Displacement of triphenylphosphine from Cu(PPh3)2NO3 and
Co(PPh3)2Cl2 by a diselenoimidodiphosphinato ligand. X-ray
cryst. structure of (PPh3)Cu[Ph2P(Se)NP(Se)Ph2] and
Co[Ph2P(Se)NP(Se)Ph2]2 containing the novel CuSe2P2N and
CoSe2P2N inorg. metallocycles

J 1999

Displacement of triphenylphosphine from Cu(PPh3)2NO3 and Co(PPh3)2Cl2 by a diselenoimidodiphosphinato ligand. X-ray cryst. structure of (PPh3)Cu[Ph2P(Se)NP(Se)Ph2] and Co[Ph2P(Se)NP(Se)Ph2]2 containing the novel CuSe2P2N and CoSe2P2N inorg. metallocycles

NOVOSAD, Josef; Marek NEČAS; Jaromír MAREK; Panagiotis VELTSISTAS; Christos PAPADIMITRIOU et. al.

Základní údaje

Originální název

Displacement of triphenylphosphine from Cu(PPh3)2NO3 and Co(PPh3)2Cl2 by a diselenoimidodiphosphinato ligand. X-ray cryst. structure of (PPh3)Cu[Ph2P(Se)NP(Se)Ph2] and Co[Ph2P(Se)NP(Se)Ph2]2 containing the novel CuSe2P2N and CoSe2P2N inorg. metallocycles

Autoři

NOVOSAD, Josef; Marek NEČAS; Jaromír MAREK ; Panagiotis VELTSISTAS; Christos PAPADIMITRIOU; Ionel HAIDUC; Makoto WATANABE a Derek J. WOOLLINS

Vydání

Inorganica Chimica Acta, USA, Elsevier Science, 1999, 0020-1693

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10402 Inorganic and nuclear chemistry

Stát vydavatele

Spojené státy

Utajení

není předmětem státního či obchodního tajemství

Impakt faktor

Impact factor: 1.295

Kód RIV

RIV/00216224:14310/99:00001110

Organizační jednotka

Přírodovědecká fakulta

UT WoS

000081407600018

Klíčová slova anglicky

crystal structures; copper complexes; diselenoimidodiphosphinato complexes

Štítky

copper complexes, crystal structures, diselenoimidodiphosphinato complexes

Změněno: 25. 6. 2009 12:03, doc. Mgr. Marek Nečas, Ph.D.

Anotace

V originále

The reaction of Cu(PPh3)2NO3 with K[Ph2P(Se)-N-P(Se)Ph2] produced a tricoordinate copper(I) complex, Cu(PPh3)[Ph2P(Se)-N-P(Se)Ph2], containing the novel inorganic (carbon-free) CuSe2P2N metallocycle. The same diselenium reagent gave with Co(PPh3)2Cl2 a spirobicyclic compound Co[Ph2P(Se)-N-P(Se)Ph2]2, containing the novel inorganic CoSe2P2N metallocycle. The crystal structure of the two compounds was investigated by X-Ray diffraction. In both compounds the inorganic metallocycles are nonplanar and display strongly distorted twisted boat conformations.

Návaznosti

MSM 143100011, záměr

Název: Struktura a vazebné poměry, vlastnosti a analýza syntetických a přírodních molekulových ansamblů

Investor: Ministerstvo školství, mládeže a tělovýchovy ČR, Struktura a vazebné poměry, vlastnosti a analýza syntetických a přírodních molekulových ansamblů

Citovat

NOVOSAD, Josef; Marek NEČAS; Jaromír MAREK; Panagiotis VELTSISTAS; Christos PAPADIMITRIOU; Ionel HAIDUC; Makoto WATANABE a Derek J. WOOLLINS. Displacement of triphenylphosphine from Cu(PPh3)2NO3 and Co(PPh3)2Cl2 by a diselenoimidodiphosphinato ligand. X-ray cryst. structure of (PPh3)Cu[Ph2P(Se)NP(Se)Ph2] and Co[Ph2P(Se)NP(Se)Ph2]2 containing the novel CuSe2P2N and CoSe2P2N inorg. metallocycles. Inorganica Chimica Acta. USA: Elsevier Science, 1999, roč. 290, č. 2, s. 256-260. ISSN 0020-1693.

@article{207451,
   author = {Novosad, Josef and Nečas, Marek and Marek, Jaromír and Veltsistas, Panagiotis and Papadimitriou, Christos and Haiduc, Ionel and Watanabe, Makoto and Woollins, Derek J.},
   article_location = {USA},
   article_number = {2},
   keywords = {crystal structures; copper complexes; diselenoimidodiphosphinato complexes},
   language = {eng},
   issn = {0020-1693},
   journal = {Inorganica Chimica Acta},
   title = {Displacement of triphenylphosphine from Cu(PPh3)2NO3 and Co(PPh3)2Cl2 by a diselenoimidodiphosphinato ligand. X-ray cryst. structure of (PPh3)Cu[Ph2P(Se)NP(Se)Ph2] and Co[Ph2P(Se)NP(Se)Ph2]2 containing the novel CuSe2P2N and CoSe2P2N inorg. metallocycles},
   volume = {290},
   year = {1999}
}

TY  - JOUR
ID  - 207451
AU  - Novosad, Josef - Nečas, Marek - Marek, Jaromír - Veltsistas, Panagiotis - Papadimitriou, Christos - Haiduc, Ionel - Watanabe, Makoto - Woollins, Derek J.
PY  - 1999
TI  - Displacement of triphenylphosphine from Cu(PPh3)2NO3 and Co(PPh3)2Cl2 by a diselenoimidodiphosphinato ligand. X-ray cryst. structure of (PPh3)Cu[Ph2P(Se)NP(Se)Ph2] and Co[Ph2P(Se)NP(Se)Ph2]2 containing the novel CuSe2P2N and CoSe2P2N inorg. metallocycles
JF  - Inorganica Chimica Acta
VL  - 290
IS  - 2
SP  - 256
EP  - 256
PB  - Elsevier Science
SN  - 00201693
KW  - crystal structures
KW  - copper complexes
KW  - diselenoimidodiphosphinato complexes
N2  - The reaction of Cu(PPh3)2NO3 with K[Ph2P(Se)-N-P(Se)Ph2] produced a tricoordinate copper(I) complex, Cu(PPh3)[Ph2P(Se)-N-P(Se)Ph2], containing the novel inorganic (carbon-free) CuSe2P2N metallocycle. The same diselenium reagent gave with Co(PPh3)2Cl2 a spirobicyclic compound Co[Ph2P(Se)-N-P(Se)Ph2]2, containing the novel inorganic CoSe2P2N metallocycle. The crystal structure of the two compounds was investigated by X-Ray diffraction. In both compounds the inorganic metallocycles are nonplanar and display strongly distorted twisted boat conformations.
ER  -

NOVOSAD, Josef; Marek NEČAS; Jaromír MAREK; Panagiotis VELTSISTAS; Christos PAPADIMITRIOU; Ionel HAIDUC; Makoto WATANABE a Derek J. WOOLLINS. Displacement of triphenylphosphine from Cu(PPh3)2NO3 and Co(PPh3)2Cl2 by a diselenoimidodiphosphinato ligand. X-ray cryst. structure of (PPh3)Cu[Ph2P(Se)NP(Se)Ph2] and Co[Ph2P(Se)NP(Se)Ph2]2 containing the novel CuSe2P2N and CoSe2P2N inorg. metallocycles. \textit{Inorganica Chimica Acta}. USA: Elsevier Science, 1999, roč.~290, č.~2, s.~256-260. ISSN~0020-1693.

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