A Raman spectroscopic study of bukovskýite Fe2(AsO4)(SO4)(OH) .
7H2O, a mineral phase with significant role in arsenic
migration

J 2011

A Raman spectroscopic study of bukovskýite Fe2(AsO4)(SO4)(OH) . 7H2O, a mineral phase with significant role in arsenic migration

LOUN, Jan; Jiří ČEJKA; Jiří SEJKORA; Jakub PLÁŠIL; Milan NOVÁK et al.

Základní údaje

Originální název

A Raman spectroscopic study of bukovskýite Fe2(AsO4)(SO4)(OH) . 7H2O, a mineral phase with significant role in arsenic migration

Autoři

LOUN, Jan; Jiří ČEJKA; Jiří SEJKORA; Jakub PLÁŠIL; Milan NOVÁK; Ray Leslie FROST; Sara PALMER a Eloise C. KEEFFE

Vydání

Journal of Raman Spectroscopy, 2011, 0377-0486

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10500 1.5. Earth and related environmental sciences

Stát vydavatele

Spojené státy

Utajení

není předmětem státního či obchodního tajemství

Impakt faktor

Impact factor: 3.087

Označené pro přenos do RIV

Ano

Kód RIV

RIV/00216224:14310/11:00055985

Organizační jednotka

Přírodovědecká fakulta

DOI

https://doi.org/10.1002/jrs.2900

UT WoS

000293001000017

Klíčová slova anglicky

bukovskyite; Raman spectroscopy; arsenate; sulfate; hydroxyl ions; molecular water

Štítky

AKR, rivok

Změněno: 14. 3. 2012 08:15, prof. RNDr. Milan Novák, CSc.

Anotace

V originále

The Raman spectrum of bukovskyite [Fe2(3+)(OH)(SO4)(AsO4) . 7H2O] has been studied and compared with that of an amorphous gel containing specifically Fe, As and S, which is understood to be an intermediate product in the formation of bukovskyite. The observed bands are assigned to the stretching and bending vibrations of (SO4)2- and (AsO4)3- units, stretching and bending vibrations and vibrational modes of hydrogen-bonded water molecules, stretching and bending vibrations of hydrogen-bonded (OH)- ions and Fe3+ -(O,OH) units. The approximate range of O-H ... O hydrogen bond lengths was inferred from the Raman spectra. Raman spectra of crystalline bukovskyite and of the amorphous gel differ in that the bukovskyite spectrum is more complex, the observed bands are sharp and the degenerate bands of (SO4)2- and (AsO4)3- are split and more intense. Lower wavenumbers of delta H2O bending vibrations in the spectrum of the amorphous gel may indicate the presence of weaker hydrogen bonds compared to those in bukovskyite.

Návaznosti

MSM0021622412, záměr

Název: Interakce mezi chemickými látkami, prostředím a biologickými systémy a jejich důsledky na globální, regionální a lokální úrovni (INCHEMBIOL) (Akronym: INCHEMBIOL)

Investor: Ministerstvo školství, mládeže a tělovýchovy ČR, Interakce mezi chemickými látkami, prostředím a biologickými systémy a jejich důsledky na globální , regionální a lokální úrovni

Citovat

LOUN, Jan; Jiří ČEJKA; Jiří SEJKORA; Jakub PLÁŠIL; Milan NOVÁK; Ray Leslie FROST; Sara PALMER a Eloise C. KEEFFE. A Raman spectroscopic study of bukovskýite Fe2(AsO4)(SO4)(OH) . 7H2O, a mineral phase with significant role in arsenic migration. Journal of Raman Spectroscopy. 2011, roč. 42, č. 7, s. 1596-1600. ISSN 0377-0486. Dostupné z: https://doi.org/10.1002/jrs.2900.

@article{974920,
   author = {Loun, Jan and Čejka, Jiří and Sejkora, Jiří and Plášil, Jakub and Novák, Milan and Frost, Ray Leslie and Palmer, Sara and Keeffe, Eloise C.},
   article_number = {7},
   doi = {https://doi.org/10.1002/jrs.2900},
   keywords = {bukovskyite; Raman spectroscopy; arsenate; sulfate; hydroxyl ions; molecular water},
   language = {eng},
   issn = {0377-0486},
   journal = {Journal of Raman Spectroscopy},
   title = {A Raman spectroscopic study of bukovskýite Fe2(AsO4)(SO4)(OH) . 7H2O, a mineral phase with significant role in arsenic migration},
   volume = {42},
   year = {2011}
}

TY  - JOUR
ID  - 974920
AU  - Loun, Jan - Čejka, Jiří - Sejkora, Jiří - Plášil, Jakub - Novák, Milan - Frost, Ray Leslie - Palmer, Sara - Keeffe, Eloise C.
PY  - 2011
TI  - A Raman spectroscopic study of bukovskýite Fe2(AsO4)(SO4)(OH) . 7H2O, a mineral phase with significant role in arsenic migration
JF  - Journal of Raman Spectroscopy
VL  - 42
IS  - 7
SP  - 1596-1600
EP  - 1596-1600
SN  - 03770486
KW  - bukovskyite
KW  - Raman spectroscopy
KW  - arsenate
KW  - sulfate
KW  - hydroxyl ions
KW  - molecular water
N2  - The Raman spectrum of bukovskyite [Fe2(3+)(OH)(SO4)(AsO4) . 7H2O] has been studied and compared with that of an amorphous gel containing specifically Fe, As and S, which is understood to be an intermediate product in the formation of bukovskyite. The observed bands are assigned to the stretching and bending vibrations of (SO4)2- and (AsO4)3- units, stretching and bending vibrations and vibrational modes of hydrogen-bonded water molecules, stretching and bending vibrations of hydrogen-bonded (OH)- ions and Fe3+ -(O,OH) units. The approximate range of O-H ... O hydrogen bond lengths was inferred from the Raman spectra. Raman spectra of crystalline bukovskyite and of the amorphous gel differ in that the bukovskyite spectrum is more complex, the observed bands are sharp and the degenerate bands of (SO4)2- and (AsO4)3- are split and more intense. Lower wavenumbers of delta H2O bending vibrations in the spectrum of the amorphous gel may indicate the presence of weaker hydrogen bonds compared to those in bukovskyite.
ER  -

LOUN, Jan; Jiří ČEJKA; Jiří SEJKORA; Jakub PLÁŠIL; Milan NOVÁK; Ray Leslie FROST; Sara PALMER a Eloise C. KEEFFE. A Raman spectroscopic study of bukovskýite Fe2(AsO4)(SO4)(OH) . 7H2O, a mineral phase with significant role in arsenic migration. \textit{Journal of Raman Spectroscopy}. 2011, roč.~42, č.~7, s.~1596-1600. ISSN~0377-0486. Dostupné z: https://doi.org/10.1002/jrs.2900.

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