Detailed Information on Publication Record
1996
Ungewohnliche Koordination am Kalium des 18-Krone-6 Komplexes von Tetraphenyldiselenoimidodiphosphinat und der analogen Schwefelverbindung Struktur von 18-Krone-6-Tetraphenyldiselenoimidophosphin.
EBERT, K., Raymundo Cea OLIVARES, G. ESPINOSA PEREZ, M. ESTRADA, Josef NOVOSAD et. al.Basic information
Original name
Ungewohnliche Koordination am Kalium des 18-Krone-6 Komplexes von Tetraphenyldiselenoimidodiphosphinat und der analogen Schwefelverbindung Struktur von 18-Krone-6-Tetraphenyldiselenoimidophosphin.
Authors
EBERT, K. (276 Germany, guarantor), Raymundo Cea OLIVARES (484 Mexico), G. ESPINOSA PEREZ (484 Mexico), M. ESTRADA (484 Mexico), Josef NOVOSAD (203 Czech Republic) and J. D. WOOLLINS (826 United Kingdom of Great Britain and Northern Ireland)
Edition
Z. Naturforsch. 1996, 0932-0784
Other information
Language
English
Type of outcome
Článek v odborném periodiku
Field of Study
10402 Inorganic and nuclear chemistry
Country of publisher
Germany
Confidentiality degree
není předmětem státního či obchodního tajemství
RIV identification code
RIV/00216224:14310/96:00005901
Organization unit
Faculty of Science
Keywords in English
ALKALINE-EARTH CATIONS; FREE CHELATE RINGS; X-RAY STRUCTURE; MOLECULAR-STRUCTURES; CRYSTAL-STRUCTURES; DERIVATIVES; CHEMISTRY; ARYL
Tags
Změněno: 27/5/2003 05:18, doc. RNDr. Josef Novosad, CSc.
Abstract
V originále
A [K(18-crown-6)] salt of the (Ph(2)PSe)(2)NH ligand was obtained by reaction of [K(Ph(2)PSe)(2)N] with 18-crown-6 [monoclinic space group C2/c with the cell parameters a = 20.310(2), b = 8.894(2), c = 22.978(3) Angstrom, beta = 114.66(2)degrees, and Z = 4]. The potassium ion has the rare coordination number 10, It is coordinated to the six oxygen atoms of the crown ether and to four carbon atoms, two from each of the two anionic Ligands neighboring the cationic moiety.
Links
| MSM 143100011, plan (intention) |
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