Syntheses and Structures of Donor-Acceptor Complexes of
Selenium Dioxide with Pyridine and Trimethylamine

J 2002

Syntheses and Structures of Donor-Acceptor Complexes of Selenium Dioxide with Pyridine and Trimethylamine

TOUŽÍN, Jiří; Kamila NEPLECHOVÁ; Zdirad ŽÁK a Miloš ČERNÍK

Základní údaje

Originální název

Syntheses and Structures of Donor-Acceptor Complexes of Selenium Dioxide with Pyridine and Trimethylamine

Autoři

TOUŽÍN, Jiří; Kamila NEPLECHOVÁ; Zdirad ŽÁK a Miloš ČERNÍK

Vydání

Collection of Czechoslovak Chemical Communications, Prague, Imperie "Politika" 2002, 0010-0765

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10402 Inorganic and nuclear chemistry

Stát vydavatele

Česká republika

Utajení

není předmětem státního či obchodního tajemství

Impakt faktor

Impact factor: 0.848

Kód RIV

RIV/00216224:14310/02:00007334

Organizační jednotka

Přírodovědecká fakulta

UT WoS

000176577500004

Klíčová slova anglicky

DA-complex; Selenium dioxide; Pyridine; Trimethylamine; Crystal structure determination; Raman spectra; Normal coordinate analysis

Štítky

Crystal structure determination, DA-complex, Normal coordinate analysis, Pyridine, Raman spectra, Selenium dioxide, Trimethylamine

Změněno: 21. 5. 2003 10:51, RNDr. Kamila Neplechová, Ph.D.

Anotace

V originále

Donor-acceptor complexes pyridine(py).SeO2 and trimethylamine(TMA).SeO2 were prepared by direct reactions of solid selenium dioxide with the amines. Both are white solids decomposing slowly at room temperature. The former decomposes into its components, while the latter undergoes a redox reaction. The single-crystal structure determination of py.SeO2 revealed that the chain-like structure of (SeO2)n is destroyed during the formation of the DA bond and py.SeO2 molecule is bonded to the nearest neighboring molecule through two weak Se...O interactions. More labile TMA.SeO2 complex could not be prepared as single crystals. Analogous molecular structure of both complexes was proved by their Raman spectra. A modified general valence force field was used for the interpretation of Raman spectra of TMA.SeO2 and TMA.SO2.

Návaznosti

MSM 143100011, záměr

Název: Struktura a vazebné poměry, vlastnosti a analýza syntetických a přírodních molekulových ansamblů

Investor: Ministerstvo školství, mládeže a tělovýchovy ČR, Struktura a vazebné poměry, vlastnosti a analýza syntetických a přírodních molekulových ansamblů

Citovat

TOUŽÍN, Jiří; Kamila NEPLECHOVÁ; Zdirad ŽÁK a Miloš ČERNÍK. Syntheses and Structures of Donor-Acceptor Complexes of Selenium Dioxide with Pyridine and Trimethylamine. Collection of Czechoslovak Chemical Communications. Prague: Imperie "Politika", 2002, roč. 2002, č. 67, s. 577-586. ISSN 0010-0765.

@article{483609,
   author = {Toužín, Jiří and Neplechová, Kamila and Žák, Zdirad and Černík, Miloš},
   article_location = {Prague},
   article_number = {67},
   keywords = {DA-complex; Selenium dioxide; Pyridine; Trimethylamine; Crystal structure determination; Raman spectra; Normal coordinate analysis},
   language = {eng},
   issn = {0010-0765},
   journal = {Collection of Czechoslovak Chemical Communications},
   title = {Syntheses and Structures of Donor-Acceptor Complexes of Selenium Dioxide with Pyridine and Trimethylamine},
   volume = {2002},
   year = {2002}
}

TY  - JOUR
ID  - 483609
AU  - Toužín, Jiří - Neplechová, Kamila - Žák, Zdirad - Černík, Miloš
PY  - 2002
TI  - Syntheses and Structures of Donor-Acceptor Complexes of Selenium Dioxide with Pyridine and Trimethylamine
JF  - Collection of Czechoslovak Chemical Communications
VL  - 2002
IS  - 67
SP  - 577
EP  - 577
PB  - Imperie "Politika"
SN  - 00100765
KW  - DA-complex
KW  - Selenium dioxide
KW  - Pyridine
KW  - Trimethylamine
KW  - Crystal structure determination
KW  - Raman spectra
KW  - Normal coordinate analysis
N2  - Donor-acceptor complexes pyridine(py).SeO2 and trimethylamine(TMA).SeO2 were prepared by direct reactions of solid selenium dioxide with the amines. Both are white solids decomposing slowly at room temperature. The former decomposes into its components, while the latter undergoes a redox reaction. The single-crystal structure determination of py.SeO2 revealed that the chain-like structure of (SeO2)n is destroyed during the formation of the DA bond and py.SeO2 molecule is bonded to the nearest neighboring molecule through two weak Se...O interactions. More labile TMA.SeO2 complex could not be prepared as single crystals. Analogous molecular structure of both complexes was proved by their Raman spectra. A modified general valence force field was used for the interpretation of Raman spectra of TMA.SeO2 and TMA.SO2.
ER  -

TOUŽÍN, Jiří; Kamila NEPLECHOVÁ; Zdirad ŽÁK a Miloš ČERNÍK. Syntheses and Structures of Donor-Acceptor Complexes of Selenium Dioxide with Pyridine and Trimethylamine. \textit{Collection of Czechoslovak Chemical Communications}. Prague: Imperie ''Politika'', 2002, roč.~2002, č.~67, s.~577-586. ISSN~0010-0765.

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