First functionalized diorganotin (IV) derivative containing the
imidobis(diphenylselenophosphinate-Se,Se') ligand. The
synthesis and X-ray crystal structures of
Bu2Sn[{N(SePPh2)(2)-Se,Se'}(2)] and
Ph2ClSn[N(SePPh2)(2)-Se,Se'].H2O

J 1997

First functionalized diorganotin (IV) derivative containing the imidobis(diphenylselenophosphinate-Se,Se') ligand. The synthesis and X-ray crystal structures of Bu2Sn[{N(SePPh2)(2)-Se,Se'}(2)] and Ph2ClSn[N(SePPh2)(2)-Se,Se'].H2O

FLORES SANTOS, L.; R. CEA OLIVARES; S. HERNANDEZ ORTEGA; RA TOSCANO; V. GARCIA MONTALVO et. al.

Základní údaje

Originální název

First functionalized diorganotin (IV) derivative containing the imidobis(diphenylselenophosphinate-Se,Se') ligand. The synthesis and X-ray crystal structures of Bu2Sn[{N(SePPh2)(2)-Se,Se'}(2)] and Ph2ClSn[N(SePPh2)(2)-Se,Se'].H2O

Autoři

FLORES SANTOS, L. (484 Mexiko); R. CEA OLIVARES (484 Mexiko); S. HERNANDEZ ORTEGA (484 Mexiko); RA TOSCANO (484 Mexiko); V. GARCIA MONTALVO (484 Mexiko); J. NOVOSAD (203 Česká republika) a JD WOOLLINS (826 Velká Británie a Severní Irsko)

Vydání

J. Organomet. Chem. 1997, 0022-328X

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10402 Inorganic and nuclear chemistry

Stát vydavatele

Švýcarsko

Utajení

není předmětem státního či obchodního tajemství

Impakt faktor

Impact factor: 1.724

Kód RIV

RIV/00216224:14310/97:00000592

Organizační jednotka

Přírodovědecká fakulta

Klíčová slova anglicky

MOLECULAR-STRUCTURE; ORGANOTIN CARBOXYLATES; CHEMISTRY; COMPLEXES; ACID

Štítky

ACID, chemistry, Complexes, MOLECULAR-STRUCTURE, ORGANOTIN CARBOXYLATES

Změněno: 27. 5. 2003 05:03, doc. RNDr. Josef Novosad, CSc.

Anotace

V originále

Reaction of the appropriate R2SnCl2 with the potassium salt of the imidobis(diphenylselenophosphinate-Se,Se') ligand (1c) in 1:2 stoichiometry yields n-Bu2Sn[{N(SePPh2}(2)-Se,Se')(2)] (2) and Ph2ClSn[N(SePPh2)(2)-Se,Se']. H2O (3). The crystal and the molecular structures of both compounds were determined by X-ray diffractometry. The core geometry in compound 2 is a quasi perfect octahedron. Two selenide ligands are coordinated symmetrically to the tin atom forming a spiro-bicyclic NP2Se2SnSe2P2N system [Sigma(Se-Sn-Se) = 360 degrees]. Both organo substituents are in trans positions [(C'-Sn-C'A) = 180.0(1)degrees] and they are almost perpendicular to the SnSe4 plane. In derivative 3 only one selenium-based ligand is coordinated asymmetrically to the tin atom and unexpectedly a chlorine atom remains attached to the metal center. The geometry around the tin atom corresponds to a distorted trigonal bipyramid with the Se(1) and Cl atoms at the axial positions.

Návaznosti

MSM 143100011, záměr

Název: Struktura a vazebné poměry, vlastnosti a analýza syntetických a přírodních molekulových ansamblů

Investor: Ministerstvo školství, mládeže a tělovýchovy ČR, Struktura a vazebné poměry, vlastnosti a analýza syntetických a přírodních molekulových ansamblů

Citovat

FLORES SANTOS, L.; R. CEA OLIVARES; S. HERNANDEZ ORTEGA; RA TOSCANO; V. GARCIA MONTALVO; J. NOVOSAD a JD WOOLLINS. First functionalized diorganotin (IV) derivative containing the imidobis(diphenylselenophosphinate-Se,Se') ligand. The synthesis and X-ray crystal structures of Bu2Sn[{N(SePPh2)(2)-Se,Se'}(2)] and Ph2ClSn[N(SePPh2)(2)-Se,Se'].H2O. J. Organomet. Chem. 1997, roč. 1997, č. 544, s. 37-41. ISSN 0022-328X.

