Detection of melamine in infant formula and grain powder by
surface-assisted laser desorption/ionization mass spectrometry

J 2012

Detection of melamine in infant formula and grain powder by surface-assisted laser desorption/ionization mass spectrometry

HSIEH, Yi-Ting; Wen-Tsen CHEN; Iva TOMALOVÁ; Jan PREISLER; Huan-Tsung CHANG et. al.

Základní údaje

Originální název

Detection of melamine in infant formula and grain powder by surface-assisted laser desorption/ionization mass spectrometry

Autoři

HSIEH, Yi-Ting; Wen-Tsen CHEN; Iva TOMALOVÁ; Jan PREISLER a Huan-Tsung CHANG

Vydání

Rapid Communications in Mass Spectrometry, Wiley InterScience, 2012, 0951-4198

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10406 Analytical chemistry

Stát vydavatele

Spojené státy

Utajení

není předmětem státního či obchodního tajemství

Odkazy

URL

Impakt faktor

Impact factor: 2.509

Kód RIV

RIV/00216224:14740/12:00057422

Organizační jednotka

Středoevropský technologický institut

DOI

https://doi.org/10.1002/rcm.6238

UT WoS

000304154300001

Klíčová slova anglicky

Melamine; Gold Nanoparticles; SALDI MS

Štítky

ok, rivok

Příznaky

Recenzováno

Změněno: 15. 2. 2018 22:17, prof. Mgr. Jan Preisler, Ph.D.

Anotace

V originále

We have developed a method for the determination of melamine (MEL), ammeline (AMN), and ammelide (AMD) by surface-assisted laser desorption/ionization mass spectrometry (SALDI-MS) using gold nanoparticles (Au NPs). The major peaks for MEL, AMN, and AMD at m/z 127.07, 128.05, and 129.04 are assigned to the [MEL + H]+, [AMN + H]+, and [AMD + H]+ ions. Because the three tested compounds adsorb weakly onto the surfaces of the Au NPs through Au–N bonding, they can be easily concentrated from complex samples by applying a simple trapping/centrifugation process. The SALDI-MS method provides limits of detection of 5, 10, and 300 nM for MEL, AMN, and AMD, respectively, at a signal-to-noise ratio of 3. The signal variation for 150-shot average spectra of the three analytes within the same spot was 15%, and the batch-to-batch variation was 20%. We have validated the practicality of this approach by the analysis of these three analytes in infant formula and grain powder. This simple and rapid SALDI-MS approach holds great potential for screening of MEL in foods.

Návaznosti

ED1.1.00/02.0068, projekt VaV

Název: CEITEC - central european institute of technology

GCP206/10/J012, projekt VaV

Název: Analýza biomolekul hmotnostní spektrometrií s laserovou desorpcí/ionizací za účasti nanomateriálů

Investor: Grantová agentura ČR, Analýza biomolekul hmotnostní spektrometrií s laserovou desorpcí/ionizací za účasti nanomateriálů

Citovat

HSIEH, Yi-Ting; Wen-Tsen CHEN; Iva TOMALOVÁ; Jan PREISLER a Huan-Tsung CHANG. Detection of melamine in infant formula and grain powder by surface-assisted laser desorption/ionization mass spectrometry. Rapid Communications in Mass Spectrometry. Wiley InterScience, 2012, roč. 26, č. 12, s. 1393-1398. ISSN 0951-4198. Dostupné z: https://doi.org/10.1002/rcm.6238.

@article{983982,
   author = {Hsieh, YiandTing and Chen, WenandTsen and Tomalová, Iva and Preisler, Jan and Chang, HuanandTsung},
   article_number = {12},
   doi = {https://doi.org/10.1002/rcm.6238},
   keywords = {Melamine; Gold Nanoparticles; SALDI MS},
   language = {eng},
   issn = {0951-4198},
   journal = {Rapid Communications in Mass Spectrometry},
   title = {Detection of melamine in infant formula and grain powder by surface-assisted laser desorption/ionization mass spectrometry},
   url = {http://onlinelibrary.wiley.com/doi/10.1002/rcm.6238/abstract;jsessionid=04DA26CB9CF54ABD25D35FC3AED0E339.d03t01},
   volume = {26},
   year = {2012}
}

TY  - JOUR
ID  - 983982
AU  - Hsieh, Yi-Ting - Chen, Wen-Tsen - Tomalová, Iva - Preisler, Jan - Chang, Huan-Tsung
PY  - 2012
TI  - Detection of melamine in infant formula and grain powder by surface-assisted laser desorption/ionization mass spectrometry
JF  - Rapid Communications in Mass Spectrometry
VL  - 26
IS  - 12
SP  - 1393-1398
EP  - 1393-1398
PB  - Wiley InterScience
SN  - 09514198
KW  - Melamine
KW  - Gold Nanoparticles
KW  - SALDI MS
UR  - http://onlinelibrary.wiley.com/doi/10.1002/rcm.6238/abstract;jsessionid=04DA26CB9CF54ABD25D35FC3AED0E339.d03t01
L2  - http://onlinelibrary.wiley.com/doi/10.1002/rcm.6238/abstract;jsessionid=04DA26CB9CF54ABD25D35FC3AED0E339.d03t01
N2  - We have developed a method for the determination of melamine (MEL), ammeline (AMN), and ammelide (AMD) by surface-assisted laser desorption/ionization mass spectrometry (SALDI-MS) using gold nanoparticles (Au NPs). The major peaks for MEL, AMN, and AMD at m/z 127.07, 128.05, and 129.04 are assigned to the [MEL + H]+, [AMN + H]+, and [AMD + H]+ ions. Because the three tested compounds adsorb weakly onto the surfaces of the Au NPs through Au–N bonding, they can be easily concentrated from complex samples by applying a simple trapping/centrifugation process. The SALDI-MS method provides limits of detection of 5, 10, and 300 nM for MEL, AMN, and AMD, respectively, at a signal-to-noise ratio of 3. The signal variation for 150-shot average spectra of the three analytes within the same spot was 15%, and the batch-to-batch variation was 20%. We have validated the practicality of this approach by the analysis of these three analytes in infant formula and grain powder. This simple and rapid SALDI-MS approach holds great potential for screening of MEL in foods.
ER  -

HSIEH, Yi-Ting; Wen-Tsen CHEN; Iva TOMALOVÁ; Jan PREISLER a Huan-Tsung CHANG. Detection of melamine in infant formula and grain powder by surface-assisted laser desorption/ionization mass spectrometry. \textit{Rapid Communications in Mass Spectrometry}. Wiley InterScience, 2012, roč.~26, č.~12, s.~1393-1398. ISSN~0951-4198. Dostupné z: https://doi.org/10.1002/rcm.6238.

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