA; Vítězslav OTRUBA a Viktor KANICKÝ. Laser-Induced Breakdown Spectroscopy of Molten Metals: Influence of Sample Temperature. \textit{Zeitschrift fur Naturforschung A}. 2011, roč.~66a, 10/11, s.~643-648. ISSN~0932-0784.

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