@article{197888,
   author = {Flores Santos, L. and Cea Olivares, R. and Hernandez Ortega, S. and Toscano, RA and Garcia Montalvo, V. and Novosad, J. and Woollins, JD},
   article_number = {544},
   keywords = {MOLECULAR-STRUCTURE; ORGANOTIN CARBOXYLATES; CHEMISTRY; COMPLEXES; ACID},
   language = {eng},
   issn = {0022-328X},
   journal = {J. Organomet. Chem.},
   title = {First functionalized diorganotin (IV) derivative containing the imidobis(diphenylselenophosphinate-Se,Se') ligand. The synthesis and X-ray crystal structures of Bu2Sn[{N(SePPh2)(2)-Se,Se'}(2)] and Ph2ClSn[N(SePPh2)(2)-Se,Se'].H2O},
   volume = {1997},
   year = {1997}
}

TY  - JOUR
ID  - 197888
AU  - Flores Santos, L. - Cea Olivares, R. - Hernandez Ortega, S. - Toscano, RA - Garcia Montalvo, V. - Novosad, J. - Woollins, JD
PY  - 1997
TI  - First functionalized diorganotin (IV) derivative containing the imidobis(diphenylselenophosphinate-Se,Se') ligand. The synthesis and X-ray crystal structures of Bu2Sn[{N(SePPh2)(2)-Se,Se'}(2)] and Ph2ClSn[N(SePPh2)(2)-Se,Se'].H2O
JF  - J. Organomet. Chem.
VL  - 1997
IS  - 544
SP  - 37-41
EP  - 37-41
SN  - 0022328X
KW  - MOLECULAR-STRUCTURE
KW  - ORGANOTIN CARBOXYLATES
KW  - CHEMISTRY
KW  - COMPLEXES
KW  - ACID
N2  - Reaction of the appropriate R2SnCl2 with the potassium salt of the imidobis(diphenylselenophosphinate-Se,Se') ligand (1c) in 1:2 stoichiometry yields n-Bu2Sn[{N(SePPh2}(2)-Se,Se')(2)] (2) and Ph2ClSn[N(SePPh2)(2)-Se,Se']. H2O (3). The crystal and the molecular structures of both compounds were determined by X-ray diffractometry. The core geometry in compound 2 is a quasi perfect octahedron. Two selenide ligands are coordinated symmetrically to the tin atom forming a spiro-bicyclic NP2Se2SnSe2P2N system [Sigma(Se-Sn-Se) = 360 degrees]. Both organo substituents are in trans positions [(C'-Sn-C'A) = 180.0(1)degrees] and they are almost perpendicular to the SnSe4 plane. In derivative 3 only one selenium-based ligand is coordinated asymmetrically to the tin atom and unexpectedly a chlorine atom remains attached to the metal center. The geometry around the tin atom corresponds to a distorted trigonal bipyramid with the Se(1) and Cl atoms at the axial positions.
ER  -

FLORES SANTOS, L.; R. CEA OLIVARES; S. HERNANDEZ ORTEGA; RA TOSCANO; V. GARCIA MONTALVO; J. NOVOSAD a JD WOOLLINS. First functionalized diorganotin (IV) derivative containing the imidobis(diphenylselenophosphinate-Se,Se') ligand. The synthesis and X-ray crystal structures of Bu2Sn[$\{$N(SePPh2)(2)-Se,Se'$\}$(2)] and Ph2ClSn[N(SePPh2)(2)-Se,Se'].H2O. \textit{J. Organomet. Chem.}. 1997, roč.~1997, č.~544, s.~37-41. ISSN~0022-328X.

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