New P-S-N containing ring systems. Reaction of
2,4-(naphthalene-1,8-diyl)-1,3,2,4-dithiadiphosphetane-2,4-disu
lfide and its 4-methoxonaphthalene derivative with
hexamethyldisilazane.

J 1998

New P-S-N containing ring systems. Reaction of 2,4-(naphthalene-1,8-diyl)-1,3,2,4-dithiadiphosphetane-2,4-disulfide and its 4-methoxonaphthalene derivative with hexamethyldisilazane.

KILIÁN, Petr; Jaromír MAREK; Jiří TOUŽÍN; Otakar HUMPA; Josef NOVOSAD et al.

Základní údaje

Originální název

New P-S-N containing ring systems. Reaction of 2,4-(naphthalene-1,8-diyl)-1,3,2,4-dithiadiphosphetane-2,4-disulfide and its 4-methoxonaphthalene derivative with hexamethyldisilazane.

Autoři

KILIÁN, Petr; Jaromír MAREK ; Jiří TOUŽÍN; Otakar HUMPA; Josef NOVOSAD; J. D. WOOLLINNS a Radek MAREK

Vydání

J. Chem. Soc. Dalton Trans. 1998, 0300-9246

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10402 Inorganic and nuclear chemistry

Stát vydavatele

Velká Británie a Severní Irsko

Utajení

není předmětem státního či obchodního tajemství

Impakt faktor

Impact factor: 2.507

Označené pro přenos do RIV

Ano

Kód RIV

RIV/00216224:14310/98:00005903

Organizační jednotka

Přírodovědecká fakulta

Klíčová slova anglicky

X-RAY STRUCTURE; NMR

Štítky

NMR, X-RAY STRUCTURE

Změněno: 21. 5. 2003 14:55, doc. RNDr. Jiří Toužín, CSc.

Anotace

V originále

Reaction of 2,4-(naphthalene-1,8-diyl)-1,3,2,4-dithiadiphosphetane 2,4-disulfide 1 with hexamethyldisilazane (hmds) in acetonitrile gave the N,N'-bis(trimethylsilyl)acetamidinium salt of the [(C10H6)P(S)(NHSiMe3)SP(S)(2)](-) anion 2, a product of P,S, ring cleavage, together with the new thiazaphosphetidine (C10H6)P(S)SN(SiMe3)P(S) 3. Analogous (methoxy derived) products to 2 (2a, 2b) and 3 (3a) were obtained when 2,4-(4-methoxynaphthalene-1,8-diyl)-1,3,2,4-dithiadiphosphetane 2,4-disulfide 1a was used instead of 1. When the reaction of 1 with hmds was performed in dichloromethane a mixture of the products was obtained, from which the hexamethyldisilazan-2-ium salt of the anion of identical structure to that in 2 has been isolated. No reaction occurred when a solventless system was used. The new compounds were studied spectroscopically (one-and two-dimensional NMR, IR spectroscopy) and by X-ray crystallography (3, 3a and 4).

Návaznosti

GA203/97/0955, projekt VaV

Název: Studium syntézy, struktury a vazebných poměrů ve sloučeninách obsahujících současně dusík, fosfor, chalkogen a/nebo halogen

Investor: Grantová agentura ČR, Studium syntézy, struktury a vazebných poměrů ve sloučeninách obsahujících současně dusík, fosfor, chalkogen a/nebo halogen

Citovat

KILIÁN, Petr; Jaromír MAREK; Jiří TOUŽÍN; Otakar HUMPA; Josef NOVOSAD; J. D. WOOLLINNS a Radek MAREK. New P-S-N containing ring systems. Reaction of 2,4-(naphthalene-1,8-diyl)-1,3,2,4-dithiadiphosphetane-2,4-disulfide and its 4-methoxonaphthalene derivative with hexamethyldisilazane. J. Chem. Soc. Dalton Trans. 1998, roč. 1998, č. 7, s. 1175-1180. ISSN 0300-9246.

@article{211971,
   author = {Kilián, Petr and Marek, Jaromír and Toužín, Jiří and Humpa, Otakar and Novosad, Josef and Woollinns, J. D. and Marek, Radek},
   article_number = {7},
   keywords = {X-RAY STRUCTURE; NMR},
   language = {eng},
   issn = {0300-9246},
   journal = {J. Chem. Soc. Dalton Trans.},
   title = {New P-S-N containing ring systems. Reaction of 2,4-(naphthalene-1,8-diyl)-1,3,2,4-dithiadiphosphetane-2,4-disulfide and its 4-methoxonaphthalene derivative with hexamethyldisilazane.},
   volume = {1998},
   year = {1998}
}

TY  - JOUR
ID  - 211971
AU  - Kilián, Petr - Marek, Jaromír - Toužín, Jiří - Humpa, Otakar - Novosad, Josef - Woollinns, J. D. - Marek, Radek
PY  - 1998
TI  - New P-S-N containing ring systems. Reaction of 2,4-(naphthalene-1,8-diyl)-1,3,2,4-dithiadiphosphetane-2,4-disulfide and its 4-methoxonaphthalene derivative with hexamethyldisilazane.
JF  - J. Chem. Soc. Dalton Trans.
VL  - 1998
IS  - 7
SP  - 1175
EP  - 1175
SN  - 03009246
KW  - X-RAY STRUCTURE
KW  - NMR
N2  - Reaction of 2,4-(naphthalene-1,8-diyl)-1,3,2,4-dithiadiphosphetane 2,4-disulfide 1 with hexamethyldisilazane (hmds) in acetonitrile gave the N,N'-bis(trimethylsilyl)acetamidinium salt of the [(C10H6)P(S)(NHSiMe3)SP(S)(2)](-) anion 2, a product of P,S, ring cleavage, together with the new thiazaphosphetidine (C10H6)P(S)SN(SiMe3)P(S) 3. Analogous (methoxy derived) products to 2 (2a, 2b) and 3 (3a) were obtained when 2,4-(4-methoxynaphthalene-1,8-diyl)-1,3,2,4-dithiadiphosphetane 2,4-disulfide 1a was used instead of 1. When the reaction of 1 with hmds was performed in dichloromethane a mixture of the products was obtained, from which the hexamethyldisilazan-2-ium salt of the anion of identical structure to that in 2 has been isolated. No reaction occurred when a solventless system was used. The new compounds were studied spectroscopically (one-and two-dimensional NMR, IR spectroscopy) and by X-ray crystallography (3, 3a and 4).
ER  -

KILIÁN, Petr; Jaromír MAREK; Jiří TOUŽÍN; Otakar HUMPA; Josef NOVOSAD; J. D. WOOLLINNS a Radek MAREK. New P-S-N containing ring systems. Reaction of 2,4-(naphthalene-1,8-diyl)-1,3,2,4-dithiadiphosphetane-2,4-disulfide and its 4-methoxonaphthalene derivative with hexamethyldisilazane. \textit{J. Chem. Soc. Dalton Trans.}. 1998, roč.~1998, č.~7, s.~1175-1180. ISSN~0300-9246.

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